Methyl 2-bromo-5-fluorobenzoate

Product Name: Methyl 2-bromo-5-fluorobenzoate
CAS No.: 6942-39-8
Chemical Name: Methyl 2-bromo-5-fluorobenzoate
Synonyms: NSC 57466;RARECHEM AL BF 0749;Methyl 6-bromo-3-fluorobenzoate;METHYL 2-BROMO-5-FLUOROBENZOATE;Methyl2-bromo-5-fluorobenzoate98%;Methyl 2-bromo-5-fluorobenzoate 98%;1-Bromo-4-fluoro-2-(methoxycarbonyl)benzene;Benzoic acid, 2-broMo-5-fluoro-, Methyl ester;Methyl 2-bromo-5-fluorobenzoate , Methyl 2-bromo-5-fluorobenzoate;1-chloro-2,5-dimethyl-4-nitrobenzene/1-chloro-2,5-dimethyl-4-nitrobenzene
CBNumber: CB2410083
Molecular Formula: C8H6BrFO2
Formula Weight: 233.03
MOL File: 6942-39-8.mol

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Methyl 2-bromo-5-fluorobenzoate Property

Boiling point:: 247.5±25.0 °C(Predicted)
Density: 1.577±0.06 g/cm3(Predicted)
refractive index: 1.5350 to 1.5390
storage temp.: Sealed in dry,Room Temperature
form: clear liquid
color: Colorless to Light yellow to Light orange

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Safety

Hazard Codes: Xi
Hazard Note: Irritant
HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M3101
Product name: Methyl 2-Bromo-5-fluorobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $96
Updated: 2025/07/31

TCI Chemical

Product number: M3101
Product name: Methyl 2-Bromo-5-fluorobenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $282
Updated: 2025/07/31

TRC

Product number: M295993
Product name: Methyl 2-Bromo-5-fluorobenzoate
Packaging: 250mg
Price: $55
Updated: 2021/12/16

TRC

Product number: M295993
Product name: Methyl 2-Bromo-5-fluorobenzoate
Packaging: 1g
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: Y9841
Product name: Methyl 2-Bromo-5-fluorobenzoate
Packaging: 5g
Price: $83
Updated: 2021/12/16

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Methyl 2-bromo-5-fluorobenzoate Chemical Properties,Usage,Production

Uses

Methyl 2-bromo-5-fluorobenzoate is a fluorine-bromine substituted compound that has been widely used in the field of organic synthesis.

Synthesis

394-28-5

18107-18-1

6942-39-8

Procedure for the synthesis of methyl 2-bromo-5-fluorobenzoate (159-1): trimethylsilylated diazomethane (338 mL, 676 mmol, 2.0 M ether solution) was slowly added dropwise to a stirring methanol (676 mL) solution of 2-bromo-5-fluorobenzoic acid (74 g, 338 mmol) at 0 °C until the reaction solution took on a persistent yellow color. Subsequently, acetic acid was added dropwise until the yellow color completely faded. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was dissolved in dichloromethane and filtered through a silica gel column, eluting with dichloromethane. Finally, the solvent was removed from the eluate by reduced pressure distillation to give 77 g (98% yield) of methyl 2-bromo-5-fluorobenzoate (159-1) as a yellow oil.

References

[1] Patent: WO2008/51532, 2008, A1. Location in patent: Page/Page column 52-53
[2] Patent: WO2009/54925, 2009, A1. Location in patent: Page/Page column 20

Methyl 2-bromo-5-fluorobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-bromo-5-fluorobenzoate Suppliers

Americas 1 China 113 Europe 1 Germany 1 India 2 Japan 1 United Kingdom 4 United States 12 Global 135

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View Lastest Price from Methyl 2-bromo-5-fluorobenzoate manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Methyl 2-bromo-5-fluorobenzoate 6942-39-8
Price: US $0.00-0.00/KG
Min. Order: 5mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-07

Career Henan Chemical Co

Product: METHYL 2-BROMO-5-FLUOROBENZOATE 6942-39-8
Price: US $2.00/KG
Min. Order: 1g
Purity: 98%MIN
Supply Ability: ASK
Release date: 2020-01-07

6942-39-8, Methyl 2-bromo-5-fluorobenzoateRelated Search:

METHYL 4-BROMO-3-FLUOROBENZOATE 98,Methyl 4-bromo-3-fluorobenzoate 98% METHYL 3-BROMO-5-FLUOROBENZOATE Methyl2-bromo-4-fluorobenzoate98%,Methyl 2-bromo-4-fluorobenzoate 98%,METHYL 2-BROMO-4-FLUOROBENZOATE 2-Bromobenzoic acid 2-Bromo-5-fluorobenzyl alcohol Methyl 2-bromobenzoate 4-Bromofluorobenzene METHYL 2-BROMO-5-FLUOROBENZOATE 2-Bromo-5-fluorobenzoic acid 2-Bromo-5-fluorotoluene 2-Bromo-5-fluorobenzaldehyde 3-Fluorobenzoic acid Methyl 3-bromo-4-fluorobenzoate 98%,Methyl3-bromo-4-fluorobenzoate98%,METHYL 3-BROMO-4-FLUOROBENZOATE METHYL 2-BROMO-4,5-DIFLUOROBENZOATE 1-FLUORO-3-(METHOXYMETHYL)BENZENE METHYL 3-FLUOROBENZOATE ETHYL 2-BROMO-4,5-DIFLUOROBENZOATE Methyl 3-bromo-2-fluorobenzoate

3,3-dimethyl-N-<4-methylphenylsulfonyl>azetidineMETHYL 2-BROMO-5-FLUOROBENZOATE

RARECHEM AL BF 0749

Methyl 2-bromo-5-fluorobenzoate 98%

Methyl2-bromo-5-fluorobenzoate98%

1-Bromo-4-fluoro-2-(methoxycarbonyl)benzene

Benzoic acid, 2-broMo-5-fluoro-, Methyl ester

Methyl 6-bromo-3-fluorobenzoate

NSC 57466

METHYL 2-BROMO-5-FLUOROBENZOATE

Methyl 2-bromo-5-fluorobenzoate , Methyl 2-bromo-5-fluorobenzoate

1-chloro-2,5-dimethyl-4-nitrobenzene/1-chloro-2,5-dimethyl-4-nitrobenzene

6942-39-8

Acids & Esters

Bromine Compounds

Fluorine Compounds

blocks

Bromides

Carboxes

FluoroCompounds

Benzene series