9-Bromoanthracene

ChemicalBook > CAS DataBase List > 9-Bromoanthracene

Product Name: 9-Bromoanthracene
CAS No.: 1564-64-3
Chemical Name: 9-Bromoanthracene
Synonyms: 9-BROMOANTHRENE;9-BROMOANTHRACENE;9-Anthryl bromide;MS-BROMOANTHRACENE;10-Bromoanthracene;9-Bromo anthrecene;TIMTEC-BB SBB007978;RARECHEM AQ BD AN02;9-Anthracyl bromide;Anthracene, 9-bromo-
CBNumber: CB5319891
Molecular Formula: C14H9Br
Formula Weight: 257.13
MOL File: 1564-64-3.mol

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9-Bromoanthracene Property

Melting point:: 97-100 °C (lit.)
Boiling point:: 303.85°C (rough estimate)
Density: 1.4251 (rough estimate)
refractive index: 1.6404 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form: Powder
color: Yellow
Water Solubility: Insoluble in water.
BRN: 1869747
InChIKey: ZIRVQSRSPDUEOJ-UHFFFAOYSA-N
CAS DataBase Reference: 1564-64-3(CAS DataBase Reference)
NIST Chemistry Reference: 9-Bromoanthracene(1564-64-3)

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Safety

Hazard Codes: Xi
Safety Statements: 22-24/25
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29049090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H341Suspected of causing genetic defects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: B56609
Product name: 9-Bromoanthracene
Purity: 94%
Packaging: 5g
Price: $79.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: B56609
Product name: 9-Bromoanthracene
Purity: 94%
Packaging: 25g
Price: $345
Updated: 2024/03/01

TCI Chemical

Product number: B0872
Product name: 9-Bromoanthracene
Purity: >95.0%(GC)
Packaging: 5g
Price: $23
Updated: 2024/03/01

TCI Chemical

Product number: B0872
Product name: 9-Bromoanthracene
Purity: >95.0%(GC)
Packaging: 25g
Price: $76
Updated: 2024/03/01

Alfa Aesar

Product number: L06733
Product name: 9-Bromoanthracene, 96%
Packaging: 5g
Price: $57.65
Updated: 2024/03/01

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9-Bromoanthracene Chemical Properties,Usage,Production

Description

9-bromoanthracene is a kind of bromine-derived anthracene. It is known to be able to reversibly photodimerize in a head-to tail fashion upon irradiation by long-wavelength ultraviolet light. The photodimers of 9-bromoanthracene are suitable to be used as alkyl halide initiators in the atom transfer radical polymerization (ATRP) reactions. It is also used as the intermediate for the preparation of the 9-substitued form of the polycyclic aromatic hydrocarbon (PAH) anthracene.

Chemical Properties

white to light yellow crystal powder. boiling point 190°C (0.16kPa, sublimation), relative density 1.409. soluble in acetic acid; carbon disulfide.

Uses

9-Bromoanthracene acts as an intermediate in the preparation of 9-substituted derivative of the polycyclic aromatic hydrocarbon (PAH) anthracene.

Preparation

Anthracene (5 g, 28.05 mmol) was dissolved in CHCl3. Then N-bromosuccinimide (NBS，4.99 g, 28.05 mmol) was added in batches away from light, and the reaction solution was continuously stirred for 12 h. The resulting mixture was stirred for another 30 min with appropriate water, and extracted with CH2Cl2. The CH2Cl2 solution was dried over anhydrous MgSO4. After removing CH2Cl2 solvent, the residue was recrystallized from anhydrous ethanol to give 4.78 g (66.3 %) of a green-yellow needle solid. 1H NMR (500 MHz, CDCl3) δ 8.55 (d, J = 8.9 Hz, 2H), 8.48 (s, 1H), 8.03 (d, J = 8.4 Hz, 2H), 7.67 – 7.60 (m, 2H), 7.56 – 7.51 (m, 2H). EI-MS (m/z): Calculated for C14H9Br: 257.13. Found [M+ ]: 255.96.

Synthesis of 9-bromoanthracene

Synthesis Reference(s)

The Journal of Organic Chemistry, 57, p. 2740, 1992 DOI: 10.1021/jo00035a038

Purification Methods

Crystallise 9-bromoanthracene from MeOH or EtOH followed by sublimation in vacuo. [Masnori et al. J Am Chem Soc 108 126 1986, Beilstein 5 IV 2295.]

References

Cohen, Nicole A., et al. Macromolecular Chemistry and Physics 210.3 ‐4 (2009): 263-268.
Xu, Xiaoming, Wenzhe Lu, and Richard B. Cole. Analytical chemistry 68.23 (1996): 4244-4253.
Dang, Hung, and Miguel A. Garcia-Garibay. Journal of the American Chemical Society 123.2 (2001): 355-356.

9-Bromoanthracene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 9-Bromoanthracene manufacturers

Shanghai Qyubiotech Co., Ltd.

Product: 9-Bromoanthracene 1564-64-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%+
Supply Ability: 10000kgs per Month
Release date: 2022-10-11

Henan Fengda Chemical Co., Ltd

Product: 9-Bromoanthracene 1564-64-3
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

Hebei Duling International Trade Co. LTD

Product: 9-Bromoanthracene 1564-64-3
Price: US $30.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100 tons
Release date: 2022-11-02

1564-64-3, 9-BromoanthraceneRelated Search:

9-(bromomethyl)anthracene ANTHRACENE, 9-BROMO-10-(1-NAPHTHALENYL)- 9-Bromo-10-(2-naphthyl)anthracene 10,10'-Dibromo-9,9'-bianthryl 9-Bromoanthracene 9,10-Dibromoanthracene 10-BROMOANTHRACENE-9-BORONIC ACID 7-BROMOBENZ[A]ANTHRACENE 2-BROMOANTHRACENE 1,5-DIBROMOANTHRAQUINONE 2,6-Dibromoanthraquinone 2-Bromoanthraquinone 1-amino-2-bromo-4-(phenylamino)anthraquinone Bromaminic acid 1-Methylamino-4-bromo anthraquinone 1-bromoanthracene-9,10-dione 2,6-DIBROMOANTHRACENE 1-amino-4-bromoanthracene-9,10-dione

9-Anthracenyl bromide

Anthracene, 9-bromo-

9-Anthracyl bromide

50KG/100KG(CIF INDIA COURIER/AIR)

RARECHEM AQ BD AN02

MS-BROMOANTHRACENE

TIMTEC-BB SBB007978

9-BROMOANTHRACENE

9-BROMOANTHRENE

9-Bromoanthracene98%

9-Bromoanthracene 98%

9-BROMOANTHRACENE: TECH., 90%

10-Bromoanthracene

9-Anthryl bromide

9-Bromo anthrecene

9-Bromoanthracene,96%

9-BroMoanthracene, 96% 25GR

9-BroMoanthracene, 96% 5GR

9-Bromoanthracene, 95%, for synthesis

9-Bromoanthracene &gt

9-Bromoanthracene Standard

9-Bromoanthracene ISO 9001：2015 REACH

1564-64-3

15464-64-3

1564-6-64-3

C14H9Br

C14H8Br

ARYL HALIDE

Halogenated Hydrocarbons

Organic Building Blocks

Aryl

C13 to C37+

Building Blocks

Anthracenes

blocks

Bromides

OLED materrials

Aryl

C13 to C37+

Halogenated Hydrocarbons

Aromatic Halides (substituted)

Anthracenes

Anthracene series

Aromatic Compounds

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