ChemicalBook > CAS DataBase List > Biphenyl-3,3',5,5'-tetracarboxylic acid

Biphenyl-3,3',5,5'-tetracarboxylic acid

Product Name: Biphenyl-3,3',5,5'-tetracarboxylic acid
CAS No.: 4371-28-2
Chemical Name: Biphenyl-3,3',5,5'-tetracarboxylic acid
Synonyms: DK7660;DK7232;Biphenyl-3,3',5,5'-tetracarboxylicaci;3,3',5,5'-Biphenyltetracarboxylicacid;3,3',5,5'-Biphenyltetracarboxylic acid;Biphenyl-3,3',5,5'-tetracarboxylic acid;Biphenyl-3,3',5,5'-tetracarboxylic Acid >[1,1'-biphenyl]-3,3',5,5'-tetracarboxylicacid;1,1'-Biphenyl]-3,3',5,5'-tetracarboxylic acid;5-(3,5-dicarboxyphenyl)benzene-1,3-dicarboxylic acid
CBNumber: CB52514526
Molecular Formula: C16H10O8
Formula Weight: 330.25
MOL File: 4371-28-2.mol

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Biphenyl-3,3',5,5'-tetracarboxylic acid Property

Melting point:: >400℃
Boiling point:: 772.3±60.0 °C(Predicted)
Density: 1.612±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 3.06±0.10(Predicted)
form: solid
color: White to Almost white
InChI: InChI=1S/C16H10O8/c17-13(18)9-1-7(2-10(5-9)14(19)20)8-3-11(15(21)22)6-12(4-8)16(23)24/h1-6H,(H,17,18)(H,19,20)(H,21,22)(H,23,24)
InChIKey: QURGMSIQFRADOZ-UHFFFAOYSA-N
SMILES: C1(C2=CC(C(O)=O)=CC(C(O)=O)=C2)=CC(C(O)=O)=CC(C(O)=O)=C1

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Safety

Hazard Codes: N
Risk Statements: 50
Safety Statements: 61
RIDADR: UN 3077
WGK Germany: 3
HS Code: 29173990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 720968
Product name: Biphenyl-3,3′,5,5′-tetracarboxylic acid
Packaging: 100mg
Price: $102
Updated: 2023/06/20

TCI Chemical

Product number: B3792
Product name: Biphenyl-3,3',5,5'-tetracarboxylic Acid
Purity: >98.0%(HPLC)
Packaging: 200mg
Price: $161
Updated: 2025/07/31

AK Scientific

Product number: 3574AE
Product name: Biphenyl-3,3′,5,5′-tetracarboxylic acid
Packaging: 1g
Price: $185
Updated: 2021/12/16

Matrix Scientific

Product number: 076971
Product name: Biphenyl-3,3',5,5'-tetracarboxylic acid
Purity: 95%
Packaging: 1g
Price: $290
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0140325
Product name: BIPHENYL-3,3',5,5'-TETRACARBOXYLIC ACID
Purity: 95.00%
Packaging: 500MG
Price: $952.88
Updated: 2021/12/16

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Biphenyl-3,3',5,5'-tetracarboxylic acid Chemical Properties,Usage,Production

Uses

Selected Applications of MOFs in Sustainable Energy Technologies

General Description

This product has been enhanced for energy efficiency.

Synthesis

109936-20-1

4371-28-2

A mixture of 3,3',5,5'-tetrakis(methoxycarbonyl)biphenyl (12) (0.96 g, 2.5 mmol) was dissolved in water (40 mL) with THF (40 mL) and NaOH (1.6 g, 40 mmol) and reacted at reflux for 1 hour. Subsequently, the organic solvent was evaporated under reduced pressure and the remaining aqueous solution was continued to reflux for 4 hours. After completion of the reaction, the reaction mixture was cooled and acidified with 50% H2SO4 until the precipitation was complete. The precipitate was collected by filtration and dried to give the target product 3,3',5,5'-biphenyltetracarboxylic acid (9) as a white powder in 89% yield. Product melting point > 350°C. 1H-NMR (400 MHz, DMSO-d6): δ = 8.44 (d, 4H, J = 1.5 Hz), 8.53 (t, 2H, J = 1.5 Hz), 13.48 (bs, 4H). 13C-NMR (100 MHz, DMSO-d6): δ = 129.5, 131.4, 132.3 , 139.2, 166.3. MS-EI, m/z (%): 330 (100) [M+], 313 (40), 285 (15), 240 (5).

References

[1] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[2] European Journal of Organic Chemistry, 2007, # 20, p. 3271 - 3276
[3] Patent: EP1972338, 2008, A1. Location in patent: Page/Page column 14
[4] Journal of the Chemical Society, 1923, vol. 123, p. 1045

Biphenyl-3,3',5,5'-tetracarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Biphenyl-3,3',5,5'-tetracarboxylic acid manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: Biphenyl-3,3',5,5'-tetracarboxylic acid 4371-28-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-30

Career Henan Chemical Co

Product: Biphenyl-3,3',5,5'-tetracarboxylic acid 4371-28-2
Price: US $2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2018-12-24

4371-28-2, Biphenyl-3,3',5,5'-tetracarboxylic acidRelated Search:

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