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Triphenylsulfonium Bromide

Product Name
Triphenylsulfonium Bromide
CAS No.
3353-89-7
Chemical Name
Triphenylsulfonium Bromide
Synonyms
riphenylsulfanium,bromide;Triphenylsulfonium Bromid;triphenylsulfanium,bromide;TRIPHENYLSULFONIUM BROMIDE;Triphenyl sulphonium bromide;Sulfonium, triphenyl-, bromide (1:1)
CBNumber
CB1705979
Molecular Formula
C18H15BrS
Formula Weight
343.28
MOL File
3353-89-7.mol
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Triphenylsulfonium Bromide Property

Melting point:
293 °C
form 
powder to crystal
color 
White to Almost white
InChI
InChI=1S/C18H15S.BrH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H/q+1;/p-1
InChIKey
VMJFYMAHEGJHFH-UHFFFAOYSA-M
SMILES
[S+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Br-]
CAS DataBase Reference
3353-89-7
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Safety

HS Code 
2930.90.2900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T1609
Product name
Triphenylsulfonium Bromide
Purity
>98.0%(T)
Packaging
1g
Price
$299
Updated
2025/07/31
TCI Chemical
Product number
T1609
Product name
Triphenylsulfonium Bromide
Purity
>98.0%(T)
Packaging
5g
Price
$1016
Updated
2025/07/31
TCI Chemical
Product number
T1609
Product name
Triphenylsulfonium Bromide
Purity
>98.0%(T)
Packaging
100mg
Price
$58
Updated
2025/07/31
TRC
Product number
T809093
Product name
Triphenylsulfonium Bromide
Packaging
10mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
9346AL
Product name
Triphenylsulfonium Bromide
Packaging
5g
Price
$1371
Updated
2021/12/16
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Triphenylsulfonium Bromide Chemical Properties,Usage,Production

Chemical Properties

Di(4-tert-butylphenyl)iodide chloride is a white solid that is soluble in organic solvents such as ethanol and diethyl ether.

Uses

Triphenylsulfonium Bromide is used in the preparation of sulfonium salt photoacid generator for deep-UV microlithography.

Preparation

Triphenylsulfonium bromide synthesis: A 3.0 M solution of phenylmagnesium bromide in diethyl ether (50 ml, 0.15 mole) was distilled under vacuum with slow heating from 20° to 80°C. Benzene (40 ml) was added, followed by n-heptane (300 ml). The resulting mixture was stirred and a solution of diphenylsulfoxide 10.1 g, (0.050 mol), in benzene (60 ml) was added during 1 hour at 80°C. The mixture was stirred for 3 hours and cooled to room temperature. An 25% aqueous hydrobromic acid solution (180 ml) was slowly added to the reaction mixture (exotherm-). The layers were separated and the organic layer was extracted twice with 5% aqueous hydrobromic acid (2 x 30 ml). The combined aqueous extracts were extracted three times with dichloromethane (3×250 ml). The dichloromethane extracts were dried over magnesium sulfate, filtered and the organic solvent evaporated to leave triphenylsulfonium bromide (10.2 g, 60%), which was crystallized from dichloromethane/diethyl ether. M.p. 285-7°C.

Triphenylsulfonium Bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Triphenylsulfonium Bromide manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Triphenylsulfonium Bromide 3353-89-7
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-30
Shaanxi Dideu Medichem Co. Ltd
Product
Triphenylsulfonium Bromide 3353-89-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-07-18
Changzhou waston chemical technology Co.,Ltd
Product
Triphenylsulfonium Bromide 3353-89-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
according to customer's requirements
Release date
2023-05-11

3353-89-7, Triphenylsulfonium Bromide Related Search:


  • TRIPHENYLSULFONIUM BROMIDE
  • Triphenyl sulphonium bromide
  • Triphenylsulfonium Bromid
  • riphenylsulfanium,bromide
  • triphenylsulfanium,bromide
  • Sulfonium, triphenyl-, bromide (1:1)
  • 3353-89-7
  • C18H15BrS
  • Sulfonium Compounds
  • Iodonium Sulfonium & Oxonium Compounds
  • Iodonium Sulfonium & Oxonium Compounds
  • Sulfonium Compounds