Nickel(II) acetate tetrahydrate

Physical Properties Uses Preparation

Product Name: Nickel(II) acetate tetrahydrate
CAS No.: 6018-89-9
Chemical Name: Nickel(II) acetate tetrahydrate
Synonyms: NICKEL ACETATE;NICKEL ACETATE TETRAHYDRATE;Nickle Acetate;NICKEL ACETATE 4H2O;NICKEL ACETATE TETRA;NICKEL ACETATE HYDRATE;ACETIC ACID NICKEL SALT;NICKEL(II) ACETATE 4 H2O;(II) acetate tetrahydrate;Nickel(II) acetate hydrate
CBNumber: CB5378827
Molecular Formula: C4H14NiO8
Formula Weight: 248.84
MOL File: 6018-89-9.mol

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Nickel(II) acetate tetrahydrate Property

Melting point:: °Cd ec.)
Boiling point:: 16℃
Density: 1.798 g/mL at 25 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in H2O, ethanol
form: Solid
Specific Gravity: 1.798
color: White to off-white
Water Solubility: 182 g/L (20 ºC)
Sensitive: Hygroscopic
Hydrolytic Sensitivity: 0: forms stable aqueous solutions
Merck: 14,6499
BRN: 3730764
Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:: Stable.
CAS DataBase Reference: 6018-89-9(CAS DataBase Reference)
EPA Substance Registry System: Nickel diacetate tetrahydrate (6018-89-9)

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Safety

Hazard Codes: T,Xn,N
Risk Statements: 45-22-43-40-68-50/53-48/23-42/43-20/22-61-49
Safety Statements: 53-36/37-45-24-22-61-60
RIDADR: UN 3077 9 / PGIII
WGK Germany: 3
RTECS: QR6126000
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29152990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H341Suspected of causing genetic defects

H350May cause cancer

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 244066
Product name: Nickel(II) acetate tetrahydrate
Purity: 98%
Packaging: 100g
Price: $35.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 244066
Product name: Nickel(II) acetate tetrahydrate
Purity: 98%
Packaging: 500g
Price: $88.2
Updated: 2024/03/01

Alfa Aesar

Product number: 010813
Product name: Nickel(II) acetate tetrahydrate, Puratronic?, 99.999% (metals basis)
Packaging: 5g
Price: $120
Updated: 2024/03/01

Alfa Aesar

Product number: 010813
Product name: Nickel(II) acetate tetrahydrate, Puratronic?, 99.999% (metals basis)
Packaging: 25g
Price: $445
Updated: 2023/06/20

Strem Chemicals

Product number: 28-1100
Product name: Nickel(II) acetate tetrahydrate (99.999%-Ni) PURATREM
Packaging: 5g
Price: $70
Updated: 2024/03/01

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Nickel(II) acetate tetrahydrate Chemical Properties,Usage,Production

Physical Properties

The tetrahydrate is a green crystalline solid; sweet taste; odor of acetic acid; density 1.744 g/cm3; loses water on heating to form a yellow-green powder of anhydrous nickel acetate; decomposes above 250°C; soluble in water, 17g/100mL at 20°C; sparingly soluble in alcohol.

Uses

Nickel acetate is used as a catalyst. It also is used as a dye mordant in textiles. Other applications are in electroplating nickel and as a sealer for anodizing aluminum.

Preparation

Nickel acetate is prepared by reacting nickel hydroxide or nickel carbonate with dilute acetic acid. The tetrahydrate is crystallized from solution.
Ni(OH)2 + 2CH3COOH → (CH3COO)2Ni + 2H2O
NiCO3 + 2CH3COOH → (CH3COO)2Ni + CO2 + 2H2O
On heating, the solution hydrolyzes depositing nickel hydroxide.

Chemical Properties

green monoclinic crystal(s); hygroscopic; used in textiles as a mordant [HAW93]

Uses

Nickel(II) Acetate Tetrahydrate is a reactant in the synthesis of metalloprophyrazines as active components of membranes of anion-selective electrodes.

Uses

Nickel(II) acetate tetrahydrate can be used in synthesis of polynuclear-nickel polyoxotungstate cluster compounds that are ideal for the design of molecular magnets.

Safety Profile

Confirmed human carcinogen. Poison by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL(II) ACETATE and NICKEL COMPOUNDS.

Purification Methods

The acetate crystallises from aqueous AcOH as the green tetrahydrate salt. It is soluble in 6 parts of H2O. It forms lower hydrates and should be kept in a well-sealed container. [Hardt & Pohlmann Z Anorg Allgem Chem 343 92 1966, Beilstein 2 IV 120.]

Nickel(II) acetate tetrahydrate Preparation Products And Raw materials

Raw materials

Nickel carbonate NICKEL(II) CARBONATE BASIC HYDRATE Nickel sulfate Acetic acid Hydrogen fluoride Sodium carbonate

Preparation Products

6,6'-Dimethyl-2,2'-dipyridyl 5,5'-DIMETHYL-2,2'-DIPYRIDYL

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Nickel(II) acetate tetrahydrate Suppliers

Belgium 1 China 208 Europe 3 France 2 Germany 3 India 16 Japan 5 Singapore 1 Switzerland 1 United Kingdom 5 United States 37 Global 282

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View Lastest Price from Nickel(II) acetate tetrahydrate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Nickel(II) acetate tetrahydrate 6018-89-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-17

Hebei Weibang Biotechnology Co., Ltd

Product: Nickel(II) acetate tetrahydrate 6018-89-9
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-21

Hebei Weibang Biotechnology Co., Ltd

Product: Nickel(II) acetate tetrahydrate 6018-89-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-31

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6018-89-9

NiC2H3O224H2O

NiCH3COO24H2O

NiCH3COO2xH2O

C4H14NiO8