ChemicalBook > CAS DataBase List > (S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide

(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide

Product Name
(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide
CAS No.
95713-52-3
Chemical Name
(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide
Synonyms
FDAA;Marfey;1-FLUORO-2,4-DINITROPHENYL-5-L-ALANINE AMIDE;MARFEY'S REAGENT;aninamide;S REAGENT;Togni’FDNP-ALA-NH2;Lawesson’FDNP-L-Ala-NH2
CBNumber
CB5413540
Molecular Formula
C9H9FN4O5
Formula Weight
272.19
MOL File
95713-52-3.mol
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(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Property

Melting point:
229 °C
Boiling point:
544.5±50.0 °C(Predicted)
Density 
1.592±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
acetone: 10 mg/mL, clear, yellow
form 
powder
pka
15.61±0.50(Predicted)
color 
yellow to orange
optical activity
[α]20/D +56±2°, c = 1% in acetone
BRN 
6820069
InChIKey
NEPLBHLFDJOJGP-BYPYZUCNSA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29242990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D7906
Product name
Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide
Purity
powder
Packaging
25mg
Price
$82.3
Updated
2024/03/01
Sigma-Aldrich
Product number
71478
Product name
Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide
Purity
for chiral derivatization, ≥99.0%
Packaging
50mg
Price
$138
Updated
2024/03/01
TCI Chemical
Product number
D2259
Product name
Nalpha-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide [HPLC Labeling Reagent for e.e. Determination]
Purity
>95.0%(HPLC)
Packaging
1g
Price
$164
Updated
2024/03/01
TCI Chemical
Product number
D2259
Product name
Nalpha-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide [HPLC Labeling Reagent for e.e. Determination]
Purity
>95.0%(HPLC)
Packaging
100mg
Price
$29
Updated
2024/03/01
Sigma-Aldrich
Product number
D7906
Product name
Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide
Purity
powder
Packaging
100mg
Price
$249
Updated
2024/03/01
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(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Chemical Properties,Usage,Production

Chemical Properties

Light yellow to yellow crystal or powder

Uses

FDAA was used as derivatizing reagent, in a study performed to understand unusual amino acids using reversed phase high performance liquid chromatography-electrospray ionization mass spectrometry (RPHPLC-ESI-MS).

Uses

N-α-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide is suitable for use for the derivatization of amino acids. glutamate and analine present in cell wall. Derivatized?D- and?L-amino acids can be resolved and quantitated by HPLC.

Uses

(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide can be used for chiral amino acid analysis.

General Description

Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide (FDAA) is a chiral derivatizing agent (CDA), has high enantioselectivity but low sensitivity as compared to other CDAs. It is generally used to assign the stereochemistry of amino acids in trace amounts.

Biochem/physiol Actions

N-α-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide (FDAA) is a chiral derivatizing agent and is used routinely to improve the detection of underivatized amino acids in high performance liquid chromatography. Its usage is effective in separating stereoisomer.

(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Suppliers

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BOC Sciences
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View Lastest Price from (S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide manufacturers

Shanghai UCHEM Inc.
Product
Marfey's reagent 95713-52-3
Price
US $356.00/g
Min. Order
5g
Purity
0.97
Supply Ability
1kg
Release date
2023-12-14
WUHAN FORTUNA CHEMICAL CO., LTD
Product
(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide 95713-52-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-13
Zhuozhou Wenxi import and Export Co., Ltd
Product
Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide 95713-52-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-26

95713-52-3, (S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMideRelated Search:

5-Fluoro-2-nitroaniline N-Isopropyl-3-fluoroaniline 4-FLUORO-2-NITROANILINE 2,4-Dinitrofluorobenzene FDNP-VAL-NH2 2,4-DINITRO-5-FLUOROANILINE 3-Fluoro-4-nitroaniline 2-Fluoro-5-nitroaniline 3-FLUORO-N-METHYLANILINE N1-(2,4-DINITRO-PHENYL)-ETHANE-1,2-DIAMINE 3,4-Diaminofluorobenzene (S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide N-(2-AMINO-ETHYL)-BENZENE-1,2-DIAMINE N-(2-NITRO-PHENYL)-ETHANE-1,2-DIAMINE 4-FLUORO-5-NITROBENZENE-1,2-DIAMINE (3-fluoro-4-nitrophenyl)methanamine 2,4-DIAMINOFLUOROBENZENE NALPHA-(5-FLUORO-2,4-DINITROPHENYL)-L-LEUCINAMIDE

