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Phenylphosphonic dichloride

Product Name
Phenylphosphonic dichloride
CAS No.
824-72-6
Chemical Name
Phenylphosphonic dichloride
Synonyms
P,P-DICHLOROPHENYLPHOSPHINE OXIDE;BPOD;DICHLOROPHENYLPHOSPHINE OXIDE;PHENYLPHOSPHONYL DICHLORIDE;phenylphosphonic;Benzenephosphonyl chloride;AURORA KA-1395;phosphonic dichL;Phenylphosphonic dic;Phenylphosphorylchloride
CBNumber
CB5411511
Molecular Formula
C6H5Cl2OP
Formula Weight
194.98
MOL File
824-72-6.mol
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Phenylphosphonic dichloride Property

Melting point:
3 °C(lit.)
Boiling point:
258 °C(lit.)
Density 
1.375 g/mL at 25 °C(lit.)
vapor pressure 
2.36Pa at 25℃
refractive index 
n20/D 1.559(lit.)
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
Miscible with benzene, chloroform, dimethyl sulfoxide and carbon tetrachloride.
form 
Liquid
color 
Clear yellow to brown
Specific Gravity
1.394 (25℃)
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
λmax
267nm(Cyclohexane)(lit.)
BRN 
1072240
Dielectric constant
26.0
InChIKey
IBDMRHDXAQZJAP-UHFFFAOYSA-N
LogP
1.089 at 20℃
CAS DataBase Reference
824-72-6(CAS DataBase Reference)
NIST Chemistry Reference
Phosphonic dichloride, phenyl-(824-72-6)
EPA Substance Registry System
Phosphonic dichloride, P-phenyl- (824-72-6)
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Safety

Hazard Codes 
C
Risk Statements 
14-34-37
Safety Statements 
26-45-8-36/37/39
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29310095
Toxicity
LD50 orally in Rabbit: 681 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
389560
Product name
Phenylphosphonic dichloride
Purity
technical grade, 90%
Packaging
100ml
Price
$86.3
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18248
Product name
Dichlorophenylphosphine oxide
Purity
for synthesis
Packaging
100mL
Price
$108
Updated
2024/03/01
Sigma-Aldrich
Product number
389560
Product name
Phenylphosphonic dichloride
Purity
technical grade, 90%
Packaging
500ml
Price
$214.8
Updated
2024/03/01
TCI Chemical
Product number
P0334
Product name
Phenylphosphonic Dichloride
Purity
>98.0%(T)
Packaging
25mL
Price
$25
Updated
2021/12/16
TCI Chemical
Product number
P0334
Product name
Phenylphosphonic Dichloride
Purity
>98.0%(T)
Packaging
500mL
Price
$214
Updated
2021/12/16
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Phenylphosphonic dichloride Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Phenylphosphonic dichloride is used in the preparation of 2-phenyl-[1,3,2]dioxaphosphepane-2-oxide. Further, it acts as an effective reagent for the chlorinative dehydration of some heterocycles.

Synthesis Reference(s)

Tetrahedron Letters, 33, p. 7473, 1992 DOI: 10.1016/S0040-4039(00)60798-0

Purification Methods

Fractionally distil it using a very efficient or a spinning band column. [Lecher et al. J Am Chem Soc 76 1045 1954, NMR: Müller et al. J Am Chem Soc 78 3557 1956, Van Wazer et al. J Am Chem Soc 78 5715 1956, IR: Daasch & Smith Anal Chem 23 853 1951, Beilstein 16 IV 1074.]

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Phenylphosphonic dichloride Suppliers

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View Lastest Price from Phenylphosphonic dichloride manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
Phenylphosphonic Dichloride 824-72-6
Price
US $10.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10 ton
Release date
2024-08-20
Career Henan Chemical Co
Product
Phenylphosphonic dichloride 824-72-6
Price
US $1000.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2018-07-24

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