2-Aminoacetophenone

Product Name: 2-Aminoacetophenone
CAS No.: 551-93-9
Chemical Name: 2-Aminoacetophenone
Synonyms: 1-(2-AMINOPHENYL)ETHAN-1-ONE;2-Acetylaniline;O-AMINOACETOPHENONE;2-AMINO-1-PHENYLETHANONE;1-Acetyl-2-aminobenzene;2'-AMINOACETOPHENONE;ETHANONE, 1-(2-AMINOPHENYL)-;FEMA 3906;Linaint-G;o-aminophenone
CBNumber: CB5383885
Molecular Formula: C8H9NO
Formula Weight: 135.16
MOL File: 551-93-9.mol

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2-Aminoacetophenone Property

Melting point:: 20 °C
Boiling point:: 85-90 °C0.5 mm Hg(lit.)
Density: 1.112 g/mL at 25 °C(lit.)
refractive index: n20/D 1.614(lit.)
FEMA: 3906 | 2-AMINOACETOPHENONE
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Dichloromethane (Sparingly), DMSO, Methanol (Slightly)
pka: 2.31±0.10(Predicted)
form: Liquid
color: Yellow to yellow-brown
Odor: grape sweet, Heavy-sweet, somewhat animal-floral odor of considerable tenacity, faintly reminiscent of tobacco leaf odor.
Odor Type: grape
Merck: 14,413
JECFA Number: 2043
BRN: 386122
InChIKey: GTDQGKWDWVUKTI-UHFFFAOYSA-N
LogP: 1.63
CAS DataBase Reference: 551-93-9(CAS DataBase Reference)
NIST Chemistry Reference: Ethanone, 1-(2-aminophenyl)-(551-93-9)
EPA Substance Registry System: Ethanone, 1-(2-aminophenyl)- (551-93-9)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-24/25-37/39
WGK Germany: 3
RTECS: AM5775000
Hazard Note: Irritant
TSCA: Yes
HS Code: 29223990
Hazardous Substances Data: 551-93-9(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W390607
Product name: 2′-Aminoacetophenone
Purity: ≥98%
Packaging: 100g
Price: $78.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: W390607
Product name: 2′-Aminoacetophenone
Purity: ≥98%
Packaging: 1kg
Price: $629
Updated: 2024/03/01

Sigma-Aldrich

Product number: A37804
Product name: 2′-Aminoacetophenone
Purity: 98%
Packaging: 5g
Price: $49.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 49868
Product name: 2′-Aminoacetophenone
Purity: analytical standard
Packaging: 250mg
Price: $65.6
Updated: 2022/05/15

TCI Chemical

Product number: A0250
Product name: 2'-Aminoacetophenone
Packaging: 5g
Price: $26
Updated: 2024/03/01

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2-Aminoacetophenone Chemical Properties,Usage,Production

Chemical Properties

2-Aminoacetophenone, also known as o-aminoacetophenone or 2-AA, is a yellow to yellow-brown liquid that has a grape-like odor. Aminoacetophenone is a pheromone produced by virgin honeybee queens and released in feces. The pheromone repels and is used to terminate agonistic interactions between queens and workers. A grape-like odor of 2-aminoacetophenone is of diagnostic importance in detecting the growth of Pseudomonas aeruginosa in culture and in burn wounds.

Occurrence

Reported present in chestnut honey (>154 ppb)*; green tea and wine (0.7 to 12.8 μg/L).

Uses

2′-Aminoacetophenone may be used as an analytical standard for the determination of the analyte in livestock particulate matter, and grape-derived beverages by gas chromatography-mass spectrometry-olfactometry (GC-MS-O) and GC-MS, respectively.

Definition

ChEBI: 2-Aminoacetophenone is an aromatic ketone that is acetophenone in which one of the ortho hydrogens of the phenyl group has been replaced by an amino group.

Preparation

Synthesis of 2-Aminoacetophenone by reaction of methyl lithium with Isatoic anhydride in an anhydrous or nearly anhydrous solvent at a reaction temperature of -50°C or less.

Synthesis Reference(s)

Journal of the American Chemical Society, 76, p. 4561, 1954 DOI: 10.1021/ja01647a016
Journal of Heterocyclic Chemistry, 24, p. 297, 1987 DOI: 10.1002/jhet.5570240201
Journal of the American Chemical Society, 105, p. 943, 1983 DOI: 10.1021/ja00342a050
The Journal of Organic Chemistry, 45, p. 4926, 1980 DOI: 10.1021/jo01312a021
The Journal of Organic Chemistry, 22, p. 358, 1957 DOI: 10.1021/jo01355a002

General Description

2′-Aminoacetophenone is one of the key volatile flavor components of masa corn flour products. It is also reported to be responsible for the grape-like odor in culture media growing Pseudomonas aeruginosa.

