METHYL 3-HYDROXY-4-METHYLBENZOATE

ChemicalBook > CAS DataBase List > METHYL 3-HYDROXY-4-METHYLBENZOATE

METHYL 3-HYDROXY-4-METHYLBENZOATE

Synthesis

Product Name: METHYL 3-HYDROXY-4-METHYLBENZOATE
CAS No.: 3556-86-3
Chemical Name: METHYL 3-HYDROXY-4-METHYLBENZOATE
Synonyms: 3,4-Cresotic acid methyl ester;METHYL 3-HYDROXY-4-METHYLBENZOATE;Methyl 4-Methyl-3-hydroxybenzoate;3-HYDROXY-P-TOLUIC ACID METHYL ESTER;Methyl 3-hydroxy-4-methylbenzoate 98%;3-HYDROXY-4-METHYLBENZOIC ACID METHYL ESTER;benzoic acid, 3-hydroxy-4-methyl-, methyl ester
CBNumber: CB5209910
Molecular Formula: C9H10O3
Formula Weight: 166.17
MOL File: 3556-86-3.mol

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METHYL 3-HYDROXY-4-METHYLBENZOATE Property

Melting point:: 119.0-120.5 °C
Boiling point:: 294.6±20.0 °C(Predicted)
Density: 1.169±0.06 g/cm3(Predicted)
storage temp.: Hygroscopic, Refrigerator, under inert atmosphere
solubility: Acetone (Slightly), Chloroform (Slightly)
pka: 9.50±0.10(Predicted)
form: Solid
color: Tan
Stability:: Hygroscopic
CAS DataBase Reference: 3556-86-3(CAS DataBase Reference)

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Safety

HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M322970
Product name: Methyl4-Methyl-3-hydroxybenzoate
Packaging: 2.5g
Price: $45
Updated: 2021/12/16

Usbiological

Product number: 283450
Product name: Methyl 3-hydroxy-4-methylbenzoate
Packaging: 2g
Price: $399
Updated: 2021/12/16

Usbiological

Product number: 164917
Product name: Methyl 4-Methyl-3-hydroxybenzoate
Packaging: 1g
Price: $403
Updated: 2021/12/16

Apolloscientific

Product number: OR311176
Product name: Methyl3-hydroxy-4-methylbenzoate
Purity: 98%
Packaging: 25g
Price: $435
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2729-1-71
Product name: Methyl 3-hydroxy-4-methylbenzoate
Purity: 98%
Packaging: 25g
Price: $480
Updated: 2021/12/16

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METHYL 3-HYDROXY-4-METHYLBENZOATE Chemical Properties,Usage,Production

Synthesis

Methyl 3-hydroxy-4-methylbenzoate is synthesized by the following steps:The amino ester 35 (60 g, 0.364 mol) was added to dil. H2SO4 (125 ml conc. H2SO4 diluted with 1 L water) and warmed on a water bath until all the compound was dissolved. Cold water (800 ml) was added and the mixture was cooled to 0 °C. NaNO2 (62.6 g, 0.907 mol) was added to this mixture with constant stirring. It was then stirred at room temperature for 15 minutes. Then, urea (65.4 g, 1.09 mol) was added in portions. The mixture was warmed at 50 ºC for 15 minutes (temperature was not allowed to rise above 55 ºC). EtOAc was added to the reaction mixture and washed with brine, dried (anhydrous Na2SO4), filtered and concentrated under reduced pressure to afford a colourless solid (26.56 g).

Uses

Methyl 4-Methyl-3-hydroxybenzoate is used in the preparation of potent antimalarial agents. Also used in the preparation of aromatic inhibtors of anthranilate synthase.

METHYL 3-HYDROXY-4-METHYLBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 3-HYDROXY-4-METHYLBENZOATE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Methyl 3-Hydroxy-4-methylbenzoate 3556-86-3
Price: US $1.00/Kg
Min. Order: 1Kg
Purity: 98%
Supply Ability: 20T
Release date: 2024-07-19

Career Henan Chemical Co

Product: METHYL 3-HYDROXY-4-METHYLBENZOATE 3556-86-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kgs
Release date: 2020-01-09

3556-86-3, METHYL 3-HYDROXY-4-METHYLBENZOATERelated Search:

METHYL 3-HYDROXY-4-METHYLBENZOATE AMAROGENTIN METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE METHYL 3-METHOXY-4-METHYLBENZOATE DIETHYL 2,5-DIHYDROXYTEREPHTHALATE METHYL 2,4-DIHYDROXY-3-METHYLBENZOATE METHYL 3,5-DIBROMO-2,4-DIHYDROXY-6-METHYLBENZOATE METHYL 2-HYDROXY-3-METHYLBENZOATE METHYL 2-HYDROXY-4-METHYLBENZOATE METHYL 2-HYDROXY-5-METHYLBENZOATE METHYL 2,4-DIMETHOXY-6-METHYLBENZOATE METHYL 3-HYDROXY-2-METHYLBENZOATE 3-Hydroxy-4-methylbenzoic acid RARECHEM AL BF 1403 4-METHYL-3-BENZYLOXYBENZOIC ACID METHYL ESTER Purpuromycin METHYL 3,5-DIMETHOXY-4-METHYLBENZOATE METHYL 3,5-DIHYDROXY-4-METHYLBENZOATE

benzoic acid, 3-hydroxy-4-methyl-, methyl ester

Methyl 4-Methyl-3-hydroxybenzoate

METHYL 3-HYDROXY-4-METHYLBENZOATE

3-HYDROXY-4-METHYLBENZOIC ACID METHYL ESTER

3-HYDROXY-P-TOLUIC ACID METHYL ESTER

3,4-Cresotic acid methyl ester

Methyl 3-hydroxy-4-methylbenzoate 98%

3556-86-3

Esters

Phenyls & Phenyl-Het