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CERIUM(IV) TRIFLUOROMETHANESULFONATE

Product Name
CERIUM(IV) TRIFLUOROMETHANESULFONATE
CAS No.
107792-63-2
Chemical Name
CERIUM(IV) TRIFLUOROMETHANESULFONATE
Synonyms
CERIUM(IV) TRIFLATE;ceric triflate;CERIUM(IV) TRIFLATE698999-65-4;CERIUM(IV) TRIFLUOROMETHANESULFONATE;CERIUM(IV) TRIFLUOROMETHANESULPHONATE;Cerium(IV) trifluoromethanesulfonate,99%;CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4
CBNumber
CB5219973
Molecular Formula
C4CeF12O12S4
Formula Weight
736.39
MOL File
107792-63-2.mol
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CERIUM(IV) TRIFLUOROMETHANESULFONATE Property

solubility 
soluble in DMSO
form 
Solid
color 
Yellow
Water Solubility 
Soluble in water.
Sensitive 
Hygroscopic
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
45-36/37/39-26
TSCA 
No
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
L20056
Product name
Cerium(IV) trifluoromethanesulfonate, 98%
Packaging
5g
Price
$52.5
Updated
2024/03/01
Alfa Aesar
Product number
L20056
Product name
Cerium(IV) trifluoromethanesulfonate, 98%
Packaging
25g
Price
$159.65
Updated
2024/03/01
TRC
Product number
C278580
Product name
Cerium(IV)trifluoromethanesulfonate
Packaging
1g
Price
$110
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0026060
Product name
CERIUM(IV)TRIFLUOROMETHANESULFONATE
Purity
95.00%
Packaging
5MG
Price
$454.46
Updated
2021/12/16
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CERIUM(IV) TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production

Chemical Properties

Cerium(IV) Trifluoromethanesulfonate (ceric triflate) is a oxidizing agent for benzyl alcohols and toluenes; yellow powder or solid; sol water, THF, DME, dioxane; insol dichloromethane, hexane, benzene.

Uses

Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers

Preparation

By the reaction of trifluoromethanesulfonic acid with freshly prepared cerium(IV) carbonate[1]. Cerium(IV) Trifluoromethanesulfonate can be prepared in situ by the electrochemical oxidation of Ce(OTf)3 in aqueous trifluoromethanesulfonic acid[2].

storage

Cerium(IV) trifluoromethanesulfonate is extremely hygroscopic and should be stored under strict absence of moisture. This reagent should be handled in a fume hood.

References

1. Imamoto, T.; Koide, Y.; Hiyama, S. CL 1990, 1445.
2. Kreh, R. P.; Spotnitz, R. M.; Lundquist, J. T. TL 1987, 28, 1067.

CERIUM(IV) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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CERIUM(IV) TRIFLUOROMETHANESULFONATE Suppliers

Belgium 1 Canada 1 China 29 Germany 1 India 2 United States 5 Global 39
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Alfa Aesar
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400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
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Adamas Reagent, Ltd.
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400-6009262 16621234537
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021-64823266
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chenyj@titansci.com
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China
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Chemsky（shanghai）International Co.,Ltd.
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021-50135380
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shchemsky@sina.com
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China
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Shandong Xiya Chemical Co., Ltd
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4009903999 13355009207
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0539-6365991
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3007715519@qq.com
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China
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Thermo Fisher Scientific
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800-810-5118
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+86-10-84193589
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cnchemical@thermofisher.com
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China
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Shanghai Macklin Biochemical Co.,Ltd.
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15221275939 15221275939
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021-50706099
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shenlinxing@macklin.cn
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China
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Aikon International Limited
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025-66113011 13155353615
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(7)02557626880
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qzhang@aikonchem.com
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China
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Alfa Chemistry
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Fax
1-516-927-0118
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Info@alfa-chemistry.com
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United States
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24072
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107792-63-2, CERIUM(IV) TRIFLUOROMETHANESULFONATERelated Search:

Sodium trifluoromethanesulfinate Methanesulfonic acid CERIUM CERIUM(III) TRIFLUOROMETHANESULFONATE CERIUM CERIUM(IV) TRIFLUOROMETHANESULFONATE HYDRATE CERIUM(IV) TRIFLUOROMETHANESULFONATE HY& CERIUM(IV) TRIFLUOROMETHANESULFONATE HYDRATE CERIUM(IV) TRIFLUOROMETHANESULFONATE P-TOLYL TRIFLATE AMMONIUM TRIFLUOROMETHANESULFONATE TRIFLUOROMETHANESULFONIC ACID TRIFLUOROMETHYL ESTER YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE SAMARIUM(III) TRIFLUOROMETHANESULFONATE DYSPROSIUM(III) TRIFLUOROMETHANESULFONATE Thulium(III) Trifluoromethanesulfonate Methanesulfonic acid, trifluoro-, cyclopropyl ester

  • CERIUM(IV) TRIFLATE
  • CERIUM(IV) TRIFLUOROMETHANESULFONATE
  • CERIUM(IV) TRIFLUOROMETHANESULPHONATE
  • ceric triflate
  • CERIUM(IV) TRIFLATE698999-65-4
  • Cerium(IV) trifluoromethanesulfonate,99%
  • CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4
  • 107792-63-2
  • 21951-90-9
  • C4F12O12S4Ce25H2O
  • C4CeF12O12S4
  • CF3SO34Ce