ChemicalBook > CAS DataBase List > Methyl 4-methylsalicylate

Methyl 4-methylsalicylate

Product Name
Methyl 4-methylsalicylate
CAS No.
4670-56-8
Chemical Name
Methyl 4-methylsalicylate
Synonyms
Methyl-4-Methyl;METHYL M-CRESOTATE;TIMTEC-BB SBB008512;RARECHEM AL BF 0822;METHYL M-CRESOTINATE;Methyl 4-methylsalic;methyl methyl salicylate;METHYL 4-METHYLSALICYLATE;Methy-4-Methyl Salicylate;METHYL-4-MEHTYL SALICYLATE
CBNumber
CB9477135
Molecular Formula
C9H10O3
Formula Weight
166.17
MOL File
4670-56-8.mol
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Methyl 4-methylsalicylate Property

Melting point:
27-28℃
Boiling point:
242 °C
Density 
1.147
refractive index 
1.5370
Flash point:
28 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Low Melting Solid
pka
9.87±0.10(Predicted)
color 
Pale brown to pale yellow
FreezingPoint 
24.0 to 28.0 ℃
InChI
InChI=1S/C9H10O3/c1-6-3-4-7(8(10)5-6)9(11)12-2/h3-5,10H,1-2H3
InChIKey
UITFCFWKYAOJEJ-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C(C)C=C1O
LogP
3.000 (est)
CAS DataBase Reference
4670-56-8(CAS DataBase Reference)
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Safety

HS Code 
2918230000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M1584
Product name
Methyl 4-Methylsalicylate
Purity
>98.0%(GC)
Packaging
5g
Price
$26
Updated
2025/07/31
TCI Chemical
Product number
M1584
Product name
Methyl 4-Methylsalicylate
Purity
>98.0%(GC)
Packaging
25g
Price
$77
Updated
2025/07/31
TRC
Product number
M338598
Product name
Methyl 4-Methylsalicylate
Packaging
500mg
Price
$60
Updated
2021/12/16
AK Scientific
Product number
J91630
Product name
Methyl 4-Methylsalicylate
Packaging
1g
Price
$10
Updated
2021/12/16
AK Scientific
Product number
A653
Product name
Methyl 4-Methylsalicylate
Packaging
5g
Price
$34
Updated
2021/12/16
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Methyl 4-methylsalicylate Chemical Properties,Usage,Production

Synthesis Reference(s)

Journal of the American Chemical Society, 102, p. 3534, 1980 DOI: 10.1021/ja00530a038

Synthesis

586-30-1

4670-56-8

Step 1: 3-hydroxy-4-methylbenzoic acid (4.56 g, 30 mmol) was dissolved in methanol (60 mL) and thionyl chloride (40 drops) was added slowly and dropwise. The reaction mixture was heated to reflux and maintained for 18 hours. Upon completion of the reaction, the volatile components were removed by distillation under reduced pressure. The crude product was purified by fast column chromatography on silica gel, using gradient elution with ethyl acetate/heptane (2%-40%) to afford methyl 2-hydroxy-4-methylbenzoate (3.04 g, 61% yield) as a colorless oil. Mass spectrometry analysis (ESI/APCI+): m/z 167 ([M-H]-).

References

[1] Patent: WO2010/130842, 2010, A1. Location in patent: Page/Page column 132-133

Methyl 4-methylsalicylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 4-methylsalicylate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
Methyl 4-methylsalicylate 4670-56-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2024-11-13
Hebei Zhuanglai Chemical Trading Co Ltd
Product
Methyl 4-methylsalicylate 4670-56-8
Price
US $60.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-11-22
Shaanxi Dideu Medichem Co. Ltd
Product
Methyl 4-methylsalicylate 4670-56-8
Price
US $1.00-1.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
100000KG
Release date
2024-08-05

4670-56-8, Methyl 4-methylsalicylateRelated Search:

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