ETHYL 3-PHENYLGLYCIDATE
- Product Name
- ETHYL 3-PHENYLGLYCIDATE
- CAS No.
- 121-39-1
- Chemical Name
- ETHYL 3-PHENYLGLYCIDATE
- Synonyms
- FEMA 2454;ethyl3-phenyloxirane;ETHYL PHENYLGLYCIDATE;strawberry glycidate 2;ethyl3-phenyloxirane-2-;ETHYL 3-PHENYLGLYCIDATE;ETHYL PHENYLGLYCIDATE FCC;Ethyl 3-Phenylglycidate ETHYL A B-EPOXYHYDROCINNAMATE;ethyl2,3-epoxy-3-phenylpropion
- CBNumber
- CB5292099
- Molecular Formula
- C11H12O3
- Formula Weight
- 192.21
- MOL File
- 121-39-1.mol
ETHYL 3-PHENYLGLYCIDATE Property
- Melting point:
- 17-18 °C
- Boiling point:
- 96 °C/0.5 mmHg (lit.)
- Density
- 1.102 g/mL at 25 °C (lit.)
- vapor pressure
- 0.12Pa at 24℃
- FEMA
- 2454 | ETHYL 3-PHENYLGLYCIDATE
- refractive index
- n20/D 1.518(lit.)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- Insoluble in water
- form
- Liquid
- color
- Clear colorless to yellow
- Odor
- at 100.00 %. sweet strawberry berry floral tropical
- Odor Type
- fruity
- Water Solubility
- 748.4mg/L at 24℃
- Sensitive
- Moisture Sensitive
- JECFA Number
- 1576
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 2.4 at 20℃
- CAS DataBase Reference
- 121-39-1(CAS DataBase Reference)
- EPA Substance Registry System
- Ethyl 3-phenylglycidate (121-39-1)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 23-24/25
- WGK Germany
- 2
- RTECS
- MB4970000
- TSCA
- Yes
- HS Code
- 29189990
- Hazardous Substances Data
- 121-39-1(Hazardous Substances Data)
- Toxicity
- The acute oral LD50 value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Shelanski, 1973a).
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H303May be harmfulif swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- W245402
- Product name
- Ethyl 3-phenylglycidate
- Purity
- mixture of
- Packaging
- sample
- Price
- $54.6
- Updated
- 2024/03/01
- Product number
- 291404
- Product name
- Ethyl 3-phenylglycidate
- Purity
- technical grade, 92%, mixture of
- Packaging
- 100ml
- Price
- $49
- Updated
- 2023/06/20
- Product number
- E0798
- Product name
- Ethyl 3-Phenylglycidate (cis- and trans- mixture)
- Purity
- >90.0%(GC)
- Packaging
- 25g
- Price
- $21
- Updated
- 2024/03/01
- Product number
- B22990
- Product name
- Ethyl 3-phenylglycidate, cis + trans, 90+%
- Packaging
- 50ml
- Price
- $28.65
- Updated
- 2024/03/01
- Product number
- B22990
- Product name
- Ethyl 3-phenylglycidate, cis + trans, 90+%
- Packaging
- 250ml
- Price
- $70.65
- Updated
- 2024/03/01
ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Usage,Production
Chemical Properties
pale yellow liquid
Chemical Properties
Ethyl 3-Phenylglycidate is a colorless liquid
with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation
of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens
reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating
harmonic, fruity notes in household and fine fragrances.
Chemical Properties
Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.
Occurrence
Apparently has not been reported to occur in nature.
Uses
Ethyl 3-Phenyloxirane-2-carboxylate is used in preparation method of early-strength viscosity-breaking Polycarboxylate water reducer containing three viscosity-breaking group and used as concrete additive.
Definition
ChEBI: Ethyl phenylglycidate is an epoxide and a carboxylic acid.
Preparation
Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.
Aroma threshold values
Detection: 8.5 ppm
Taste threshold values
Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.
Synthesis Reference(s)
Synthetic Communications, 12, p. 355, 1982 DOI: 10.1080/00397918209408010
General Description
Clear pale yellow or yellow liquid.
Air & Water Reactions
Slightly water soluble.
Reactivity Profile
Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Fire Hazard
ETHYL 3-PHENYLGLYCIDATE is probably combustible.
Flammability and Explosibility
Non flammable
Safety Profile
Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ETHYL 3-PHENYLGLYCIDATE manufacturers
- Product
- ETHYL 3-PHENYLGLYCIDATE 121-39-1
- Price
- US $45.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2024-12-19
- Product
- ETHYL 3-PHENYLGLYCIDATE 121-39-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-25
- Product
- ETHYL 3-PHENYLGLYCIDATE 121-39-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-06-27