ChemicalBook > CAS DataBase List > ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE

Product Name
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
CAS No.
1235-21-8
Chemical Name
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
Synonyms
AURORA KA-1148;acetonyltriphenyl-phosphoniuchloride;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE;OxopropyltriphenylphosphoniuM chlorid;Acetonyltriphenylphosphonium chloride,99%;Acetonyltriphenylphosphonium Chloride >2-oxopropyl(triphenyl)phosphanium chloride;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%;(2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE;2-Oxopropyltriphenylphosphonium chloride 98%
CBNumber
CB5414572
Molecular Formula
C21H20ClOP
Formula Weight
354.81
MOL File
1235-21-8.mol
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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Property

Melting point:
243-245 °C(lit.)
storage temp. 
Store below +30°C.
form 
solid
color 
White to Light yellow to Light orange
Water Solubility 
Soluble in hot water.
Sensitive 
Hygroscopic
CAS DataBase Reference
1235-21-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-S24/25-S22-60-37-26
WGK Germany 
3
RTECS 
TA1841000
F 
3
HS Code 
29319019
Toxicity
mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01535,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.41028
Product name
Acetonyltriphenylphosphonium chloride
Purity
for synthesis
Packaging
25g
Price
$110
Updated
2023/01/07
TCI Chemical
Product number
A1305
Product name
Acetonyltriphenylphosphonium Chloride
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$37
Updated
2024/03/01
Alfa Aesar
Product number
A14691
Product name
Acetonyltriphenylphosphonium chloride, 99%
Packaging
25g
Price
$38.65
Updated
2024/03/01
Alfa Aesar
Product number
A14691
Product name
Acetonyltriphenylphosphonium chloride, 99%
Packaging
100g
Price
$129.65
Updated
2024/03/01
Alfa Aesar
Product number
A14691
Product name
Acetonyltriphenylphosphonium chloride, 99%
Packaging
500g
Price
$485.65
Updated
2024/03/01
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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

WHITE TO SLIGHTLY BEIGE FINE CRYSTALLINE POWDER

Uses

Acetonyltriphenylphosphonium chloride is used to investigate the antimycobacterial activities of Me alkenyl quinolones. It is used as a reactant for synthesis of unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination.

Uses

Used to investigate the antimycobacterial activities of Me alkenyl quinolones

Reactant for synthesis of:

  • Unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination
  • Fused oxygen and nitrogen heterocycles via regioselective cyclocondensation

Reactant for Wittig olefinations

Purification Methods

Recrystallise it from CHCl3/*C6H6/pet ether (b 60-80o) or by dissolving it in CHCl3 and pouring it into dry Et2O. max nm() 255(3,600), 262(3,700), 268(4,000) and 275(3,100). The iodide salt crystallises from H2O and has m 207-209o. [Ramirez & Dershowitz J Org Chem 22 41 1957.] Itisan IRRITANT and is hygroscopic. When shaken with a 10% aqueous solution of Na2CO3 (8hours) it gives acetylmethylene triphenyl phosphorane which is recrystallised from MeOH/H2O and after drying at 70o/0.1mm has m 205-206o. UV: nm() 268 (6600), 275 (6500) and 288 (5700), IR: max 1529 (s), 1470 (m), 1425 (s), max 1374 (m), 1105 and 978 (s) (cm-1). [Ramirez & Dershowitz J Org Chem 22 41, 44 1957, Beilstein 16 H 761, 16 II 373.]

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Suppliers

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View Lastest Price from ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Acetonyltriphenylphosphonium chloride 1235-21-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-23
Henan Aochuang Chemical Co.,Ltd.
Product
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE 1235-21-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
Acetonyltriphenylphosphonium chloride 1235-21-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

1235-21-8, ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDERelated Search:

Acetyl-D-2-aminobutyric acid (ACETYLACETONATO)DICARBONYLIRIDIUM(I) AC-NLE-OH Benfotiamine Benzotriazole-1-yl-oxytripyrrolidinophosphonium hexafluorophosphate Acetone (3-ETHOXYCARBONYL-2-OXOPROPYL)TRIPHENYLPHOSPHONIUM CHLORIDE 3-CHLORO-2-OXOPROPYL TRIPHENYLPHOSPHONIUM CHLORIDE BENZOYLMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE AURORA KA-1161 AURORA KA-411 ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE

  • acetonyltriphenyl-phosphoniuchloride
  • (2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE
  • ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
  • AURORA KA-1148
  • ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%
  • Acetonyltriphenylphosphonium chloride,99%
  • OxopropyltriphenylphosphoniuM chlorid
  • 2-Oxopropyltriphenylphosphonium chloride 98%
  • Acetonyltriphenylphosphonium chloride for synthesis
  • 2-oxopropyl(triphenyl)phosphanium chloride
  • (Acetylmethylene)triphenylphosphoniumchloride
  • Acetonyltriphenylphosphonium Chloride &gt
  • Phosphonium, (2-oxopropyl)triphenyl-, chloride (1:1)
  • 1235-21-8
  • C21H20OP
  • CH3COCH2PClC6H53
  • C21H20CIOP
  • C21H20ClOP
  • C21H20OPCl
  • C-C Bond Formation
  • Olefination
  • Synthetic Reagents
  • Wittig Reagents
  • Phosphonium Compounds
  • Wittig Reaction
  • Wittig & Horner-Emmons Reaction
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction