ChemicalBook > CAS DataBase List > 2-(TRIBUTYLSTANNYL)PYRIDINE

2-(TRIBUTYLSTANNYL)PYRIDINE

Product Name
2-(TRIBUTYLSTANNYL)PYRIDINE
CAS No.
17997-47-6
Chemical Name
2-(TRIBUTYLSTANNYL)PYRIDINE
Synonyms
stannyL;tributyl(pyridin-2-yl)stannane;SKL964;2-(Tri-n-butyL;Tributylpyridyltin;2-PYRIDYLTRIBUTYLTIN;TRIBUTYL(2-PYRIDYL)TIN;2-PYRIDYLTRI-N-BUTYLTIN;2-(Tributyltin)pyridine;TRI-N-BUTYL(2-PYRIDYL)TIN
CBNumber
CB5256787
Molecular Formula
C17H31NSn
Formula Weight
368.14
MOL File
17997-47-6.mol
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2-(TRIBUTYLSTANNYL)PYRIDINE Property

Melting point:
132-135 °C
Boiling point:
134 °C
Density 
1.15
refractive index 
1.5130
Flash point:
>110°C
storage temp. 
-20°C
pka
5.21±0.19(Predicted)
form 
liquid
Specific Gravity
1.142
color 
Clear, yellow
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
479329
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
InChIKey
GYUURHMITDQTRU-UHFFFAOYSA-N
CAS DataBase Reference
17997-47-6(CAS DataBase Reference)
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Safety

Hazard Codes 
T,Xi,N
Risk Statements 
21-25-36/38-48/23/25-50/53-10
Safety Statements 
35-36/37/39-45-61-60
RIDADR 
2788
WGK Germany 
3
Hazard Note 
Toxic
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
678333
Product name
2-(Tributylstannyl)pyridine
Purity
85%
Packaging
1g
Price
$72.86
Updated
2025/07/31
Sigma-Aldrich
Product number
678333
Product name
2-(Tributylstannyl)pyridine
Purity
85%
Packaging
5g
Price
$83.5
Updated
2025/07/31
TRC
Product number
T896350
Product name
2-(Tributylstannyl)pyridine
Packaging
100mg
Price
$60
Updated
2021/12/16
SynQuest Laboratories
Product number
9H50-1-Y4
Product name
2-(Tributylstannyl)pyridine
Purity
95%
Packaging
100g
Price
$576
Updated
2021/12/16
AK Scientific
Product number
7773AJ
Product name
2-(Tributylstannyl)pyridine
Packaging
100g
Price
$659
Updated
2021/12/16
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2-(TRIBUTYLSTANNYL)PYRIDINE Chemical Properties,Usage,Production

Uses

Building block in an efficient, palladium-catalyzed synthesis of 2-pyridylazaazulene, a bidentate ligand showing pH and cationic-metal dependent emission spectra.

Synthesis

109-04-6

1461-22-9

17997-47-6

General procedure for the preparation of 2-tributylmethyltin alkylpyridine by the reaction of 2-bromopyridine with tributyltin chloride: butyllithium (2.5 M hexane solution, 6.33 mmol) was added dropwise to a solution of freshly distilled 2-bromopyridine (1 g, 6.33 mmol) in tetrahydrofuran (12 mL) at -78 °C and degassed. After stirring for 30 minutes, tributyltin chloride (1.7 mL, 6.33 mmol) was added to the slightly reddish solution and stirring was continued at -78 °C for 1 hour, then brought to room temperature and stirred for 1 hour. Upon completion of the reaction, the reaction was quenched with saturated ammonium chloride solution and extracted with diethyl ether. The organic phase was washed with saturated sodium chloride solution, dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 20/1) to afford the target product 2-tributylmethylstannylpyridine in 94% yield.1H NMR (CDCl3) δ (ppm): 8.73 (dtd, J = 4.9,1.9,1.0,1H,H6), 7.48 (dt, J = 7.4,1.8,1H,H5). 7.39 (dt, J = 7.4,1.6,1H, H3), 7.10 (ddd, J = 6.9,4.9,1.7,1H, H4), 1.70-1.05 (m, 18H, CH2), 0.85 (t, 9H, J = 7.3, CH3).

