ETHYL 3-PHENYLGLYCIDATE

ChemicalBook > CAS DataBase List > ETHYL 3-PHENYLGLYCIDATE

ETHYL 3-PHENYLGLYCIDATE

Product Name: ETHYL 3-PHENYLGLYCIDATE
CAS No.: 121-39-1
Chemical Name: ETHYL 3-PHENYLGLYCIDATE
Synonyms: FEMA 2454;ethyl3-phenyloxirane;ETHYL PHENYLGLYCIDATE;strawberry glycidate 2;ethyl3-phenyloxirane-2-;ETHYL 3-PHENYLGLYCIDATE;ETHYL PHENYLGLYCIDATE FCC;Ethyl 3-Phenylglycidate ETHYL A B-EPOXYHYDROCINNAMATE;ethyl2,3-epoxy-3-phenylpropion
CBNumber: CB5292099
Molecular Formula: C11H12O3
Formula Weight: 192.21
MOL File: 121-39-1.mol

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ETHYL 3-PHENYLGLYCIDATE Property

Melting point:: 17-18 °C
Boiling point:: 96 °C/0.5 mmHg (lit.)
Density: 1.102 g/mL at 25 °C (lit.)
vapor pressure: 0.12Pa at 24℃
FEMA: 2454 | ETHYL 3-PHENYLGLYCIDATE
refractive index: n20/D 1.518(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Insoluble in water
form: Liquid
color: Clear colorless to yellow
Odor: at 100.00 %. sweet strawberry berry floral tropical
Odor Type: fruity
Water Solubility: 748.4mg/L at 24℃
Sensitive: Moisture Sensitive
JECFA Number: 1576
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
LogP: 2.4 at 20℃
CAS DataBase Reference: 121-39-1(CAS DataBase Reference)
EPA Substance Registry System: Ethyl 3-phenylglycidate (121-39-1)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 23-24/25
WGK Germany: 2
RTECS: MB4970000
TSCA: Yes
HS Code: 29189990
Hazardous Substances Data: 121-39-1(Hazardous Substances Data)
Toxicity: The acute oral LD₅₀ value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD₅₀ value in rabbits was reported as > 5 g/kg (Shelanski, 1973a).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W245402
Product name: Ethyl 3-phenylglycidate
Purity: mixture of
Packaging: sample
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 291404
Product name: Ethyl 3-phenylglycidate
Purity: technical grade, 92%, mixture of
Packaging: 100ml
Price: $49
Updated: 2023/06/20

TCI Chemical

Product number: E0798
Product name: Ethyl 3-Phenylglycidate (cis- and trans- mixture)
Purity: >90.0%(GC)
Packaging: 25g
Price: $21
Updated: 2024/03/01

Alfa Aesar

Product number: B22990
Product name: Ethyl 3-phenylglycidate, cis + trans, 90+%
Packaging: 50ml
Price: $28.65
Updated: 2024/03/01

Alfa Aesar

Product number: B22990
Product name: Ethyl 3-phenylglycidate, cis + trans, 90+%
Packaging: 250ml
Price: $70.65
Updated: 2024/03/01

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ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Usage,Production

Chemical Properties

pale yellow liquid

Chemical Properties

Ethyl 3-Phenylglycidate is a colorless liquid with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating harmonic, fruity notes in household and fine fragrances.

Chemical Properties

Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.

Occurrence

Apparently has not been reported to occur in nature.

Uses

Ethyl 3-Phenyloxirane-2-carboxylate is used in preparation method of early-strength viscosity-breaking Polycarboxylate water reducer containing three viscosity-breaking group and used as concrete additive.

Definition

ChEBI: Ethyl phenylglycidate is an epoxide and a carboxylic acid.

Preparation

Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.

Aroma threshold values

Detection: 8.5 ppm

Taste threshold values

Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.

Synthesis Reference(s)

Synthetic Communications, 12, p. 355, 1982 DOI: 10.1080/00397918209408010

General Description

Clear pale yellow or yellow liquid.

Air & Water Reactions

Slightly water soluble.

Reactivity Profile

Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Fire Hazard

ETHYL 3-PHENYLGLYCIDATE is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials

Raw materials

Sodium anthraquinone-2-sulfonate Ethanol Ethyl formate Propionic acid Toluene Sodium Triethylamine Benzaldehyde Acetic acid Iodoethane Ethyl chloroacetate

Preparation Products

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ETHYL 3-PHENYLGLYCIDATE Suppliers

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View Lastest Price from ETHYL 3-PHENYLGLYCIDATE manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: ETHYL 3-PHENYLGLYCIDATE 121-39-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-06-27

Hebei Guanlang Biotechnology Co., Ltd.

Product: ETHYL 3-PHENYLGLYCIDATE 121-39-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-08-02

Shaanxi Dideu Medichem Co. Ltd

Product: Ethyl 3-Phenylglycidate (cis- and trans- Mixture) 121-39-1
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50 tons
Release date: 2020-01-19

121-39-1, ETHYL 3-PHENYLGLYCIDATERelated Search:

Glycidol (2R,3R)-3-PHENYLGLYCIDOL DL-GLYCERIC ACID Ethyl propionate ETHYL 3-PHENYLGLYCIDATE Ethyl 3-methyl-3-phenylglycidate ETHYL 3-(4-ISOBUTYLPHENYL)-3-METHYL GLYCIDATE ethyl-2-phenylglycidate ETHYL-3,4-DICHLOROPHENYL GLYCIDATE 3-(3-CYANO-PHENYL)-3-METHYL-OXIRANE-2-CARBOXYLIC ACID ETHYL ESTER ETHYL-3-PHENYLGLYCIDATE, CIS TRANS 92% AURORA KA-2972 ETHYL-2,4-DICHLOROPHENYL GLYCIDATE TOSLAB 22668 (2R,3S)-3-(4-CHLORO-PHENYL)-2-METHYL-OXIRANE-2-CARBOXYLIC ACID ETHYL ESTER ETHYL 3-(6-METHOXY-2-NAPHTHYL)-3-METHYL GLYCIDATE AURORA KA-2973

(2R,3R)-3-Phenyloxirane-2-carboxylic acid ethyl ester

3-Phenyloxirane-2-carboxylic acid ethyl ester

Ethyl 3-Phenylglycidate (cis- and trans- mixture)

(2S,3S)-3-Phenyloxirane-2-carboxylic acid ethyl ester

Ethyl 3-phenylglycidate,98%,mixture of cis and trans

Ethyl 3-phenylglycidate,90%,mixture of cis and trans

ethyl2,3-epoxy-3-phenylpropion

Ethyl 2,3-epoxy-3-phenylpropionate

Ethyl 3-phenyl-2-oxiranecarboxylate

Ethyl alpha,beta-epoxy-alpha-phenylpropionate

Ethyl alpha,beta-epoxyhydrocinnamate

ethyl2,3-epoxy-3-phenylpropionate

ethyl3-phenylglycidate,mixtureofcisandtrans

ethyl3-phenyloxirane

ethyl3-phenyloxirane-2-

ethyl3-phenyloxirane-2-carboxylate

ethyl3-phenyloxiranecarboxylate

ethylalpha,beta-epoxy-alpha-phenylpropionate

ethylalpha,beta-epoxyhydrocinnamate

Oxiranecarboxylicacid,3-phenyl-,ethylester

3-Phenylglycidic Acid Ethyl Ester Ethyl 3-Phenyloxiranecarboxylate

Ethyl 3-Phenylglycidate&nbsp

Ethyl 3-Phenylglycidate (<i>cis</i>- and <i>trans</i>- mixture)

3-phenyl-glycidicaciethylester

3-phenyl-oxiranecarboxylicaciethylester

GLYCIDIC ACID, 3-PHENYL:ETHYL ESTER

ETHYL 3-PHENYLGLYCIDATE

FEMA 2454

ETHYL PHENYLGLYCIDATE

ETHYL A B-EPOXYHYDROCINNAMATE

ETHYL3-PHENYLGLYCIDATE,TECHNICAL

23EPOXY3PHENYLPROPIONICACIDETHYLESTERCISTRANS

Ethyl-3-phenyloxiran-2-carboxylat

Ethyl 3-phenylglycidate, cis + trans, 90+%

ETHYL PHENYLGLYCIDATE FCC

3-PHENYLGLYCIDIC ACID ETHYL ESTER

3-PHENYLOXIRANECARBOXYLIC ACID ETHYL ESTER

ETHYL 3-PHENYLGLYCIDATE 92+% &

ETHYL 3-PHENYLGLYCIDATE, TECH., 92%, MIX TURE OF CIS AND TRANS

Ethyl 3-phenylglycidate, cis + trans, 95%

Ethyl3-Phenylglycidate(cis-andtrans-mixture)&gt

2-Oxiranecarboxylic acid, 3-phenyl-, ethyl ester

ETHYL 3-PHENYLGLYCIDATE USP/EP/BP

strawberry glycidate 2

121-39-1

C11H12O3C11H12O3C11H12O3C11H12O3C11H12O3

Oxygen Compounds

Organic Building Blocks

Epoxides

Building Blocks

Alphabetical Listings

E-F

Flavors and Fragrances

Epoxides

Organic Building Blocks

Oxygen Compounds

Building Blocks

Chemical Synthesis