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Biphenyl-3,3',5,5'-tetracarboxylic acid

Product Name
Biphenyl-3,3',5,5'-tetracarboxylic acid
CAS No.
4371-28-2
Chemical Name
Biphenyl-3,3',5,5'-tetracarboxylic acid
Synonyms
DK7660;DK7232;Biphenyl-3,3',5,5'-tetracarboxylicaci;3,3',5,5'-Biphenyltetracarboxylicacid;3,3',5,5'-Biphenyltetracarboxylic acid;Biphenyl-3,3',5,5'-tetracarboxylic acid;Biphenyl-3,3',5,5'-tetracarboxylic Acid >[1,1'-biphenyl]-3,3',5,5'-tetracarboxylicacid;1,1'-Biphenyl]-3,3',5,5'-tetracarboxylic acid;5-(3,5-dicarboxyphenyl)benzene-1,3-dicarboxylic acid
CBNumber
CB52514526
Molecular Formula
C16H10O8
Formula Weight
330.25
MOL File
4371-28-2.mol
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Biphenyl-3,3',5,5'-tetracarboxylic acid Property

Melting point:
>400℃
Boiling point:
772.3±60.0 °C(Predicted)
Density 
1.612±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
3.06±0.10(Predicted)
form 
solid
color 
White to Almost white
InChI
InChI=1S/C16H10O8/c17-13(18)9-1-7(2-10(5-9)14(19)20)8-3-11(15(21)22)6-12(4-8)16(23)24/h1-6H,(H,17,18)(H,19,20)(H,21,22)(H,23,24)
InChIKey
QURGMSIQFRADOZ-UHFFFAOYSA-N
SMILES
C1(C2=CC(C(O)=O)=CC(C(O)=O)=C2)=CC(C(O)=O)=CC(C(O)=O)=C1
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Safety

Hazard Codes 
N
Risk Statements 
50
Safety Statements 
61
RIDADR 
UN 3077
WGK Germany 
3
HS Code 
29173990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
720968
Product name
Biphenyl-3,3′,5,5′-tetracarboxylic acid
Packaging
100mg
Price
$102
Updated
2023/06/20
TCI Chemical
Product number
B3792
Product name
Biphenyl-3,3',5,5'-tetracarboxylic Acid
Purity
>98.0%(HPLC)
Packaging
200mg
Price
$161
Updated
2025/07/31
AK Scientific
Product number
3574AE
Product name
Biphenyl-3,3′,5,5′-tetracarboxylic acid
Packaging
1g
Price
$185
Updated
2021/12/16
Matrix Scientific
Product number
076971
Product name
Biphenyl-3,3',5,5'-tetracarboxylic acid
Purity
95%
Packaging
1g
Price
$290
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0140325
Product name
BIPHENYL-3,3',5,5'-TETRACARBOXYLIC ACID
Purity
95.00%
Packaging
500MG
Price
$952.88
Updated
2021/12/16
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Biphenyl-3,3',5,5'-tetracarboxylic acid Chemical Properties,Usage,Production

Uses

Selected Applications of MOFs in Sustainable Energy Technologies

General Description

This product has been enhanced for energy efficiency.

Synthesis

109936-20-1

4371-28-2

A mixture of 3,3',5,5'-tetrakis(methoxycarbonyl)biphenyl (12) (0.96 g, 2.5 mmol) was dissolved in water (40 mL) with THF (40 mL) and NaOH (1.6 g, 40 mmol) and reacted at reflux for 1 hour. Subsequently, the organic solvent was evaporated under reduced pressure and the remaining aqueous solution was continued to reflux for 4 hours. After completion of the reaction, the reaction mixture was cooled and acidified with 50% H2SO4 until the precipitation was complete. The precipitate was collected by filtration and dried to give the target product 3,3',5,5'-biphenyltetracarboxylic acid (9) as a white powder in 89% yield. Product melting point > 350°C. 1H-NMR (400 MHz, DMSO-d6): δ = 8.44 (d, 4H, J = 1.5 Hz), 8.53 (t, 2H, J = 1.5 Hz), 13.48 (bs, 4H). 13C-NMR (100 MHz, DMSO-d6): δ = 129.5, 131.4, 132.3 , 139.2, 166.3. MS-EI, m/z (%): 330 (100) [M+], 313 (40), 285 (15), 240 (5).

References

[1] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[2] European Journal of Organic Chemistry, 2007, # 20, p. 3271 - 3276
[3] Patent: EP1972338, 2008, A1. Location in patent: Page/Page column 14
[4] Journal of the Chemical Society, 1923, vol. 123, p. 1045

Biphenyl-3,3',5,5'-tetracarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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Biphenyl-3,3',5,5'-tetracarboxylic acid Suppliers

Americas 1 China 111 Europe 1 India 2 Japan 1 United States 6 Global 122
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from Biphenyl-3,3',5,5'-tetracarboxylic acid manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
Biphenyl-3,3',5,5'-tetracarboxylic acid 4371-28-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Career Henan Chemical Co
Product
Biphenyl-3,3',5,5'-tetracarboxylic acid 4371-28-2
Price
US $2.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2018-12-24

4371-28-2, Biphenyl-3,3',5,5'-tetracarboxylic acidRelated Search:

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