CERIUM(III) CHLORIDE HEPTAHYDRATE
- Product Name
- CERIUM(III) CHLORIDE HEPTAHYDRATE
- CAS No.
- 18618-55-8
- Chemical Name
- CERIUM(III) CHLORIDE HEPTAHYDRATE
- Synonyms
- CERIUM CHLORIDE HEPTAHYDRATE;CEROUS CHLORIDE HEPTAHYDRATE;oride heptahydrate;Ceriumchloridehydrate;CERIUM CHLORIDE (CERIC);3/5000 Cerium chloride;Cerium(III) chloride 99,5%;CERIUM (III) CHLORIDE 7 H2O;CERIUM(III) CHLORIDE HYDRATE;CeriuM(III)chlorideheptahydra
- CBNumber
- CB5378887
- Molecular Formula
- CeCl3H14O7
- Formula Weight
- 372.58
- MOL File
- 18618-55-8.mol
CERIUM(III) CHLORIDE HEPTAHYDRATE Property
- Melting point:
- 848 °C
- Density
- ~3.94 g/mL at 25 °C(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- very soluble in H2O, ethanol
- form
- Crystals or Crystalline Powder
- color
- Light yellow
- Odor Threshold
- Stinging odor
- Water Solubility
- Soluble in alcohol, water, and acetone. Slightly soluble in tetrahydrofuran.
- Sensitive
- Hygroscopic
- Merck
- 14,1997
- Stability:
- Stable, but may be moisture sensitive. Incompatible with strong acids, strong oxidizing agents.
- InChI
- InChI=1S/Ce.3ClH.7H2O/h;3*1H;7*1H2/q+3;;;;;;;;;;/p-3
- InChIKey
- KPZSTOVTJYRDIO-UHFFFAOYSA-K
- SMILES
- [Ce](Cl)(Cl)Cl.O.O.O.O.O.O.O
- CAS DataBase Reference
- 18618-55-8(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
N-Bromosuccinimide Price
- Product number
- 202983
- Product name
- Cerium(III) chloride heptahydrate
- Purity
- 99.999% trace metals basis
- Packaging
- 10g
- Price
- $181
- Updated
- 2024/03/01
- Product number
- 202983
- Product name
- Cerium(III) chloride heptahydrate
- Purity
- 99.999% trace metals basis
- Packaging
- 100g
- Price
- $879
- Updated
- 2024/03/01
- Product number
- A12947
- Product name
- Cerium(III) chloride heptahydrate, 99%
- Packaging
- 50g
- Price
- $45.4
- Updated
- 2024/03/01
- Product number
- A12947
- Product name
- Cerium(III) chloride heptahydrate, 99%
- Packaging
- 250g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- 228931
- Product name
- Cerium(III) chloride heptahydrate
- Purity
- 99.9% trace metals basis
- Packaging
- 25g
- Price
- $52.7
- Updated
- 2024/03/01
CERIUM(III) CHLORIDE HEPTAHYDRATE Chemical Properties,Usage,Production
Chemical Properties
colourless crystalline solid
Uses
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
Uses
Catalyst employed in a solvent-free microwave-assisted synthesis of 2-quinolones via condensation of ?-ketoesters with o-anilinoketones. Coupled with NaI promotes the Beckmann rearrangement of oximes.
Uses
Cerium(III) chloride heptahydrate can be used in the conversion of esters to allylsilanes.
Application
Cerium(III) chloride heptahydrate can be used:
As a precursor to prepare cerium oxide nanoparticles for biomedical applications and photocatalytic degradation.
As a solution to fabricate thin films of CeO2 on glass substrates by the spray pyrolysis process.
As a dopant to fabricate ZnO and CeO2 nanocrystals for electrochemical sensing of H2O2 and photocatalytic degradation of Rhodamine B and Congo red dyes.
As an additive to prepare corrosion-inhibiting formulations and coatings.
To synthesize carbon nanofiber composites to fabricate high-temperature polymer electrolyte membrane fuel cell cathodes.
As a support for the combination of cerium(III)chloride heptahydrate and sodium iodide supported on silica gel to promoteMichael-type additions. These catalysts are used to convert from indolesand nitroalkenes to 2-indolyl-1-nitroalkane derivatives in good yields.
General Description
Cerium(III) chloride heptahydrate is a mild Lewis acid. It participates in the allylation of aldehydes. Cerium(III) chloride heptahydrate in combination with sodium iodide supported on silica gel efficiently promotes Michael-type addition. Cerium(III) chloride heptahydrate in the presence of sodium iodide acts as an efficient catalyst for the Michael addition of 1,3-dicarbonyl compounds to α,β-unsaturated ketones and α,β-unsaturated aldehydes.
CERIUM(III) CHLORIDE HEPTAHYDRATE Preparation Products And Raw materials
Raw materials
Preparation Products
CERIUM(III) CHLORIDE HEPTAHYDRATE Suppliers
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View Lastest Price from CERIUM(III) CHLORIDE HEPTAHYDRATE manufacturers
- Product
- CERIUM(III) CHLORIDE HEPTAHYDRATE 18618-55-8
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-14
- Product
- Cerium Chloride Hexahydrate 18618-55-8
- Price
- US $5.40-2.50/kg
- Min. Order
- 500kg
- Purity
- 99.9
- Supply Ability
- 200tons
- Release date
- 2024-03-13
- Product
- CERIUM(III) CHLORIDE HEPTAHYDRATE 18618-55-8
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2018-12-19