2-Aminoacetophenone Preparation Products And Raw materials

Raw materials

Preparation Products

ETHYL 2,4-DIMETHYLQUINOLINE-3-CARBOXYLATE ETHYL 2-(CHLOROMETHYL)-4-METHYLQUINOLINE-3-CARBOXYLATE HYDROCHLORIDE 2-CHLORO-4-METHYLQUINOLINE-3-CARBONITRILE 4-METHYL-2-(1H-PYRROL-2-YL)QUINOLINE 2-AMINO-4-METHYL-QUINOLINE-3-CARBONITRILE (2,4-DIMETHYLQUINOLIN-3-YL)ACETIC ACID HYDROCHLORIDE METHYL 2-(CHLOROMETHYL)-4-METHYLQUINOLINE-3-CARBOXYLATE HYDROCHLORIDE 2-ETHYL-4-METHYLQUINOLINE-3-CARBOXYLIC ACID 2,4-DIMETHYLQUINOLINE-3-CARBOXYLIC ACID 1-(2,4-DIMETHYLQUINOLIN-3-YL)ETHANONE HYDROCHLORIDE

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2-Aminoacetophenone Suppliers

Americas 1 Belgium 4 China 408 Europe 6 France 1 Germany 6 India 41 Japan 5 Slovakia 1 South Korea 1 Switzerland 4 The Netherlands 1 Turkey 1 Ukraine 2 United Kingdom 19 United States 59 USA 1 Global 561

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CARBONE SCIENTIFIC CO.,LTD

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MOLEKULA Ltd.

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View Lastest Price from 2-Aminoacetophenone manufacturers

HebeiShuoshengImportandExportco.,Ltd

Product: 2-Aminoacetophenone 551-93-9
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-08

Shanghai Qyubiotech Co., Ltd.

Product: 2-Aminoacetophenone 551-93-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%+
Supply Ability: 10000kgs per Month
Release date: 2023-08-16

Hebei Longbang Technology Co., Ltd

Product: 2-Aminoacetophenone 551-93-9
Price: US $6.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20TONS
Release date: 2024-05-10

551-93-9, 2-AminoacetophenoneRelated Search:

Methyl anthranilate Acetophenone 4'-Hydroxyacetophenone L-PICEIN 3-Nitroacetophenone 2'-Hydroxyacetophenone 2-Aminobenzaldehyde 2-Aminophenol 8-Bromo-3-methyl-xanthine (R)-1-Boc-3-Aminopiperidine o-Anisidine 1,2-Dimethoxybenzene 2-Bromobenzonitrile 3-Methoxysalicylaldehyde 1-Bromo-2-iodobenzene o-Phenetidine aminoacetophenon Anthranilic acid

1-(2-aminophenyl)-ethanon

1-Acetyl-2-aminobenzene

2’-amino-acetophenon

2-Acetylaniline

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o-acetylaniline

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2-AMINO-1-PHENYLETHANONE

2'-AMINOACETOPHENONE

2-AMINOACETOPHENONE

1-(2-AMINOPHENYL)ETHAN-1-ONE

1-(2-aminophenyl)-ethanone

AMINOACETOPHENONE(2-)

O-AMINOPHENYL METHYL KETONE

O-AMINOACETOPHENONE

ETHANONE, 1-(2-AMINOPHENYL)-

FEMA 3906

2'-AMINOACETOPHENONE 98+%

2'-AminoActophenone

2-Aminoacetophenone99%

ORTHO-AMINOACETOPHENONE

2''-AMINOACETOPHENONE 98.0+%

2'-Aminoacetophenone,97%

o-Aminoacetophenone(2-

2′-Aminoacetophenone,2-Acetylaniline

1-(2-Aminophenyl)ethan-1-one, 2-Acetylaniline

Neighboring aMino acetophenone

Linaint-G

Linagliptin Impurity 67 (2-Aminoacetophenone)

Linagliptin Impurity 96

Linagliptin Impurity 107

Compound Fr14273

2’-Aminoacetophenone (2-AAP)

o-aminophenone

2'-Aminoacetophenone

2’-Aminoacetophenone (2-AAP)

2-Aminoacetophenone 98% For Synthesis

551-93-9

551-93-3

55-93-9

CH3COC6H4NH2

C8H9NO

AMINE

ALDEHYDE

Organic Building Blocks

Ketones

C7 to C8

Carbonyl Compounds

Building Blocks

Aromatic Acetophenones & Derivatives (substituted)

pharmaceutical intermediates

Amines and Anilines

Carbonyl Compounds

J's

551-93-9

bc0001

john's