TEMPO Methacrylate

ChemicalBook > CAS DataBase List > TEMPO Methacrylate

Product Name: TEMPO Methacrylate
CAS No.: 15051-46-4
Chemical Name: TEMPO Methacrylate
Synonyms: 2,2,6,6-Tetramethyl-4-[(2-methyl-1-oxo-2-propenyl)oxy]-1-piperidinyloxy;PTMA Monomer;TEMPO Methacrylate;TEMPO methacrylate 98%;4-Methacryloyloxy-TEMPO Free Radical;4-Methacryloyloxy-2,2,6,6-tetraMethylpiperidine 1-Oxyl Free Radical;4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine1-OxylFreeRadical>(1-λ1-oxidanyl-2,2,6,6-tetramethylpiperidin-4-yl) 2-methylprop-2-enoate;(1-λsup1sup-oxidanyl-2,2,6,6-tetramethylpiperidin-4-yl)2-methylprop-2-enoate
CBNumber: CB52638246
Molecular Formula: C13H24NO3*
Formula Weight: 242.33456
MOL File: 15051-46-4.mol

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TEMPO Methacrylate Property

Melting point:: 87.0 to 91.0 °C
storage temp.: 2-8°C
form: powder to crystal
color: Light yellow to Yellow to Orange

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Safety

Hazard Codes: Xi
Risk Statements: 43
Safety Statements: 36/37
WGK Germany: 1
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 730297
Product name: TEMPO methacrylate
Purity: 98%
Packaging: 1g
Price: $126
Updated: 2023/06/20

TCI Chemical

Product number: M1531
Product name: 4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $109
Updated: 2024/03/01

TCI Chemical

Product number: M1531
Product name: 4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $376
Updated: 2024/03/01

TRC

Product number: T889675
Product name: 2,2,6,6-Tetramethyl-4-[(2-methyl-1-oxo-2-propenyl)oxy]-1-piperidinyloxy
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: T889675
Product name: 2,2,6,6-Tetramethyl-4-[(2-methyl-1-oxo-2-propenyl)oxy]-1-piperidinyloxy
Packaging: 50mg
Price: $45
Updated: 2021/12/16

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TEMPO Methacrylate Chemical Properties,Usage,Production

Chemical Properties

White to orange powder

Uses

2,2,6,6-Tetramethyl-4-[(2-methyl-1-oxo-2-propenyl)oxy]-1-piperidinyloxy is used in the synthesis of Poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate). Poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) has application in batteries and solar cells.

Uses

TEMPO methacrylate (4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl) may be employed as counter radical for polymerization of styrene.

Definition

ChEBI: 4-methacryloyloxy-TEMPO is a member of the class of piperidines that is TEMPO carrying a methacryloyloxy group at position 4. It has a role as a polymerisation monomer. It is a member of aminoxyls, a member of piperidines and an enoate ester. It is functionally related to a TEMPO.

General Description

TEMPO methacrylate (4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl) undergoes anionic dispersion polymerization to afford nanometer-sized polymer particles bearing 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) radicals.

TEMPO Methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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15051-46-4, TEMPO MethacrylateRelated Search:

SODIUM METHACRYLATE 2-[3-(2H-Benzotriazol-2-yl)-4-hydroxyphenyl]ethyl methacrylate POLY(2-HYDROXYETHYL METHACRYLATE) 2-Hydroxyethyl methacrylate Methyl propiolate Methyl methacrylate Glycidyl methacrylate 2-Methoxyethyl acrylate

TEMPO methacrylate 98%

TEMPO Methacrylate

4-Methacryloyloxy-2,2,6,6-tetraMethylpiperidine 1-Oxyl Free Radical

2,2,6,6-Tetramethyl-4-[(2-methyl-1-oxo-2-propenyl)oxy]-1-piperidinyloxy

4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine1-OxylFreeRadical&gt

4-Methacryloyloxy-TEMPO Free Radical

PTMA Monomer

(1-λ1-oxidanyl-2,2,6,6-tetramethylpiperidin-4-yl) 2-methylprop-2-enoate

(1-λsup1sup-oxidanyl-2,2,6,6-tetramethylpiperidin-4-yl)2-methylprop-2-enoate

15051-46-4

C13H22NO3