ChemicalBook > CAS DataBase List > ISOPROPENYLOXYTRIMETHYLSILANE

ISOPROPENYLOXYTRIMETHYLSILANE

Product Name
ISOPROPENYLOXYTRIMETHYLSILANE
CAS No.
1833-53-0
Chemical Name
ISOPROPENYLOXYTRIMETHYLSILANE
Synonyms
DK177;IPOTMS;(CH3)3SiOC(CH3)=CH2;2-(TRIMETHYLSILOXY)PROPENE;ISOPROPENOXYTRIMETHYLSILANE;2-(TRIMETHYLSILYLOXY)PROPENE;Trimethyl Isopropenoxysilane;Trimethyl lsopropenoxysilane;TRIMETHYLISOPROPENYLOXYSILANE;ISOPROPENYLOXYTRIMETHYLSILANE
CBNumber
CB5326015
Molecular Formula
C6H14OSi
Formula Weight
130.26
MOL File
1833-53-0.mol
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ISOPROPENYLOXYTRIMETHYLSILANE Property

Melting point:
40-45 °C
Boiling point:
93-95 °C
Density 
0.78 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.395(lit.)
Flash point:
45 °F
storage temp. 
-20°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
Specific Gravity
0.786
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
1849023
CAS DataBase Reference
1833-53-0(CAS DataBase Reference)
NIST Chemistry Reference
CH2=(CH3)OSi(CH3)3(1833-53-0)
EPA Substance Registry System
Silane, trimethyl[(1-methylethenyl)oxy]- (1833-53-0)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-26-36-37/39
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
F 
10-21
TSCA 
Yes
HazardClass 
3.1
PackingGroup 
II
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
376078
Product name
(Isopropenyloxy)trimethylsilane
Purity
≥85%
Packaging
1g
Price
$96.6
Updated
2024/03/01
Sigma-Aldrich
Product number
376078
Product name
(Isopropenyloxy)trimethylsilane
Purity
≥85%
Packaging
5g
Price
$181
Updated
2024/03/01
TCI Chemical
Product number
I0324
Product name
Isopropenyloxytrimethylsilane [Trimethylsilylating Agent]
Purity
>90.0%(GC)
Packaging
5mL
Price
$97
Updated
2024/03/01
Usbiological
Product number
281025
Product name
Isopropenyloxytrimethylsilane
Packaging
2g
Price
$340
Updated
2021/12/16
AK Scientific
Product number
8100AL
Product name
Isopropenyloxytrimethylsilane
Packaging
5g
Price
$171
Updated
2021/12/16
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ISOPROPENYLOXYTRIMETHYLSILANE Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

General Description

(Isopropenyloxy)trimethylsilane is an enol silyl ether. It participates as nucleophile in Lewis acid-promoted C3-nucleophile substitution of tetracyclic bromide. It is reported to participate in the total synthesis of (±)-powelline. It is reported to participate in dityltin bis(triflate) catalyzed Michael addition reaction of enol silyl ethers.

Purification Methods

Purify it by fractional distillation using a very efficient column at atmospheric pressure. It usually contains 5% of hexamethyldisiloxalane which boils at 99-101o, but is generally non-reactive and need not be removed. [Hauser & Hance J Am Chem Soc 71 5091 1952.] It has been distilled under N2 through a 15cm column packed with glass helices. Fraction b 99-104o is further purified by gas chromatography through a Carbowax column (Autoprep A 700) at a column temperature of 87o, and has a retention time of 9.5minutes. [Krüger & Rochow J Organomet Chem 1 476 1963-4.]

ISOPROPENYLOXYTRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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ISOPROPENYLOXYTRIMETHYLSILANE Suppliers

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View Lastest Price from ISOPROPENYLOXYTRIMETHYLSILANE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(Isopropenyloxy)trimethylsilane 1833-53-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
(Isopropenyloxy)trimethylsilane 1833-53-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08
Zhuozhou Wenxi import and Export Co., Ltd
Product
(Isopropenyloxy)trimethylsilane 1833-53-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

1833-53-0, ISOPROPENYLOXYTRIMETHYLSILANERelated Search:

(TRIISOPROPYLSILOXY)METHYL CHLORIDE TRIMETHYLSILYL METHACRYLATE Trimethyl(phenoxy)silane METHOXYTRIMETHYLSILANE 4-TRIMETHYLSILOXY-3-PENTEN-2-ONE 1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE 1-Cyclohexenyloxytrimethylsilane 2-(Trimethylsiloxy)-1,3-butadiene 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 1-(Trimethylsiloxy)cyclopentene 2-(TERT-BUTYLDIMETHYLSILOXY)PENT-2-EN-4-ONE 2,3-BIS(TRIMETHYLSILYLOXY)-1,3-BUTADIENE ISOPROPENYLOXYTRIMETHYLSILANE 2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE ALLYLOXYTRIMETHYLSILANE DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL 3-CHLORO-2-TRIMETHYLSILOXYPROPENE

  • TRIMETHYLISOPROPENYLOXYSILANE
  • ACETONE ENOL TRIMETHYLSILYL ETHER
  • 2-(TRIMETHYLSILYLOXY)PROPENE
  • 2-(TRIMETHYLSILOXY)PROPENE
  • IPOTMS
  • ISOPROPENOXYTRIMETHYLSILANE
  • (CH3)3SiOC(CH3)=CH2
  • Silane, trimethyl[(1-methylethenyl)oxy]-
  • trimethyl[(1-methylethenyl)oxy]-silan
  • trimethyl[(1-methylethenyl)oxy]-Silane
  • ISOPROPENYLOXYTRIMETHYLSILANE
  • 2-(Trimethylsiloxy)propene, Acetone enol trimethylsilyl ether, IPOTMS
  • trimethyl[(1-methylvinyl)oxy]silane
  • 2-(TRIMETHYLSILYLOXY)PROPENE, 85+%
  • isopropenyloxytrimethylsilane[trimethylsilylatingagent]90+%
  • Isopropenyloxytrimethylsilane(2-Trimethylsiloxypropene)
  • Isopropenyloxytrimethylsilane [Trimethylsilylating Agent]
  • Isopropenyl(trimethylsilyl) ether
  • 2-(Trimethylsilyloxy)propene,90%
  • Trimethyl Isopropenoxysilane
  • Trimethyl(prop-1-en-2-yloxy)silane
  • (Isopropenyloxy)triMethylsilane >=85%
  • Isopropenyloxytrimethylsilane[TrimethylsilylatingAgent]&gt
  • rimethyl(prop-1-en-2-yloxy)silane
  • 2- (trimethylsiloxyl) propylene
  • DK177
  • Trimethyl lsopropenoxysilane
  • 1833-53-0
  • CH3CCH2OSiCH33
  • Silicon Compounds (for Synthesis)
  • Si (Classes of Silicon Compounds)
  • Monoalkoxysilanes
  • Vinylsilanes, Allylsilanes
  • Si-O Compounds
  • Building Blocks
  • Organic Building Blocks
  • Enol Ethers
  • Oxygen Compounds
  • Building Blocks
  • Chemical Synthesis
  • Enol Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • Monoalkoxysilanes
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Si-O Compounds
  • Synthetic Organic Chemistry
  • Vinylsilanes, Allylsilanes