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ETHYL 3-PHENYLGLYCIDATE

Product Name
ETHYL 3-PHENYLGLYCIDATE
CAS No.
121-39-1
Chemical Name
ETHYL 3-PHENYLGLYCIDATE
Synonyms
FEMA 2454;ethyl3-phenyloxirane;ETHYL PHENYLGLYCIDATE;strawberry glycidate 2;ethyl3-phenyloxirane-2-;ETHYL 3-PHENYLGLYCIDATE;ETHYL PHENYLGLYCIDATE FCC;Ethyl 3-Phenylglycidate ETHYL A B-EPOXYHYDROCINNAMATE;ethyl2,3-epoxy-3-phenylpropion
CBNumber
CB5292099
Molecular Formula
C11H12O3
Formula Weight
192.21
MOL File
121-39-1.mol
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ETHYL 3-PHENYLGLYCIDATE Property

Melting point:
17-18 °C
Boiling point:
96 °C/0.5 mmHg (lit.)
Density 
1.102 g/mL at 25 °C (lit.)
vapor pressure 
0.12Pa at 24℃
FEMA 
2454 | ETHYL 3-PHENYLGLYCIDATE
refractive index 
n20/D 1.518(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Insoluble in water
form 
Liquid
color 
Clear colorless to yellow
Odor
at 100.00 %. sweet strawberry berry floral tropical
Odor Type
fruity
Water Solubility 
748.4mg/L at 24℃
Sensitive 
Moisture Sensitive
JECFA Number
1576
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
LogP
2.4 at 20℃
CAS DataBase Reference
121-39-1(CAS DataBase Reference)
EPA Substance Registry System
Ethyl 3-phenylglycidate (121-39-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
23-24/25
WGK Germany 
2
RTECS 
MB4970000
TSCA 
Yes
HS Code 
29189990
Hazardous Substances Data
121-39-1(Hazardous Substances Data)
Toxicity
The acute oral LD50 value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Shelanski, 1973a).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W245402
Product name
Ethyl 3-phenylglycidate
Purity
mixture of
Packaging
sample
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
291404
Product name
Ethyl 3-phenylglycidate
Purity
technical grade, 92%, mixture of
Packaging
100ml
Price
$49
Updated
2023/06/20
TCI Chemical
Product number
E0798
Product name
Ethyl 3-Phenylglycidate (cis- and trans- mixture)
Purity
>90.0%(GC)
Packaging
25g
Price
$21
Updated
2024/03/01
Alfa Aesar
Product number
B22990
Product name
Ethyl 3-phenylglycidate, cis + trans, 90+%
Packaging
50ml
Price
$28.65
Updated
2024/03/01
Alfa Aesar
Product number
B22990
Product name
Ethyl 3-phenylglycidate, cis + trans, 90+%
Packaging
250ml
Price
$70.65
Updated
2024/03/01
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ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Usage,Production

Chemical Properties

pale yellow liquid

Chemical Properties

Ethyl 3-Phenylglycidate is a colorless liquid with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating harmonic, fruity notes in household and fine fragrances.

Chemical Properties

Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.

Occurrence

Apparently has not been reported to occur in nature.

Uses

Ethyl 3-Phenyloxirane-2-carboxylate is used in preparation method of early-strength viscosity-breaking Polycarboxylate water reducer containing three viscosity-breaking group and used as concrete additive.

Definition

ChEBI: Ethyl phenylglycidate is an epoxide and a carboxylic acid.

Preparation

Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.

Aroma threshold values

Detection: 8.5 ppm

Taste threshold values

Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.

Synthesis Reference(s)

Synthetic Communications, 12, p. 355, 1982 DOI: 10.1080/00397918209408010

General Description

Clear pale yellow or yellow liquid.

Air & Water Reactions

Slightly water soluble.

Reactivity Profile

Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Fire Hazard

ETHYL 3-PHENYLGLYCIDATE is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL 3-PHENYLGLYCIDATE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
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96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
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sales8178@energy-chemical.com
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Adamas Reagent, Ltd.
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400-6009262 16621234537
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021-64823266
Email
zhangsn@titansci.com
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China
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jiliang chemicals
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21-62165282 15801962796;
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021 61153784
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bidingchem@163.com
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China
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Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
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3007715519@qq.com
Country
China
ProdList
18736
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Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12990
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RYSS TECH LTD
Tel
400-188-0725 +86 21 34310725 13611771617
Fax
+86 21 34311076
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China
ProdList
2002
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View Lastest Price from ETHYL 3-PHENYLGLYCIDATE manufacturers

Hebei Mojin Biotechnology Co., Ltd
Product
ETHYL 3-PHENYLGLYCIDATE 121-39-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-27
Hebei Guanlang Biotechnology Co., Ltd.
Product
ETHYL 3-PHENYLGLYCIDATE 121-39-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-08-02
Shaanxi Dideu Medichem Co. Ltd
Product
Ethyl 3-Phenylglycidate (cis- and trans- Mixture) 121-39-1
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50 tons
Release date
2020-01-19

121-39-1, ETHYL 3-PHENYLGLYCIDATERelated Search:


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  • strawberry glycidate 2
  • 121-39-1
  • C11H12O3C11H12O3C11H12O3C11H12O3C11H12O3
  • Oxygen Compounds
  • Organic Building Blocks
  • Epoxides
  • Building Blocks
  • Alphabetical Listings
  • E-F
  • Flavors and Fragrances
  • Epoxides
  • Organic Building Blocks
  • Oxygen Compounds
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  • Chemical Synthesis