ChemicalBook > CAS DataBase List > (R)-(+)-1-Phenylethylamine

(R)-(+)-1-Phenylethylamine

Product Name
(R)-(+)-1-Phenylethylamine
CAS No.
3886-69-9
Chemical Name
(R)-(+)-1-Phenylethylamine
Synonyms
(R)-1-phenylethan-1-amine;(R)-1-PHENYLETHYLAMINE;(1R)-1-PHENYLETHANAMINE;(R)-1-phenethylamine;(R)-ALPHA-METHYLBENZYLAMINE;(+)-PEA;(2S,α(R)-(+)-1-PhenyL;D-PHENYLETHYLAMINE;D-α-Phenethylamine
CBNumber
CB5429141
Molecular Formula
C8H11N
Formula Weight
121.18
MOL File
3886-69-9.mol
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(R)-(+)-1-Phenylethylamine Property

Melting point:
-10 °C
alpha 
40 º (neat)
Boiling point:
187-189 °C(lit.)
Density 
0.952 g/mL at 20 °C(lit.)
vapor pressure 
0.5 mm Hg ( 20 °C)
refractive index 
n20/D 1.526(lit.)
Flash point:
175 °F
storage temp. 
2-8°C
solubility 
40g/l
form 
Liquid
pka
9.04±0.10(Predicted)
color 
Clear colorless
PH
>7 (40g/l, H2O, 20℃)
optical activity
[α]23/D +38°, neat
Water Solubility 
40 g/L (20 ºC)
Sensitive 
Air Sensitive
Merck 
14,6026
BRN 
2410916
InChIKey
RQEUFEKYXDPUSK-SSDOTTSWSA-N
LogP
1.31-1.49 at 25℃
CAS DataBase Reference
3886-69-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanamine, «alpha»-methyl-, (R)-(3886-69-9)
EPA Substance Registry System
Benzenemethanamine, .alpha.-methyl-, (.alpha.R)- (3886-69-9)
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Safety

Hazard Codes 
C
Risk Statements 
21/22-34
Safety Statements 
26-28-36/37/39-45-28A-27
RIDADR 
UN 2735 8/PG 2
WGK Germany 
3
F 
3-10-23-34
Autoignition Temperature
355 °C DIN 51794
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29214980
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.07031
Product name
(R)-(+)-1-Phenylethylamine
Purity
for the resolution of racemates for synthesis
Packaging
10ml
Price
$31
Updated
2024/03/01
Sigma-Aldrich
Product number
Y0001962
Product name
Levetiracetam impurity E
Purity
European Pharmacopoeia (EP) Reference Standard
Packaging
Y0001962
Price
$152
Updated
2024/03/01
Sigma-Aldrich
Product number
8.07031
Product name
(R)-(+)-1-Phenylethylamine
Purity
for the resolution of racemates for synthesis
Packaging
100mL
Price
$181
Updated
2024/03/01
Sigma-Aldrich
Product number
115541
Product name
(R)-(+)-α-Methylbenzylamine
Purity
98%
Packaging
10ml
Price
$73.2
Updated
2024/03/01
Sigma-Aldrich
Product number
115541
Product name
(R)-(+)-α-Methylbenzylamine
Purity
98%
Packaging
25ml
Price
$113
Updated
2024/03/01
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(R)-(+)-1-Phenylethylamine Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(+)-1-Phenylethylamine is a chiral amine used for the determination of the enantiomeric purity of acids.

Uses

(R)-(+)-a-Methylbenzylamine also known as (R)-(+)-1-Phenylethylamine may be used in resolution of a chiral arylalkylamine involving high-conversion enantioselective condensation with capric acid followed by hydrolysis to yield corresponding (R)-(+)-amide.

Definition

ChEBI: The (R)-enantiomer of 1-phenylethanamine.

General Description

(R)-(+)-α-Methylbenzylamine is a chiral amine.

Flammability and Explosibility

Non flammable

Purification Methods

Dissolve the amine in toluene, dry over NaOH and distil; fraction boiling at 187-188o/atm is collected. Store it under N2 to avoid forming the carbamate and urea. Similarly for the S-(-) enantiomer [2627-86-3]. [Ingersoll Org Synth Coll Vol II 503 1943, Robinson & Snyder Org Synth Coll Vol III 717 1955, Beilstein 12 IV 2424, 2425.]

(R)-(+)-1-Phenylethylamine Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-Bis[(R)-1-phenylethyl]amine (R)-(+)-2-Methyl-2-propanesulfinamide (R)-(+)-1,1'-Bi-2-naphthol DL-alpha-Methylbenzylamine (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE (S)-(-)-1,1'-Bi-2-naphthol (S)-3-Aminoquinuclidine dihydrochloride (R)-(+)-BORNYLAMINE (R)-PIPERAZINE-2-CARBOXYLIC ACID
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View Lastest Price from (R)-(+)-1-Phenylethylamine manufacturers

Jinan Finer Chemical Co., Ltd
Product
(R)-(+)-1-Phenylethylamine 3886-69-9
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
2000MT
Release date
2022-04-13
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
(R)-(+)-1-Phenylethylamine 3886-69-9
Price
US $99.00-66.00/kg
Min. Order
0.0010000000474974513kg
Purity
99%
Supply Ability
5000
Release date
2024-08-19
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
(R)-(+)-1-Phenylethylamine 3886-69-9
Price
US $180.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-06-05

