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P-METHYLPHENYLACETALDEHYDE

Product Name
P-METHYLPHENYLACETALDEHYDE
CAS No.
104-09-6
Chemical Name
P-METHYLPHENYLACETALDEHYDE
Synonyms
FEMA 3071;Tolylacetaldehyd;p-Tolylacetaldehyd;4-tolyacetaldehyde;lilac acetaldehyde;P-TOLYLACETALDEHYDE;4-TOLYLACETALDEHYDE;p-Toly-acetoaldehyde;2-P-TOLYLACETALDEHYDE;PARA-TOLUACETALDEHYDE
CBNumber
CB5299119
Molecular Formula
C9H10O
Formula Weight
134.18
MOL File
104-09-6.mol
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P-METHYLPHENYLACETALDEHYDE Property

Melting point:
40°C
Boiling point:
221.5°C (estimate)
Density 
1.0052
refractive index 
1.5255 (estimate)
FEMA 
3071 | P-TOLYLACETALDEHYDE
storage temp. 
2-8°C
Odor
at 10.00 % in dipropylene glycol. fresh sweet green cortex lilac narcissus nutty phenolic fruity cherry
Odor Type
green
JECFA Number
1023
LogP
2.24
EPA Substance Registry System
Benzeneacetaldehyde, 4-methyl- (104-09-6)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Rieke Metals
Product number
AL0342
Product name
P-Tolylacetaldehyde
Packaging
1g
Price
$160
Updated
2021/12/16
Matrix Scientific
Product number
081611
Product name
(4-Methylphenyl)acetaldehyde
Purity
95%
Packaging
1g
Price
$268
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0012355
Product name
4-TOLYLACETALDEHYDE
Purity
95.00%
Packaging
1G
Price
$776.16
Updated
2021/12/16
Alichem
Product number
104096
Product name
2-(p-Tolyl)acetaldehyde
Packaging
1g
Price
$199.68
Updated
2021/12/16
AHH
Product number
MT-18513
Product name
p-Methylphenylacetaldehyde
Purity
98%
Packaging
50g
Price
$420
Updated
2021/12/16
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P-METHYLPHENYLACETALDEHYDE Chemical Properties,Usage,Production

Chemical Properties

p-Tolylacetaldehyde has a powerful and refreshing green-fruity, "forest-like", sweet, floral odor of moderate tenacity. The undiluted material has a rather sharp initial odor, but sweetness predominates in the diluted product. The taste is sweet-fruity, mildly green at concentrations near 10 ppm.

Uses

4-Methylphenylacetaldehyde (p-Tolylacetaldehyde) is used in perfumes, e.g., in soap, in tobacco fragrances, in the preparation of pesticides, etc.

Preparation

From p-methylbenzaldehyde; also from p-methylbenzyl chloride and hexamethylene tetramine.The methods of preparation correspond closely to those of phenylacetaldehyde. Thus, the compound can be prepared by glycidic ester synthesis from 4-methylbenzaldehyde and chloroacetate ester, by hydroformylation of 4-methylbenzylhalide with Co2(CO)8Na2CO3 in acetonitrile, or by oxidation of 4-methylstyrene.

Production Methods

p-Tolylacetaldehyde can be produced 1) from para-Methylbenzaldehyde via Darzen's reaction. 2) from para-Methylbenzy lchloride plus Hexamethyiene tetramine.

Definition

ChEBI: (4-Methylphenyl)acetaldehyde is a member of phenylacetaldehydes.

Taste threshold values

Taste characteristics at 10 ppm: sweet, fruity cherry with spicy an nutty nuances.

Synthesis Reference(s)

Synthetic Communications, 17, p. 677, 1987 DOI: 10.1080/00397918708075741

P-METHYLPHENYLACETALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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104-09-6, P-METHYLPHENYLACETALDEHYDERelated Search:

Ibuprofen 4-METHYLPHENYLACETONE 5-ETHYL-5-P-TOLYLBARBITURIC ACID 99+% 5-(4-METHYLPHENYL)-5-PHENYLHYDANTOIN 2,5-DIHYDROXY-1,4-BENZENEDIACETIC ACID 4-(BROMOMETHYL)PHENYLACETIC ACID 4-(TRIFLUOROMETHYL)MANDELIC ACID MESITYLACETIC ACID 4-Methylphenylacetic acid 4,4'-DIMETHYLBENZIL 1,4-Phenylenediacetic acid ETHYL P-TOLYLACETATE 4-(Trifluoromethyl)phenylacetic acid 4-Biphenylacetic acid 3,4-xylylacetaldehyde 2,4-dimethylphenylacetaldehyde A-METHYLPHENYLACETALDEHYDE,METHYLPHENYLACETALDEHYDE,alpha-Methylphenylacetaldehyde 3-(2-FURYL)-2-PHENYLPROPENAL

  • (4-Methylphenyl)acetaldehyde
  • (4-methyl-phenyl)-acetaldehyde
  • 4-methyl-benzeneacetaldehyd
  • 4-methyl-Benzeneacetaldehyde
  • 4-methyl-phenyl-acetaldehyde
  • P-TOLYLACETALDEHYDE
  • benzeneacetaldehyde,-methyl-
  • 4-TOLYLACETALDEHYDE
  • 2-P-TOLYLACETALDEHYDE
  • FEMA 3071
  • P-METHYLPHENYLACETALDEHYDE
  • p-tolylacetaldehyde50%soln.inphenylethylalcohol
  • Benzeneacetaldehyde, 4-methyl-
  • p-Toly-acetoaldehyde
  • PARA-TOLUACETALDEHYDE
  • PARA-TOLYLACETALDEHYDE
  • p-Tolylacetaldehyd
  • Tolylacetaldehyd
  • 4-METHYL-BENZENEACETALDEHYDE,98.5%, GLC ()
  • 4-tolyacetaldehyde
  • p-TOLYL ACETALDEHYDE 50% IN P.E.A.
  • P-TOLYLACETALDEHYDE 50% IN D.P.G.
  • 2-(4-Methylphenyl)acetaldehyde
  • 2-(4-methylphenyl)ethanal
  • P-METHYLPHENYLACETALDEHYDE USP/EP/BP
  • lilac acetaldehyde
  • 104-09-6
  • 0104-09-06
  • CH3C6H5CH2CHO
  • CH3C6H4CH2CHO
  • Aromatic Aldehydes & Derivatives (substituted)
  • Aldehydes
  • Phenyls & Phenyl-Het
  • Benzene derivatives