4-N-HEXYLBENZENEBORONIC ACID
- Product Name
- 4-N-HEXYLBENZENEBORONIC ACID
- CAS No.
- 105365-50-2
- Chemical Name
- 4-N-HEXYLBENZENEBORONIC ACID
- Synonyms
- AKOS BRN-0153;4-Hexylphenylboronicaci;4-hexylphenylboronic acid;4-HEXYLBENZENEBORONIC ACID;4-N-HEXYLPHENYLBORONIC ACID;4-N-HEXYLBENZENEBORONIC ACID;1-Borono-4-(hex-1-yl)benzene;B-(4-Hexylphenyl)boronic acid;4-(Hex-1-yl)benzeneboronic acid;Boronic acid,B-(4-hexylphenyl)-
- CBNumber
- CB5309126
- Molecular Formula
- C12H19BO2
- Formula Weight
- 206.09
- MOL File
- 105365-50-2.mol
4-N-HEXYLBENZENEBORONIC ACID Property
- Melting point:
- 81-84°
- Boiling point:
- 342.6±35.0 °C(Predicted)
- Density
- 1.00±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- soluble in Methanol
- pka
- 8.73±0.16(Predicted)
- form
- Solid
- color
- White to Almost white
Safety
- Hazard Codes
- Xi
- Hazard Note
- Irritant
- HS Code
- 2931900090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- H1489
- Product name
- 4-Hexylphenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $73
- Updated
- 2025/07/31
- Product number
- H1489
- Product name
- 4-Hexylphenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $241
- Updated
- 2025/07/31
- Product number
- H297403
- Product name
- 4-HexylphenylboronicAcid
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- H297403
- Product name
- 4-HexylphenylboronicAcid
- Packaging
- 250mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- X1301
- Product name
- 4-n-Hexylphenylboronicacid
- Packaging
- 1g
- Price
- $61
- Updated
- 2021/12/16
4-N-HEXYLBENZENEBORONIC ACID Chemical Properties,Usage,Production
Synthesis
23703-22-2
105365-50-2
A n-hexane solution of n-butyllithium (1.67 M, 131 mL, 218 mmol) was slowly added dropwise to a solution of anhydrous THF (300 mL) of 1-bromo-4-hexylbenzene (50.0 g, 207 mmol) under nitrogen protection, keeping the reaction temperature at -75 °C. After the dropwise addition was completed, stirring of the reaction mixture was continued for 2 hours. Subsequently, trimethoxyborane (64.6 g, 622 mmol) was slowly added dropwise to the reaction system, and after completion of the dropwise addition, stirring was continued for 2 hours. At the end of the reaction, 1N dilute hydrochloric acid (300 mL) was slowly added to the reaction system and stirred for 30 minutes. The reaction mixture was extracted with ethyl acetate, the organic layer was washed with saturated aqueous sodium chloride solution, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give the intermediate 4-N-hexylphenylboronic acid (42.5 g, 99% yield) as a colorless solid.
References
[1] Patent: EP2695882, 2014, A1. Location in patent: Paragraph 0377
[2] Organic Letters, 2006, vol. 8, # 18, p. 4071 - 4074
[3] Patent: US2011/281822, 2011, A1. Location in patent: Page/Page column 7-8
4-N-HEXYLBENZENEBORONIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
4-N-HEXYLBENZENEBORONIC ACID Suppliers
- Tel
- --
- Fax
- --
- info@pschemicals.com
- Country
- The Netherlands
- ProdList
- 2724
- Advantage
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View Lastest Price from 4-N-HEXYLBENZENEBORONIC ACID manufacturers
- Product
- 4-N-HEXYLBENZENEBORONIC ACID 105365-50-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2019-12-25