ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE

Product Name: ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
CAS No.: 1235-21-8
Chemical Name: ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
Synonyms: AURORA KA-1148;acetonyltriphenyl-phosphoniuchloride;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE;OxopropyltriphenylphosphoniuM chlorid;Acetonyltriphenylphosphonium chloride,99%;Acetonyltriphenylphosphonium Chloride >2-oxopropyl(triphenyl)phosphanium chloride;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%;(2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE;2-Oxopropyltriphenylphosphonium chloride 98%
CBNumber: CB5414572
Molecular Formula: C21H20ClOP
Formula Weight: 354.81
MOL File: 1235-21-8.mol

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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Property

Melting point:: 243-245 °C(lit.)
storage temp.: Store below +30°C.
form: solid
color: White to Light yellow to Light orange
Water Solubility: Soluble in hot water.
Sensitive: Hygroscopic
CAS DataBase Reference: 1235-21-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 22-24/25-S24/25-S22-60-37-26
WGK Germany: 3
RTECS: TA1841000
F: 3
HS Code: 29319019
Toxicity: mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01535,

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.41028
Product name: Acetonyltriphenylphosphonium chloride
Purity: for synthesis
Packaging: 25g
Price: $110
Updated: 2023/01/07

TCI Chemical

Product number: A1305
Product name: Acetonyltriphenylphosphonium Chloride
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $37
Updated: 2024/03/01

Alfa Aesar

Product number: A14691
Product name: Acetonyltriphenylphosphonium chloride, 99%
Packaging: 25g
Price: $38.65
Updated: 2024/03/01

Alfa Aesar

Product number: A14691
Product name: Acetonyltriphenylphosphonium chloride, 99%
Packaging: 100g
Price: $129.65
Updated: 2024/03/01

Alfa Aesar

Product number: A14691
Product name: Acetonyltriphenylphosphonium chloride, 99%
Packaging: 500g
Price: $485.65
Updated: 2024/03/01

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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

WHITE TO SLIGHTLY BEIGE FINE CRYSTALLINE POWDER

Uses

Acetonyltriphenylphosphonium chloride is used to investigate the antimycobacterial activities of Me alkenyl quinolones. It is used as a reactant for synthesis of unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination.

Uses

Used to investigate the antimycobacterial activities of Me alkenyl quinolones

Reactant for synthesis of:

Unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination
Fused oxygen and nitrogen heterocycles via regioselective cyclocondensation

Reactant for Wittig olefinations

Purification Methods

Recrystallise it from CHCl3/*C6H6/pet ether (b 60-80o) or by dissolving it in CHCl3 and pouring it into dry Et2O. max nm() 255(3,600), 262(3,700), 268(4,000) and 275(3,100). The iodide salt crystallises from H2O and has m 207-209o. [Ramirez & Dershowitz J Org Chem 22 41 1957.] Itisan IRRITANT and is hygroscopic. When shaken with a 10% aqueous solution of Na2CO3 (8hours) it gives acetylmethylene triphenyl phosphorane which is recrystallised from MeOH/H2O and after drying at 70o/0.1mm has m 205-206o. UV: nm() 268 (6600), 275 (6500) and 288 (5700), IR: max 1529 (s), 1470 (m), 1425 (s), max 1374 (m), 1105 and 978 (s) (cm-1). [Ramirez & Dershowitz J Org Chem 22 41, 44 1957, Beilstein 16 H 761, 16 II 373.]

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Suppliers

Americas 1 Australia 1 Austria 2 Belgium 3 China 93 Europe 1 France 3 Germany 8 India 6 Japan 6 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 19 United States 32 Global 179

Creasyn Finechem(Tianjin) Co., Ltd.

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Beijing Donghualituo Techonlogy Development Co.,Ltd.

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Alfa Aesar

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Energy Chemical

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Shanghai Sinch Parmaceuticals Tech. Co. Ltd.

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Adamas Reagent, Ltd.

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View Lastest Price from ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Acetonyltriphenylphosphonium chloride 1235-21-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-23

Henan Aochuang Chemical Co.,Ltd.

Product: ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE 1235-21-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: Acetonyltriphenylphosphonium chloride 1235-21-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

1235-21-8, ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDERelated Search:

Acetyl-D-2-aminobutyric acid (ACETYLACETONATO)DICARBONYLIRIDIUM(I) AC-NLE-OH Benfotiamine Benzotriazole-1-yl-oxytripyrrolidinophosphonium hexafluorophosphate Acetone (3-ETHOXYCARBONYL-2-OXOPROPYL)TRIPHENYLPHOSPHONIUM CHLORIDE 3-CHLORO-2-OXOPROPYL TRIPHENYLPHOSPHONIUM CHLORIDE BENZOYLMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE AURORA KA-1161 AURORA KA-411 ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE

acetonyltriphenyl-phosphoniuchloride

(2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE

AURORA KA-1148

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%

Acetonyltriphenylphosphonium chloride,99%

OxopropyltriphenylphosphoniuM chlorid

2-Oxopropyltriphenylphosphonium chloride 98%

Acetonyltriphenylphosphonium chloride for synthesis

2-oxopropyl(triphenyl)phosphanium chloride

(Acetylmethylene)triphenylphosphoniumchloride

Acetonyltriphenylphosphonium Chloride &gt

Phosphonium, (2-oxopropyl)triphenyl-, chloride (1:1)

1235-21-8

C21H20OP

CH3COCH2PClC6H53

C21H20CIOP

C21H20ClOP

C21H20OPCl

C-C Bond Formation

Olefination

Synthetic Reagents

Wittig Reagents

Phosphonium Compounds

Wittig Reaction

Wittig & Horner-Emmons Reaction

Phosphonium Compounds

Synthetic Organic Chemistry

Wittig & Horner-Emmons Reaction

Wittig Reaction