Triphenylsulfonium Bromide
- Product Name
- Triphenylsulfonium Bromide
- CAS No.
- 3353-89-7
- Chemical Name
- Triphenylsulfonium Bromide
- Synonyms
- riphenylsulfanium,bromide;Triphenylsulfonium Bromid;TRIPHENYLSULFONIUM BROMIDE;Triphenyl sulphonium bromide
- CBNumber
- CB1705979
- Molecular Formula
- C18H15BrS
- Formula Weight
- 343.28
- MOL File
- 3353-89-7.mol
Triphenylsulfonium Bromide Property
- Melting point:
- 293 °C
- form
- powder to crystal
- color
- White to Almost white
- InChI
- InChI=1S/C18H15S.BrH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H/q+1;/p-1
- InChIKey
- VMJFYMAHEGJHFH-UHFFFAOYSA-M
- SMILES
- [S+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Br-]
- CAS DataBase Reference
- 3353-89-7
Safety
- HS Code
- 2930.90.2900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- T1609
- Product name
- Triphenylsulfonium Bromide
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $307
- Updated
- 2024/03/01
- Product number
- T1609
- Product name
- Triphenylsulfonium Bromide
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $1042
- Updated
- 2024/03/01
- Product number
- T1609
- Product name
- Triphenylsulfonium Bromide
- Purity
- >98.0%(T)
- Packaging
- 100mg
- Price
- $60
- Updated
- 2024/03/01
- Product number
- T809093
- Product name
- Triphenylsulfonium Bromide
- Packaging
- 10mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 9346AL
- Product name
- Triphenylsulfonium Bromide
- Packaging
- 5g
- Price
- $1371
- Updated
- 2021/12/16
Triphenylsulfonium Bromide Chemical Properties,Usage,Production
Uses
Triphenylsulfonium Bromide is used in the preparation of sulfonium salt photoacid generator for deep-UV microlithography.
Preparation
Triphenylsulfonium bromide synthesis: A 3.0 M solution of phenylmagnesium bromide in diethyl ether (50 ml, 0.15 mole) was distilled under vacuum with slow heating from 20° to 80°C. Benzene (40 ml) was added, followed by n-heptane (300 ml). The resulting mixture was stirred and a solution of diphenylsulfoxide 10.1 g, (0.050 mol), in benzene (60 ml) was added during 1 hour at 80°C. The mixture was stirred for 3 hours and cooled to room temperature. An 25% aqueous hydrobromic acid solution (180 ml) was slowly added to the reaction mixture (exotherm-). The layers were separated and the organic layer was extracted twice with 5% aqueous hydrobromic acid (2 x 30 ml). The combined aqueous extracts were extracted three times with dichloromethane (3×250 ml). The dichloromethane extracts were dried over magnesium sulfate, filtered and the organic solvent evaporated to leave triphenylsulfonium bromide (10.2 g, 60%), which was crystallized from dichloromethane/diethyl ether. M.p. 285-7°C.
Triphenylsulfonium Bromide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Triphenylsulfonium Bromide manufacturers
- Product
- Triphenylsulfonium Bromide 3353-89-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-07-18
- Product
- Triphenylsulfonium Bromide 3353-89-7
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- according to customer's requirements
- Release date
- 2023-05-11