CERIUM(IV) TRIFLUOROMETHANESULFONATE

Product Name: CERIUM(IV) TRIFLUOROMETHANESULFONATE
CAS No.: 107792-63-2
Chemical Name: CERIUM(IV) TRIFLUOROMETHANESULFONATE
Synonyms: CERIUM(IV) TRIFLATE;ceric triflate;CERIUM(IV) TRIFLATE698999-65-4;CERIUM(IV) TRIFLUOROMETHANESULFONATE;CERIUM(IV) TRIFLUOROMETHANESULPHONATE;Cerium(IV) trifluoromethanesulfonate,99%;CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4
CBNumber: CB5219973
Molecular Formula: C4CeF12O12S4
Formula Weight: 736.39
MOL File: 107792-63-2.mol

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CERIUM(IV) TRIFLUOROMETHANESULFONATE Property

solubility: soluble in DMSO
form: Solid
color: Yellow
Water Solubility: Soluble in water.
Sensitive: Hygroscopic

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 45-36/37/39-26
TSCA: No
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar

Product number: L20056
Product name: Cerium(IV) trifluoromethanesulfonate, 98%
Packaging: 5g
Price: $52.5
Updated: 2024/03/01

Alfa Aesar

Product number: L20056
Product name: Cerium(IV) trifluoromethanesulfonate, 98%
Packaging: 25g
Price: $159.65
Updated: 2024/03/01

TRC

Product number: C278580
Product name: Cerium(IV)trifluoromethanesulfonate
Packaging: 1g
Price: $110
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0026060
Product name: CERIUM(IV)TRIFLUOROMETHANESULFONATE
Purity: 95.00%
Packaging: 5MG
Price: $454.46
Updated: 2021/12/16

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CERIUM(IV) TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production

Chemical Properties

Cerium(IV) Trifluoromethanesulfonate (ceric triflate) is a oxidizing agent for benzyl alcohols and toluenes; yellow powder or solid; sol water, THF, DME, dioxane; insol dichloromethane, hexane, benzene.

Uses

Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers

Preparation

By the reaction of trifluoromethanesulfonic acid with freshly prepared cerium(IV) carbonate^[1]. Cerium(IV) Trifluoromethanesulfonate can be prepared in situ by the electrochemical oxidation of Ce(OTf)3 in aqueous trifluoromethanesulfonic acid^[2].

storage

Cerium(IV) trifluoromethanesulfonate is extremely hygroscopic and should be stored under strict absence of moisture. This reagent should be handled in a fume hood.

References

1. Imamoto, T.; Koide, Y.; Hiyama, S. CL 1990, 1445.
2. Kreh, R. P.; Spotnitz, R. M.; Lundquist, J. T. TL 1987, 28, 1067.

CERIUM(IV) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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CERIUM(IV) TRIFLUOROMETHANESULFONATE Suppliers

Belgium 1 Canada 1 China 29 Germany 1 India 2 United States 5 Global 39

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107792-63-2, CERIUM(IV) TRIFLUOROMETHANESULFONATERelated Search:

CERIUM(IV) TRIFLATE

CERIUM(IV) TRIFLUOROMETHANESULFONATE

CERIUM(IV) TRIFLUOROMETHANESULPHONATE

ceric triflate

CERIUM(IV) TRIFLATE698999-65-4

Cerium(IV) trifluoromethanesulfonate,99%

CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4

107792-63-2

21951-90-9

C4F12O12S4Ce25H2O

C4CeF12O12S4

CF3SO34Ce