METHYL 2-FLUORO-3-METHYLBENZOATE
- Product Name
- METHYL 2-FLUORO-3-METHYLBENZOATE
- CAS No.
- 586374-04-1
- Chemical Name
- METHYL 2-FLUORO-3-METHYLBENZOATE
- Synonyms
- 2-fluoro-3-methylbenzoate;METHYL 2-FLUORO-3-METHYLBENZOATE;2-Fluoro-3-methyl benzoate methyl;2-Fluoro-3-methylbenzoic acid methyl ester;Benzoic acid, 2-fluoro-3-methyl-, methyl ester;2-fluoro-3-methyl-Benzoic acid methyl ester (9CI ACI);Benzoic acid, 2-fluoro-3-methyl-, methyl ester (9CI, ACI)
- CBNumber
- CB52454716
- Molecular Formula
- C9H9FO2
- Formula Weight
- 168.16
- MOL File
- 586374-04-1.mol
METHYL 2-FLUORO-3-METHYLBENZOATE Property
- Boiling point:
- 229.0±28.0℃ (760 Torr)
- Density
- 1.137±0.06 g/cm3 (20 ºC 760 Torr)
- Flash point:
- 89.8±18.9℃
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light pink Liquid
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 209485
- Product name
- Methyl 2-fluoro-3-methylbenzoate
- Packaging
- 250mg
- Price
- $25
- Updated
- 2021/12/16
- Product number
- 209485
- Product name
- Methyl 2-fluoro-3-methylbenzoate
- Packaging
- 1g
- Price
- $48
- Updated
- 2021/12/16
- Product number
- 209485
- Product name
- Methyl 2-fluoro-3-methylbenzoate
- Packaging
- 5g
- Price
- $148
- Updated
- 2021/12/16
- Product number
- 209485
- Product name
- Methyl 2-fluoro-3-methylbenzoate
- Packaging
- 25g
- Price
- $499
- Updated
- 2021/12/16
- Product number
- HCH0369203
- Product name
- METHYL-2-FLUORO-3-METHYLBENZOATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $504.85
- Updated
- 2021/12/16
METHYL 2-FLUORO-3-METHYLBENZOATE Chemical Properties,Usage,Production
Chemical Properties
off-white powder
Synthesis
67-56-1
315-31-1
586374-04-1
Step A: Thionyl chloride (2.8 mL, 39.0 mmol) was added slowly and dropwise to a stirred solution of 2-fluoro-3-methylbenzoic acid (4.0 g, 26.0 mmol) in anhydrous methanol (52 mL) at 0 °C. The reaction mixture was stirred overnight under reflux conditions. Upon completion of the reaction, the mixture was diluted with methanol and the excess thionyl chloride was subsequently removed by concentration under reduced pressure. The residue was dissolved in ethyl acetate, the organic layer was washed with saturated aqueous sodium bicarbonate, dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to afford methyl 2-fluoro-3-methylbenzoate (3.6 g, 83% yield) as a clear oil. The product could be used in subsequent steps without further purification.1H NMR (500 MHz, CDCl3) δ 7.75-7.72 (m, 1H), 7.38-7.35 (m, 1H), 7.26-7.06 (m, 1H), 3.91 (s, 3H), 2.31 (s, 3H).
References
[1] Patent: WO2011/8572, 2011, A2. Location in patent: Page/Page column 62
[2] Patent: WO2005/18557, 2005, A2. Location in patent: Page/Page column 304
[3] Patent: WO2005/18557, 2005, A2. Location in patent: Page/Page column 304
METHYL 2-FLUORO-3-METHYLBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 2-FLUORO-3-METHYLBENZOATE Suppliers
- Tel
- --
- Fax
- --
- enquiries@fluorochem.co.uk
- Country
- United Kingdom
- ProdList
- 6401
- Advantage
- 74
View Lastest Price from METHYL 2-FLUORO-3-METHYLBENZOATE manufacturers
- Product
- Methyl 2-fluoro-3-methylbenzoate 586374-04-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 97.0%
- Supply Ability
- 100 tons
- Release date
- 2022-01-14
- Product
- METHYL 2-FLUORO-3-METHYLBENZOATE 586374-04-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-08