ChemicalBook > CAS DataBase List > 2-Methylresorcinol

2-Methylresorcinol

Product Name
2-Methylresorcinol
CAS No.
608-25-3
Chemical Name
2-Methylresorcinol
Synonyms
1,3-Benzenediol, 2-methyl-;2,6-DIHYDROXYTOLUENE;2-methyl-3-benzenediol;2-METHYL-1,3-BENZENEDIOL;1,3-Dihydroxy-2-methylbenzene;2-methyl-1,3-dihydroxybenzene;2-MR;Rodol MRP;2,6-Dihydr;JAROCOL 2MR
CBNumber
CB5431461
Molecular Formula
C7H8O2
Formula Weight
124.14
MOL File
608-25-3.mol
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2-Methylresorcinol Property

Melting point:
114-120 °C(lit.)
Boiling point:
264 °C(lit.)
Density 
1.1006 (rough estimate)
vapor pressure 
0.017Pa at 20℃
refractive index 
1.4922 (estimate)
Flash point:
135°C
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
263g/l
form 
Glassy Irregular Shaped Granules
pka
pK1:10.05;pK2:11.64 (25°C,μ=0.65)
color 
White
Water Solubility 
Soluble in water and methanol.
BRN 
2042177
InChIKey
ZTMADXFOCUXMJE-UHFFFAOYSA-N
LogP
1.58 at 25℃
CAS DataBase Reference
608-25-3(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Benzenediol, 2-methyl-(608-25-3)
EPA Substance Registry System
1,3-Benzenediol, 2-methyl- (608-25-3)
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Safety

Hazard Codes 
T,C
Risk Statements 
25-36/37/38-34-20/21/22
Safety Statements 
26-36-45-37/39-28A-36/37/39-27
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
RTECS 
VH2009500
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29072900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H317May cause an allergic skin reaction

H318Causes serious eye damage

H400Very toxic to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
302589
Product name
2-Methylresorcinol
Purity
98%
Packaging
25g
Price
$78.1
Updated
2024/03/01
Sigma-Aldrich
Product number
302589
Product name
2-Methylresorcinol
Purity
98%
Packaging
100g
Price
$199
Updated
2024/03/01
TCI Chemical
Product number
M0425
Product name
2-Methylresorcinol
Purity
>98.0%(GC)
Packaging
25g
Price
$107
Updated
2024/03/01
TCI Chemical
Product number
M0425
Product name
2-Methylresorcinol
Purity
>98.0%(GC)
Packaging
100g
Price
$266
Updated
2024/03/01
Alfa Aesar
Product number
A11821
Product name
2-Methylresorcinol, 98%
Packaging
50g
Price
$39.1
Updated
2024/03/01
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2-Methylresorcinol Chemical Properties,Usage,Production

Chemical Properties

White to off-white crystal powder

Uses

2-Methylresorcinol is used in the preparation of aromatic benziporphyrins, tripyrrane analogs and C-5-bromo-2-hydroxyphenylcalix[4]-2-methylresorcinarene. Further, it is employed in oxidative and non-oxidative hair dye formulations.

Application

2-Methylresorcinol is used as medicine, pesticide, dye intermediate, hair auxiliaries, etc.

Preparation

Synthesis of 2-methylresorcinol: The synthetic routes to an alkylresorcinol that is partially alkylated at a position other than the 4th position on the aromatic ring are multistep and give low overall yields. For example, a 50% yield of a 2-methylresorcinol is obtained by hydrogenation of resorcinol and methylation of the resulting dihydroresorcinol to 2-methylcyclohexane-1,3-dione which on treatment with bromine is converted into 4,6-dibromo-2-methylresorcinol and finally hydrogenolysis of the dibromo derivative to produce the 2-methylresorcinol. Another example is that 5-methylresorcinol can be prepared by a five-step synthesis starting with p-toluidine or a four-step synthesis starting from ethyl crotonate. The five-step synthesis involves acetylation, two-step nitration, reductive hydrogenation, and hydrolysis.
Literature source US04086281

General Description

The reaction between 2-methylresorcinol and 2-alkenals was studied to investigate the scavenging ability of m-diphenols for the 2-alkenals formed during lipid oxidation.

Flammability and Explosibility

Non flammable

2-Methylresorcinol Preparation Products And Raw materials

Raw materials

Preparation Products

TRIOXSALEN
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2-Methylresorcinol Suppliers

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View Lastest Price from 2-Methylresorcinol manufacturers

Jinan Finer Chemical Co., Ltd
Product
2-Methylresorcinol 608-25-3
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
200MT
Release date
2021-12-24
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
2-Methylresorcinol 608-25-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-06
Baoji Guokang Bio-Technology Co., Ltd.
Product
2-Methylresorcinol 608-25-3
Price
US $380.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1-10mt
Release date
2021-06-03

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