Triphenylsulfonium nonaflate
- Product Name
- Triphenylsulfonium nonaflate
- CAS No.
- 144317-44-2
- Chemical Name
- Triphenylsulfonium nonaflate
- Synonyms
- TPS-PFBS;Triphenylsulfonium nonaflate;TRIPHENYLSULFONIUM PERFLUORO-1-;TRIPHENYLSULFONIUM PERFLUORO-1-BUTANESUL;Triphenylsulfonium perfluoro-1-butanesufonate;Triphenylsulfonium nonafluorobutane-1-sulfonate;Triphenylsulfonium perfluoro-1-butanesufonate;Triphenylsulfonium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate;Triphenyl-sulfonium-1,1,2,2,3,3,4,4,4-nonafluoro-1-butane- sulfonate;TriphenylsulfoniuM perfluoro-1-butanesufonate electronic grade, >=99%
- CBNumber
- CB5500277
- Molecular Formula
- C22H15F9O3S2
- Formula Weight
- 562.46
- MOL File
- 144317-44-2.mol
Triphenylsulfonium nonaflate Property
- Melting point:
- 84-88 °C (lit.)
- solubility
- PGMEA: ~50%
- InChI
- InChI=1S/C18H15S.C4HF9O3S/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h1-15H;(H,14,15,16)/q+1;/p-1
- InChIKey
- VLLPVDKADBYKLM-UHFFFAOYSA-M
- SMILES
- [S+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.C(F)(F)(C(F)(F)S([O-])(=O)=O)C(F)(F)C(F)(F)F
- EPA Substance Registry System
- Sulfonium, triphenyl-, salt with 1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonic acid (1:1) (144317-44-2)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 531057
- Product name
- Triphenylsulfonium perfluoro-1-butanesufonate
- Purity
- electronic grade, ≥99%
- Packaging
- 1g
- Price
- $311
- Updated
- 2024/03/01
- Product number
- 531057
- Product name
- Triphenylsulfonium perfluoro-1-butanesufonate
- Purity
- electronic grade, ≥99%
- Packaging
- 5g
- Price
- $1000
- Updated
- 2023/06/20
- Product number
- O607
- Product name
- Triphenylsulfoniumnonaflate
- Packaging
- 5g
- Price
- $1115
- Updated
- 2021/12/16
- Product number
- ING0001068
- Product name
- TRIPHENYLSULPHONIUM NONAFLATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1472.28
- Updated
- 2021/12/16
- Product number
- ING0001068
- Product name
- TRIPHENYLSULPHONIUM NONAFLATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $805.27
- Updated
- 2021/12/16
Triphenylsulfonium nonaflate Chemical Properties,Usage,Production
Uses
Cationic photoinitiator. Photoacid generator.
Synthesis
Add a mixed compound solvent ethyl acetate and water solution into a 1L four-neck flask equipped with a stirring blade, condenser tube, and thermometer, and turn on the stirring. Add triphenylthiobromide to the system, slowly add sodium perfluorobutane sulfonate to the reaction system, and raise the temperature to 60°C. Incubate the reaction for 9 hours, monitor its progress, take samples to detect completion, and cool it to 0-5°C—centrifugation to obtain wet crude triphenyl sulfur perfluorobutane sulfonium salt. The crude product was recrystallized with a mixed solution of n-butanol and water under stirring at 85°C for 40min, and after cooling to 0-5°C, the obtained solid was dried below 80°C to obtain 150.32g of solid product. The product yield was 81.17%.
Triphenylsulfonium nonaflate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Triphenylsulfonium nonaflate manufacturers
- Product
- Triphenyl sulfonium Perfluoro-1-Butanesufonate; Triphenyl sulfonium Nonaflate 144317-44-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 20KG
- Purity
- 99.50%
- Supply Ability
- 20 TON
- Release date
- 2023-03-14
- Product
- Triphenylsulfonium nonaflate 144317-44-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-08-09