  • 1-FLUORO-2,4-DINITROPHENYL-5-L-ALANINE AMIDE
  • Nα-(2,4-Dinitro-5-fluorophenyl)-L-alanine amide≥ 98% (HPLC)
  • NALPHA-(5-FLUORO-2,4-DINITROPHENYL)-L-ALANINAMIDE
  • N-ALPHA-(2,4-DINITRO-5-FLUOROPHENYL)-L-ALANINAMIDE
  • N-ALPHA-(2,4-DINITRO-5-FLUOROPHENYL)-L-ALANINE AMIDE
  • (2,4-Dinitro-5-fluorophenyl) L-Alaninamide
  • Marfey's Reagent, 99%, for chiral derivatization
  • Nalpha-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide [HPLC Labeling Reagent for e.e. Determination]
  • MARFEY'S REAGENT
  • FDNP-ALA-NH2
  • FDAA
  • NA-(2,4-DINITRO-5-FLUOROPHENYL)-L-*ALANI NAMIDE
  • N(ALPHA)-(2,4-DINITRO-5-FLUOROPHENYL)-L-
  • NALPHA-(2,4-DINITRO-5-FLUOROPHENYL)-L-ALANINAMIDE [HPLC LABELING REAGENT FOR E.E. DETERMINATION]
  • N-a-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide[HPLClabellingreagentfore.e.determination)
  • nα-(2,4-dinitro-5-fluorophenyl)-l-alaninamide
  • FATTYACIDMETHYLESTER
  • FDAA, Marfeys reagent
  • (S)-2-[(5-Fluoro-2,4-dinitrophenyl)amino]propionamide
  • L-Marfey's reagent
  • N2-(2,4-Dinitro-5-fluorophenyl)alaninamide
  • N2-(5-Fluoro-2,4-dinitrophenyl)alaninamide
  • Nα-(2,4-Dinitro-5-fluorophenyl)alaninamide
  • Nα-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide
  • FDAA, Marfeys reagent, Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide
  • aninamide
  • Nα-(2,4-Dinitro-5-fL
  • N(ALPHA)-(5)-2,4-DINITROPHENYL-L-ALANIMIDE
  • Togni&rsquo
  • Lawesson&rsquo
  • S REAGENT
  • (2S)-2-[(5-Fluoro-2,4-dinitrophenyl)aMino]propanaMide
  • Nalpha-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide Marfey's Reagent
  • Nα-(5-Fluoro-2,4-dinitrophenyl)-L-alaninaMide [HPLC Labeling Reagent for e.e. DeterMination]
  • PropanaMide,2-[(5-fluoro-2,4-dinitrophenyl)aMino]-, (2S)-
  • N-(2,4-Dinitro-5-fluorophenyl)-L-alaninaMide (powder)
  • FDNP-Ala-NH2( MARFEY'S REAGENT)
  • Marfey
  • (3R,4S)-4-amino -3-hydroxypentanoic acid
  • </SUB>-(2,4-Dinitro-5-fluorophenyl)-<SC>L</SC>-alaninamide
  • FDNP-L-Ala-NH2
  • Marfey's reagent ,98%
  • Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide,FDAA, Marfey’s reagent
  • (S)-2-(5-Fluoro-2,4-dinitrophenylaMino)propanaMide
  • Nα-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide[HPLCLabelingReagentfore.e.Determination]&gt
  • N2-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide
  • (S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide USP/EP/BP
  • Nα-(2,4-Dinitro-5-fluorophenyl)-L-alanine amide
  • Nα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide
  • Nα-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide
  • Marfeys Reagent extrapure AR, 98%
  • N-alpha-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide, 98%,
  • Nα-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide [HPLC Labeling Reagent for e.e. Determination]
  • (2S)-2-(5-Fluoro-2,4-dinitroanilino)propanamide
  • Sodium 5-fluoro-2,4-dinitrophenyl-5-L-alanine amino acid
  • L-Alanine amide
  • MARFEY'S REAGENT
  • 95713-52-3