ChemicalBook > CAS DataBase List > CERIUM(III) CHLORIDE HEPTAHYDRATE

CERIUM(III) CHLORIDE HEPTAHYDRATE

Product Name
CERIUM(III) CHLORIDE HEPTAHYDRATE
CAS No.
18618-55-8
Chemical Name
CERIUM(III) CHLORIDE HEPTAHYDRATE
Synonyms
CERIUM CHLORIDE HEPTAHYDRATE;CEROUS CHLORIDE HEPTAHYDRATE;oride heptahydrate;Ceriumchloridehydrate;CERIUM CHLORIDE (CERIC);3/5000 Cerium chloride;Cerium(III) chloride 99,5%;CERIUM (III) CHLORIDE 7 H2O;CERIUM(III) CHLORIDE HYDRATE;CeriuM(III)chlorideheptahydra
CBNumber
CB5378887
Molecular Formula
CeCl3H14O7
Formula Weight
372.58
MOL File
18618-55-8.mol
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CERIUM(III) CHLORIDE HEPTAHYDRATE Property

Melting point:
848 °C
Density 
~3.94 g/mL at 25 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
very soluble in H2O, ethanol
form 
Crystals or Crystalline Powder
color 
Light yellow
Odor Threshold
Stinging odor
Water Solubility 
Soluble in alcohol, water, and acetone. Slightly soluble in tetrahydrofuran.
Sensitive 
Hygroscopic
Merck 
14,1997
Stability:
Stable, but may be moisture sensitive. Incompatible with strong acids, strong oxidizing agents.
InChI
InChI=1S/Ce.3ClH.7H2O/h;3*1H;7*1H2/q+3;;;;;;;;;;/p-3
InChIKey
KPZSTOVTJYRDIO-UHFFFAOYSA-K
SMILES
[Ce](Cl)(Cl)Cl.O.O.O.O.O.O.O
CAS DataBase Reference
18618-55-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
UN 3260 8 / PGIII
WGK Germany 
3
RTECS 
FK5100000
3-10-21
Autoignition Temperature
400°C
TSCA 
Yes
HS Code 
28461090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
202983
Product name
Cerium(III) chloride heptahydrate
Purity
99.999% trace metals basis
Packaging
10g
Price
$181
Updated
2024/03/01
Sigma-Aldrich
Product number
202983
Product name
Cerium(III) chloride heptahydrate
Purity
99.999% trace metals basis
Packaging
100g
Price
$879
Updated
2024/03/01
Alfa Aesar
Product number
A12947
Product name
Cerium(III) chloride heptahydrate, 99%
Packaging
50g
Price
$45.4
Updated
2024/03/01
Alfa Aesar
Product number
A12947
Product name
Cerium(III) chloride heptahydrate, 99%
Packaging
250g
Price
$136
Updated
2024/03/01
Sigma-Aldrich
Product number
228931
Product name
Cerium(III) chloride heptahydrate
Purity
99.9% trace metals basis
Packaging
25g
Price
$52.7
Updated
2024/03/01
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CERIUM(III) CHLORIDE HEPTAHYDRATE Chemical Properties,Usage,Production

Chemical Properties

colourless crystalline solid

Uses

Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.

Uses

Catalyst employed in a solvent-free microwave-assisted synthesis of 2-quinolones via condensation of ?-ketoesters with o-anilinoketones. Coupled with NaI promotes the Beckmann rearrangement of oximes.

Uses

Cerium(III) chloride heptahydrate can be used in the conversion of esters to allylsilanes.

Application

Cerium(III) chloride heptahydrate can be used:
As a precursor to prepare cerium oxide nanoparticles for biomedical applications and photocatalytic degradation.
As a solution to fabricate thin films of CeO2 on glass substrates by the spray pyrolysis process.
As a dopant to fabricate ZnO and CeO2 nanocrystals for electrochemical sensing of H2O2 and photocatalytic degradation of Rhodamine B and Congo red dyes.
As an additive to prepare corrosion-inhibiting formulations and coatings.
To synthesize carbon nanofiber composites to fabricate high-temperature polymer electrolyte membrane fuel cell cathodes.
As a support for the combination of cerium(III)chloride heptahydrate and sodium iodide supported on silica gel to promoteMichael-type additions. These catalysts are used to convert from indolesand nitroalkenes to 2-indolyl-1-nitroalkane derivatives in good yields.

General Description

Cerium(III) chloride heptahydrate is a mild Lewis acid. It participates in the allylation of aldehydes. Cerium(III) chloride heptahydrate in combination with sodium iodide supported on silica gel efficiently promotes Michael-type addition. Cerium(III) chloride heptahydrate in the presence of sodium iodide acts as an efficient catalyst for the Michael addition of 1,3-dicarbonyl compounds to α,β-unsaturated ketones and α,β-unsaturated aldehydes.

reaction suitability

reagent type: catalyst
core: cerium

CERIUM(III) CHLORIDE HEPTAHYDRATE Preparation Products And Raw materials

Raw materials

Preparation Products

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CERIUM(III) CHLORIDE HEPTAHYDRATE Suppliers

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View Lastest Price from CERIUM(III) CHLORIDE HEPTAHYDRATE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
CERIUM(III) CHLORIDE HEPTAHYDRATE 18618-55-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-14
Shandong Juchuang Chemical Co., LTD
Product
Cerium Chloride Hexahydrate 18618-55-8
Price
US $5.40-2.50/kg
Min. Order
500kg
Purity
99.9
Supply Ability
200tons
Release date
2024-03-13
Career Henan Chemical Co
Product
CERIUM(III) CHLORIDE HEPTAHYDRATE 18618-55-8
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-19

18618-55-8, CERIUM(III) CHLORIDE HEPTAHYDRATERelated Search:


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  • Catalysis and Inorganic Chemistry
  • Cerium
  • Rare-Earth Metals
  • Catalysis and Inorganic Chemistry
  • Ce
  • Cerium
  • Isoquinolines ,Quinolines ,Indolines ,Quinaldines
  • Cerium Salts
  • Chemical Synthesis
  • Materials Science
  • Metal and Ceramic Science
  • Salts
  • Ultra-High Purity Materials