Methyl 2-bromo-4-fluorobenzoate

Uses

Product Name: Methyl 2-bromo-4-fluorobenzoate
CAS No.: 653-92-9
Chemical Name: Methyl 2-bromo-4-fluorobenzoate
Synonyms: RARECHEM AL BF 1088;Bromo-4-fluorobenzoate;2-bromo-4-fluorobenzoate;METHYL 2-BROMO-4-FLUOROBENZOATE;Methyl 4-fluoro-2-bromobenzoate;2-bromo-4-fluoro-3-methylbenzoate;Methyl2-bromo-4-fluorobenzoate98%;Methyl 2-bromo-4-fluorobenzoate 98%;5-fluoro-2-(methoxycarbonyl)bromobenzene;methyl 2-bromo-4-fluorobenzenecarboxylate
CBNumber: CB5198865
Molecular Formula: C8H6BrFO2
Formula Weight: 233.03
MOL File: 653-92-9.mol

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Methyl 2-bromo-4-fluorobenzoate Property

Boiling point:: 75-78/1mm
Density: 1.577
Flash point:: 100℃
storage temp.: Sealed in dry,Room Temperature
Appearance: Colorless to light yellow Liquid
InChI: InChI=1S/C8H6BrFO2/c1-12-8(11)6-3-2-5(10)4-7(6)9/h2-4H,1H3
InChIKey: JENBPOJAZCPSEW-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(F)C=C1Br

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 22
HazardClass: IRRITANT
HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: M295998
Product name: Methyl2-bromo-4-fluorobenzoate
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M295998
Product name: Methyl2-bromo-4-fluorobenzoate
Packaging: 500mg
Price: $65
Updated: 2021/12/16

Matrix Scientific

Product number: 047369
Product name: Methyl 2-bromo-4-fluorobenzoate
Purity: >95%
Packaging: 5g
Price: $24
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2623-B-X0
Product name: Methyl 2-bromo-4-fluorobenzoate
Purity: 97%
Packaging: 5G
Price: $40
Updated: 2021/12/16

Matrix Scientific

Product number: 047369
Product name: Methyl 2-bromo-4-fluorobenzoate
Purity: >95%
Packaging: 25g
Price: $79
Updated: 2021/12/16

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Methyl 2-bromo-4-fluorobenzoate Chemical Properties,Usage,Production

Uses

Methyl 2-bromo-4-fluorobenzoate is a carboxylic acid ester derivative used as an organic intermediate.

Chemical Properties

off-white powder

Synthesis

DBU (1.7 equiv, 1.16 mL, 7.76 mmol) was added to a solution of 2-bromo-4-fluorobenzoicacid (1.0equiv, 1.0 g, 4.57 mmol) and iodomethane (2.0 equiv, 0.57 mL, 9.14 mmol) in CH3CN(11 mL) at 23 °C. After stirring for 48 h, the reaction was quenched with H2O(10 mL) and extracted with Et2O (2 x 10 mL). The combined organic extracts were washed with water (20 mL) and brine (20 mL), dried over Na2SO4 and filtrated. Evaporation of the solvent under reduced pressure followed by flash chromatography (SiO2, 95/5 hexane/EtOAc) afforded 1.0 g (98%)of Methyl 2-bromo-4-fluorobenzoate as a colourless oil.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2015, vol. 25, # 20, p. 4393 - 4398
[2] Patent: US6407250, 2002, B1
[3] Patent: US6511999, 2003, B2
[4] Patent: US2002/128233, 2002, A1
[5] Patent: US2004/162323, 2004, A1

Methyl 2-bromo-4-fluorobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-bromo-4-fluorobenzoate Suppliers

China 160 Germany 1 India 1 Italy 1 United Kingdom 2 United States 17 Global 182

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View Lastest Price from Methyl 2-bromo-4-fluorobenzoate manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: Methyl 2-bromo-4-fluorobenzoate 653-92-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-06-06

Henan Aochuang Chemical Co.,Ltd.

Product: Methyl2-bromo-4-fluorobenzoate 653-92-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-27

Shaanxi Dideu Medichem Co. Ltd

Product: Methyl 2-bromo-4-fluorobenzenecarboxylate 653-92-9
Price: US $0.00-0.00/KG
Min. Order: 5mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-07

653-92-9, Methyl 2-bromo-4-fluorobenzoateRelated Search:

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653-92-9

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