3886-69-9, (R)-(+)-1-PhenylethylamineRelated Search:

(n)-1-phenylethylamine,a-Phenylethylamine95%,DL-Phenylethylamine, 98%,DL-1-Phenylethylamine=(-ALPHA-Methylbenzylamine Benzylamine Levetiracetam impurity 1 2-Hexenamide, 2-cyano-5-methyl- Hexanoic acid,3-(aminomethyl)-5-methyl-, (3R)- 2,4-Dicyano-3-(2-Methylpropyl)-pentanediaMide 3-((methoxycarbonyl)methyl)-5-methylhexanoic acid 4,9-diisobutyl-1,6-diazecane-2,7-dione Isovaleraldehyde Pregabalin Impurity PD0224377 Pregabalin Impurity 49 4-Isobutyl-2-pyrrolidinone PD 312236 Pregabalin Impurity 28 Pregabalin Impurity D: Pregabalin-2-ene (S)-Pregabalin Methyl Ester 2-ISOBUTYL SUCCINIC ACID (R)-(-)-3-Carbamoymethyl-5-methylhexanoic acid

  • (1R)-1-PHENYLETHANAMINE
  • (1R)-1-PHENYLETHYLAMINE
  • (+)-D-ALPHA-METHYLBENZYLAMINE
  • D(+)-ALPHA-METHYLBENZYLAMINE
  • D-ALPHA-METHYLBENZYLAMINE
  • D-(+)-ALPHA-PHENYLETHYLAMINE
  • D-ALPHA-PHENYLETHYLAMINE
  • D-(+)-A-METHYLBENZYLAMINE
  • D-(+)-ALPHA-AMINOETHYLBENZENE
  • D-(+)-1-PHENYLETHYLAMINE
  • D-PHENYLETHYLAMINE
  • (R)-alpha-Methylbenzenemethanamine
  • (theta)-benzenemethanamin
  • R(+)-a-phenylethylamine
  • R(+)-α-phenylethylamine
  • (R)-(+)-α-Methylbenzylamine
  • (R)-(+)-1-PHENYLETHANAMINE
  • (R)-(+)-1-PHENYLETHYLAMINE
  • (R)-1-PHENYLETHYLAMINE
  • (R)-(+)-1-METHYLBENZYLAMINE
  • (R)(+)-ALPHA-PHENETHYLAMINE
  • R-(+)-ALPHA-PHENYLETHYLAMINE
  • (R)-(+)-A-METHYLBENZYLAMINE
  • (R)-(+)-ALPHA-METHYLBENZYLAMINE
  • (R)-ALPHA-METHYLBENZYLAMINE
  • R-ALFA-METHYLBENZYLAMINE
  • (R)-(+)-1-Phenylethylamine, 99%, ee 99+%
  • (R)-α-Methylbenzylamine,99%e.e.
  • (R)-(+)-1-Phenylethylamine for the resolution of racemates for synthesis
  • (R)-(+)-alpha-Methylbenzylamine ChiPros(R), produced by BASF, >=99.0%
  • (R)-(+)-alpha-Methylbenzylamine purum, >=98.0% (sum of enantiomers, GC)
  • R (+) - α- phenethylamine (D - (+) - α- methylbenzylamine)
  • (R)-(+)-<ALPHA>-METHYLBENZYLAMIN
  • (R)-(+)-1-PHENYLETHYLAMINE FOR THE RESOLUTION OF RACEMATES 99+%
  • ( R)-(+)-1-PHENYLETHYLAMINE, EE: 99%
  • D-α-Phenethylamine
  • (R)-(+)-1-Phenylethylamine, produced by BASF AG, 99+%
  • D(+)-alpha-Methylbenzylamine, 99+%, (99% ee)
  • (R)-(+)-1-Phenylethylamine, ChiPros\(tm, 99+%, ee 99+%
  • (R)-(+)-α-Methylbenz
  • (+)-a-Phenethylamine
  • (R)-(+)-1-PhenylethylaMine, Produced by Basfag AG
  • R(+)-α-phenylethylaMine (PhenethylaMine)
  • D(+)-alpha-MethylbenzylaMine, 99+%, (99% ee) 25GR
  • D(+)-alpha-MethylbenzylaMine, 99+%, (99% ee) 5GR
  • (αR)-α-Methyl-benzeneMethanaMine
  • (R)-(+)-1-PHENYLETHYLAMINE FOR THE RESOL
  • Pregabalin IMpurity II
  • R(+)-α-phenylethylaMine, R(+)-α-MethylbenzylaMine
  • BenzeneMethanaMine, a-Methyl-, (aR)-
  • (R)-(+)-1-PhenylethylaMine, 99.0%(GC)
  • R(+)-a- phenylethylamine , R(+)-a-methylbenzylamine
  • (R) -(+)-α-methylbenzylamine ((R)-(+)-1-phenylethylamine)
  • (aR)-a-Methyl-benzenemethanamine
  • (R)-(+)-a-Methylbenzamine
  • (R)-1-Amino-1-phenylethan
  • Benzenemethanamine, .alpha.-methyl-, (.alpha.R)-
  • d-(+)-à-methylbenzylamine