2-Methyl anthraquinone

Product Name: 2-Methyl anthraquinone
CAS No.: 84-54-8
Chemical Name: 2-Methyl anthraquinone
Synonyms: 2-METHYLANTHRAQUINONE;TECTOQUINONE;2-Methyl-9,10-anthraquinone;Tectochinon;2-methylanthracene-9,10-dione;2-METHYL AQ;Techtoquinone;CH3C6H3COC6H4CO;Methylanthraquinone;9,10-Antracenedione
CBNumber: CB5472864
Molecular Formula: C15H10O2
Formula Weight: 222.24
MOL File: 84-54-8.mol

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2-Methyl anthraquinone Property

Melting point:: 170-173 °C (lit.)
Boiling point:: 236-238 °C/10 mmHg (lit.)
Density: 1.1404 (rough estimate)
vapor pressure: 0Pa at 25℃
refractive index: 1.6600 (estimate)
Flash point:: 209 °C
storage temp.: 2-8°C
solubility: Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form: powder to crystal
color: Light orange to Yellow to Green
Water Solubility: Soluble in water 1.234 mg/L @ 25°C.
Merck: 14,6021
BRN: 2050523
InChIKey: NJWGQARXZDRHCD-UHFFFAOYSA-N
LogP: 3.4 at 25℃
CAS DataBase Reference: 84-54-8(CAS DataBase Reference)
NIST Chemistry Reference: 9,10-Anthracenedione, 2-methyl-(84-54-8)
EPA Substance Registry System: 2-Methylanthraquinone (84-54-8)

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Safety

Hazard Codes: Xi,N
Risk Statements: 51/53
Safety Statements: 22-24/25-61
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
Hazard Note: Irritant
TSCA: Yes
HS Code: 29146990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 65800
Product name: 2-Methylanthraquinone
Purity: technical, ≥95% (HPLC)
Packaging: 100g
Price: $68.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 65800
Product name: 2-Methylanthraquinone
Purity: technical, ≥95% (HPLC)
Packaging: 500g
Price: $260
Updated: 2024/03/01

TCI Chemical

Product number: M0156
Product name: 2-Methylanthraquinone
Purity: >99.0%(GC)
Packaging: 25g
Price: $42
Updated: 2024/03/01

TCI Chemical

Product number: M0156
Product name: 2-Methylanthraquinone
Purity: >99.0%(GC)
Packaging: 500g
Price: $427
Updated: 2022/04/27

Alfa Aesar

Product number: A14502
Product name: 2-Methylanthraquinone, 97%
Packaging: 50g
Price: $28.65
Updated: 2024/03/01

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2-Methyl anthraquinone Chemical Properties,Usage,Production

Chemical Properties

YELLOW TO GREEN-YELLOW FINE POWDER

Uses

2-Methylanthraquinone is used as a pharmaceutical intermediate. It is used in smog dyes.
2-Methylanthraquinone may be used in the preparation of potential bioreducible anthraquinone derivatives.

Definition

ChEBI: 2-methylanthraquinone is an anthraquinone that is 9,10-anthraquinone in which the hydrogen at position 2 is substituted by a methyl group. It derives from a 9,10-anthraquinone.

Reactions

The compound is produced by the reaction of phthalic anhydride and toluene. It can be chlorinated to give 1-chloro-2-methylanthraquinone. Nitration gives 1-nitro-2-methylanthraquinone, which can be reduced to 1-amino-2-methyl derivative. Oxidation of the methyl group gives anthraquinone-2-carboxylic acid.

Synthesis Reference(s)

Canadian Journal of Chemistry, 44, p. 2881, 1966 DOI: 10.1139/v66-428

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 1, p. 353, 1941
Tetrahedron Letters, 24, p. 5499, 1983 DOI: 10.1016/S0040-4039(00)94122-4

Flammability and Explosibility

Not classified

Purification Methods

Crystallise the quinone from EtOH, then sublime it. It has max at 257, 275 and 330nm (EtOH). [Hersbery & Fieser J Am Chem Soc 63 2562 1941, Beilstein 7 H 809, 7 III 4104, 7 IV 2574.]

2-Methyl anthraquinone Preparation Products And Raw materials

Raw materials

FUMING SULFURIC ACID Aluminum chloride Phthalic anhydride 2-(4-Methylbenzoyl)benzoic acid

Preparation Products

Emodin Vat Orange 9 SOLWAY BLUE RN

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2-Methyl anthraquinone Suppliers

Americas 1 Belgium 1 China 307 Europe 1 Germany 4 India 10 Japan 3 Norway 1 Slovakia 1 Switzerland 1 United Kingdom 9 United States 22 USA 1 Global 362

Shanghai Chemical Pharm-Intermediate Tech.Co., Ltd.

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Henan Puhui Tiancheng Biotechnology Co., Ltd

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WUHAN BIOCATA BIOLOGICAL TECHNOLOGY CO,.LTD

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Jinan Finer Chemical Co., Ltd

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Country: China
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J & K SCIENTIFIC LTD.

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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Alfa Aesar

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TAIYUAN RHF CO.,LTD.

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
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ProdList: 44689
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View Lastest Price from 2-Methyl anthraquinone manufacturers

Jinan Finer Chemical Co., Ltd

Product: 2-Methyl anthraquinone 84-54-8
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 500mt/year
Release date: 2024-05-17

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Tectoquinone/2-Methyl anthraquinone 84-54-8
Price: US $120.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-04-25

Hebei Weibang Biotechnology Co., Ltd

Product: 2-Methyl anthraquinone 84-54-8
Price: US $1.00/PCS
Min. Order: 1PCS
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-30

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Dicarbomethoxyzinc dihydrate

4'-ethyl-2,3-difluoro-4-(4-propylcyclohexyl)-1,1'-biphenyl

Tectoquinone/2-Methyl anthraquinone

2-Methylanthraquinone in isooctane

84-54-8

85-54-8

C6H4CO2C6H4CH3

Anthraquinones

Chloroanthraquine, etc.

Building Blocks

Carbonyl Compounds

C15 to C38

Ketones

Organic Building Blocks

commercial

Anthraquinones, Hydroquinones and Quinones

Anthraquinones

Chloroanthraquine, etc.

C15 to C38

Carbonyl Compounds