Methyl 4-methylsalicylate
- Product Name
- Methyl 4-methylsalicylate
- CAS No.
- 4670-56-8
- Chemical Name
- Methyl 4-methylsalicylate
- Synonyms
- Methyl-4-Methyl;METHYL M-CRESOTATE;TIMTEC-BB SBB008512;RARECHEM AL BF 0822;METHYL M-CRESOTINATE;Methyl 4-methylsalic;methyl methyl salicylate;METHYL 4-METHYLSALICYLATE;Methy-4-Methyl Salicylate;METHYL-4-MEHTYL SALICYLATE
- CBNumber
- CB9477135
- Molecular Formula
- C9H10O3
- Formula Weight
- 166.17
- MOL File
- 4670-56-8.mol
Methyl 4-methylsalicylate Property
- Melting point:
- 27-28℃
- Boiling point:
- 242 °C
- Density
- 1.147
- refractive index
- 1.5370
- Flash point:
- 28 °C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Low Melting Solid
- pka
- 9.87±0.10(Predicted)
- color
- Pale brown to pale yellow
- FreezingPoint
- 24.0 to 28.0 ℃
- InChI
- InChI=1S/C9H10O3/c1-6-3-4-7(8(10)5-6)9(11)12-2/h3-5,10H,1-2H3
- InChIKey
- UITFCFWKYAOJEJ-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C(C)C=C1O
- LogP
- 3.000 (est)
- CAS DataBase Reference
- 4670-56-8(CAS DataBase Reference)
Safety
- HS Code
- 2918230000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M1584
- Product name
- Methyl 4-Methylsalicylate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $26
- Updated
- 2025/07/31
- Product number
- M1584
- Product name
- Methyl 4-Methylsalicylate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $77
- Updated
- 2025/07/31
- Product number
- M338598
- Product name
- Methyl 4-Methylsalicylate
- Packaging
- 500mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- A653
- Product name
- Methyl 4-Methylsalicylate
- Packaging
- 25g
- Price
- $90
- Updated
- 2021/12/16
- Product number
- 172526
- Product name
- Methyl 4-methylsalicylate
- Packaging
- 5g
- Price
- $100
- Updated
- 2021/12/16
Methyl 4-methylsalicylate Chemical Properties,Usage,Production
Synthesis Reference(s)
Journal of the American Chemical Society, 102, p. 3534, 1980 DOI: 10.1021/ja00530a038
Synthesis
586-30-1
4670-56-8
Step 1: 3-hydroxy-4-methylbenzoic acid (4.56 g, 30 mmol) was dissolved in methanol (60 mL) and thionyl chloride (40 drops) was added slowly and dropwise. The reaction mixture was heated to reflux and maintained for 18 hours. Upon completion of the reaction, the volatile components were removed by distillation under reduced pressure. The crude product was purified by fast column chromatography on silica gel, using gradient elution with ethyl acetate/heptane (2%-40%) to afford methyl 2-hydroxy-4-methylbenzoate (3.04 g, 61% yield) as a colorless oil. Mass spectrometry analysis (ESI/APCI+): m/z 167 ([M-H]-).
References
[1] Patent: WO2010/130842, 2010, A1. Location in patent: Page/Page column 132-133
Methyl 4-methylsalicylate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 4-methylsalicylate manufacturers
- Product
- Methyl 4-methylsalicylate 4670-56-8
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-13
- Product
- Methyl 4-methylsalicylate 4670-56-8
- Price
- US $60.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2024-11-22
- Product
- Methyl 4-methylsalicylate 4670-56-8
- Price
- US $1.00-1.50/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100000KG
- Release date
- 2024-08-05