References

[1] Patent: US2013/296302, 2013, A1. Location in patent: Paragraph 0592
[2] Patent: US2014/194441, 2014, A1. Location in patent: Paragraph 0455
[3] Inorganic Chemistry, 2013, vol. 52, # 9, p. 5570 - 5580
[4] Patent: US9219237, 2015, B1. Location in patent: Page/Page column 11
[5] European Journal of Inorganic Chemistry, 2002, # 3, p. 573 - 579

2-(TRIBUTYLSTANNYL)PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-(TRIBUTYLSTANNYL)PYRIDINE manufacturers

Sach biotech Co.,Ltd
Product
2-(TRIBUTYLSTANNYL)PYRIDINE 17997-47-6
Price
US $1000.00-800.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
5mt
Release date
2025-06-11
Shanghai UCHEM Inc.
Product
2-Tri-n-butylstannylpyridine 17997-47-6
Price
US $7.00-120.00/g
Min. Order
5g
Purity
0.98
Supply Ability
25kg
Release date
2024-10-25
Career Henan Chemical Co
Product
2-(TRIBUTYLSTANNYL)PYRIDINE 17997-47-6
Price
US $8.80/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
100kg
Release date
2019-07-04

17997-47-6, 2-(TRIBUTYLSTANNYL)PYRIDINERelated Search:

Tributyltin Hydride Triacetin 2-(TRIBUTYLSTANNYL)PYRIDINE 3-FLUORO-2-(TRIBUTYLSTANNYL)PYRIDINE 3-(1,1,1-Tributylstannyl)pyridine, tech,3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE,3-(TRIBUTYLSTANNYL)PYRIDINE 2-METHOXY-6-(TRIBUTYLSTANNYL)PYRIDINE 3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE 4-[6-(TRIBUTYLSTANNYL)-2-PYRIDINYL]MORPHOLINE 5-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE, 96% 4-CHLORO-2-(TRIBUTYLSTANNYL)PYRIDINE 6-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE 4-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE 4-N,N-Dimethylamino-2-(tributylstannyl)-pyridine 2-FLUORO-3-(TRIBUTYLSTANNYL)PYRIDINE 6-FLUORO-2-(TRIBUTYLSTANNYL)PYRIDINE 2-FLUORO-5-METHYL-3-(TRIBUTYLSTANNYL)PYRIDINE 2-METHOXY-3-(TRIBUTYLSTANNYL)PYRIDINE 4-(TRIBUTYLSTANNYL)PYRIDINE

  • TRI-N-BUTYL(2-PYRIDYL)TIN
  • TRIBUTYL(2-PYRIDYL)TIN
  • 2-TRI-N-BUTYLSTANNYLPYRIDINE
  • 2-(Tributylstannyl)pyridine 85%
  • tributyl(pyridin-2-yl)stannane
  • (Pyridin-2-yl)(tributyl)tin, (Pyridin-2-yl)tributylstannane
  • 2-(Tri-n-butyL
  • stannyL
  • 2-(TRIBUTYLSTANNYL)PYRIDINE
  • 2-PYRIDINETRIBUTYLSTANNANE
  • 2-PYRIDYLTRI-N-BUTYLTIN
  • 2-PYRIDYLTRIBUTYLTIN
  • 2-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
  • 2-(Tributylstannyl)pyridine 85-95%
  • 2-TRI-N-BUTYLSTANNYLPYRIDINE, TECH. 80%
  • 2-(1,1,1-Tributylstannyl)pyridine , Tech., Tech
  • 2-(1,1,1-Tributylstannyl)pyridine, TECH
  • Tributylpyridyltin
  • 2-(Tributylstannyl)pyridine 85
  • (2-Pyridyl)tri-N-butyltine
  • 2-PYRIDYLTRI-n-BUTYLTIN 95%
  • 2-(Tributylstannanyl)pyridine
  • 2-(Tributyltin)pyridine
  • 2-Pyridyltributylstannane
  • Tris(but-1-yl)(pyridin-2-yl)tin, (Pyridin-2-yl)tributylstannane
  • Pyridine,2-(tributylstannyl)-
  • 2-Pyridyltributyltin 2-(Tributylstannyl)pyridine
  • 2-(1,1,1-Tributylstannyl)pyridine, technical
  • (2-Pyridinyl)tributylstannane
  • tributyl(2-pyridyl)stannane
  • 2-(TRIBUTYLSTANNYL)PYRIDINE ISO 9001：2015 REACH
  • SKL964
  • (Tributylstannyl)pyridine
  • 2-Tributylstannyl pyridine,97%min
  • 2-(Tributylstannyl)pyridine - [T2792]
  • 17997-47-6
  • C17H31NSn
  • C5H4NSnCH23CH33
  • Typical Metal Compounds
  • Classes of Metal Compounds
  • Sn (Tin) Compounds
  • Organometallic Reagents
  • Organotins
  • Organotin
  • Organometallic Reagents
  • Organotin
  • Organotins
  • Pyridines
  • Organostannes
  • Pyridine
  • Tributylstanny
  • Classes of Metal Compounds
  • Sn (Tin) Compounds
  • Typical Metal Compounds
  • organic tin