TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER
- Product Name
- TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER
- CAS No.
- 15177-67-0
- Chemical Name
- TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER
- Synonyms
- TRANS-4-(METHOXYCARBONYL)CYCLOHEXANECARBOXYLIC ACID;trans-4-(Methoxycarbonyl);Monmethyl trans-1,4-cyclohexanedicarboxylate;MonoMethyl trans-1,4-cyclohexanedicarboxylate;Methyl trans-4-carboxycyclohexane-1-carboxylate;4(METHOXY CARBONYL) CYCLOHEXANE CARBOXYLIC ACID;4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER;TRANS-4-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID;TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL;Monomethyl trans-1,4-Cyclohexanedicarboxylate >
- CBNumber
- CB5363218
- Molecular Formula
- C9H14O4
- Formula Weight
- 186.21
- MOL File
- 15177-67-0.mol
TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER Property
- Melting point:
- 126.0 to 130.0 °C
- Boiling point:
- 303.1±35.0 °C(Predicted)
- Density
- 1.191±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- 4.66±0.10(Predicted)
- color
- White to Almost white
- InChI
- InChI=1S/C9H14O4/c1-13-9(12)7-4-2-6(3-5-7)8(10)11/h6-7H,2-5H2,1H3,(H,10,11)/t6-,7-
- InChIKey
- ZQJNPHCQABYENK-LJGSYFOKSA-N
- SMILES
- [C@@H]1(C(OC)=O)CC[C@@H](C(O)=O)CC1
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- HazardClass
- IRRITANT
- HS Code
- 2917200090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
N-Bromosuccinimide Price
- Product number
- M2526
- Product name
- Monomethyl trans-1,4-Cyclohexanedicarboxylate
- Purity
- >97.0%(GC)(T)
- Packaging
- 5g
- Price
- $52
- Updated
- 2025/07/31
- Product number
- M2526
- Product name
- Monomethyl trans-1,4-Cyclohexanedicarboxylate
- Purity
- >97.0%(GC)(T)
- Packaging
- 25g
- Price
- $175
- Updated
- 2025/07/31
- Product number
- C997758
- Product name
- trans-1,4-CyclohexanedicarboxylicAcidMonomethylEster
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 290693
- Product name
- Trans-1,4-cyclohexane dicarboxylic acid monomethyl ester
- Packaging
- 5g
- Price
- $342
- Updated
- 2021/12/16
- Product number
- 047211
- Product name
- trans-1,4-Cyclohexanedicarboxylicacidmonomethylester
- Purity
- 98%
- Packaging
- 1g
- Price
- $10
- Updated
- 2021/12/16
TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER Chemical Properties,Usage,Production
Uses
Trans-cyclohexane-1,4-dicarboxylic acid monomethyl ester is a carboxylic acid ester derivative, used as organic reagents.
Synthesis
94-60-0
15177-67-0
(1) Isomerization reaction: 0.5 mol (100.1 g) of dimethyl 1,4-cyclohexanedicarboxylate (Ib) with a trans/cis isomer ratio of 3/7 to 5/5 was dissolved in 200 g of methanol at 40°C. The reaction was carried out by adding 15 g of pyridine as a catalyst. 15 g of pyridine was added as a catalyst, and after 2 h of reaction, a methanolic solution of dimethyl 1,4-cyclohexanedicarboxylate (II-b) with a trans/cis isomer ratio of 9/1 was obtained. (2) Monoester hydrolysis reaction: The methanol solution of dimethyl 1,4-cyclohexanedicarboxylate (II-b) with a trans/cis isomer ratio of 9/1 obtained in step (1) was cooled to room temperature, and 150 g of potassium hydroxide was added. The reaction was carried out at 20°C for 3 h. Monoester hydrolysis was carried out to obtain a water-soluble carboxylic acid ester of trans-1,4-cyclohexanedicarboxylic acid monomethyl ester. (3) Acidification and post-treatment: 200 g of water and 100 g of toluene were added to the reaction system of step (2), and the organic phase was removed by extraction and stratification. The aqueous phase was adjusted to pH 1-2 with concentrated hydrochloric acid and the mixture was cooled to 0 °C. After filtration, the mixture was dried under reduced pressure at 50 °C to afford 66.4 g of white solid powder of monomethyl trans-1,4-cyclohexanedicarboxylate (III). The yield was 71.32% and the purity of compound (III) was 98.9% as determined by gas chromatography.
References
[1] Patent: CN108129307, 2018, A. Location in patent: Paragraph 0027-0041
TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER Suppliers
- Tel
- 18916626092
- targsense@qq.com
- Country
- China
- ProdList
- 110
- Advantage
- 65
- Tel
- 023-86822659 18611316925
- sales@acemol.com
- Country
- China
- ProdList
- 993
- Advantage
- 55
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006356688 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- +49 3493/605464
- Fax
- +49 3493/605470
- sales@intatrade.de
- Country
- Germany
- ProdList
- 3572
- Advantage
- 66
- Tel
- 5108538618
- Fax
- 86 510 85386988-8017
- suger.wang@chemfuture.com
- Country
- China
- ProdList
- 832
- Advantage
- 65
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 010-010-82967028 13522913783
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12000
- Advantage
- 60
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9310
- Advantage
- 66
View Lastest Price from TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER manufacturers
- Product
- TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER 15177-67-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-28
- Product
- TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER 15177-67-0
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-02-26
- Product
- Trans-1,4-cyclohexanedicarboxylic acid monomethyl ester 15177-67-0
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 100 tons
- Release date
- 2022-02-08