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Triphenylsulfonium nonaflate

Product Name
Triphenylsulfonium nonaflate
CAS No.
144317-44-2
Chemical Name
Triphenylsulfonium nonaflate
Synonyms
TPS-PFBS;Triphenylsulfonium nonaflate;TRIPHENYLSULFONIUM PERFLUORO-1-;TRIPHENYLSULFONIUM PERFLUORO-1-BUTANESUL;Triphenylsulfonium perfluoro-1-butanesufonate;Triphenylsulfonium nonafluorobutane-1-sulfonate;Triphenylsulfonium perfluoro-1-butanesufonate;Triphenylsulfonium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate;Triphenyl-sulfonium-1,1,2,2,3,3,4,4,4-nonafluoro-1-butane- sulfonate;TriphenylsulfoniuM perfluoro-1-butanesufonate electronic grade, >=99%
CBNumber
CB5500277
Molecular Formula
C22H15F9O3S2
Formula Weight
562.46
MOL File
144317-44-2.mol
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Triphenylsulfonium nonaflate Property

Melting point:
84-88 °C (lit.)
solubility 
PGMEA: ~50%
InChI
InChI=1S/C18H15S.C4HF9O3S/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h1-15H;(H,14,15,16)/q+1;/p-1
InChIKey
VLLPVDKADBYKLM-UHFFFAOYSA-M
SMILES
[S+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.C(F)(F)(C(F)(F)S([O-])(=O)=O)C(F)(F)C(F)(F)F
EPA Substance Registry System
Sulfonium, triphenyl-, salt with 1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonic acid (1:1) (144317-44-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2930909899
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531057
Product name
Triphenylsulfonium perfluoro-1-butanesufonate
Purity
electronic grade, ≥99%
Packaging
1g
Price
$311
Updated
2024/03/01
Sigma-Aldrich
Product number
531057
Product name
Triphenylsulfonium perfluoro-1-butanesufonate
Purity
electronic grade, ≥99%
Packaging
5g
Price
$1000
Updated
2023/06/20
AK Scientific
Product number
O607
Product name
Triphenylsulfoniumnonaflate
Packaging
5g
Price
$1115
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0001068
Product name
TRIPHENYLSULPHONIUM NONAFLATE
Purity
95.00%
Packaging
5G
Price
$1472.28
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0001068
Product name
TRIPHENYLSULPHONIUM NONAFLATE
Purity
95.00%
Packaging
1G
Price
$805.27
Updated
2021/12/16
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Triphenylsulfonium nonaflate Chemical Properties,Usage,Production

Uses

Cationic photoinitiator. Photoacid generator.

Synthesis

Add a mixed compound solvent ethyl acetate and water solution into a 1L four-neck flask equipped with a stirring blade, condenser tube, and thermometer, and turn on the stirring. Add triphenylthiobromide to the system, slowly add sodium perfluorobutane sulfonate to the reaction system, and raise the temperature to 60°C. Incubate the reaction for 9 hours, monitor its progress, take samples to detect completion, and cool it to 0-5°C—centrifugation to obtain wet crude triphenyl sulfur perfluorobutane sulfonium salt. The crude product was recrystallized with a mixed solution of n-butanol and water under stirring at 85°C for 40min, and after cooling to 0-5°C, the obtained solid was dried below 80°C to obtain 150.32g of solid product. The product yield was 81.17%.

Triphenylsulfonium nonaflate Preparation Products And Raw materials

Raw materials

Preparation Products

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Triphenylsulfonium nonaflate Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from Triphenylsulfonium nonaflate manufacturers

Shanghai Z&T Chemical Co., Ltd
Product
Triphenyl sulfonium Perfluoro-1-Butanesufonate; Triphenyl sulfonium Nonaflate 144317-44-2
Price
US $0.00-0.00/KG
Min. Order
20KG
Purity
99.50%
Supply Ability
20 TON
Release date
2023-03-14
Career Henan Chemical Co
Product
Triphenylsulfonium nonaflate 144317-44-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2018-08-09

144317-44-2, Triphenylsulfonium nonaflateRelated Search:


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