ChemicalBook > CAS DataBase List > 2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE

2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE

Product Name: 2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE
CAS No.: 19225-92-4
Chemical Name: 2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE
Synonyms: AKOS BBS-00005326;2-Chloromethyl-1-methylimidazole;2-(Chloromethyl)-N-methylimidazole;1-Methyl-2-(chloromethyl)imidazole;2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE;1H-Imidazole,2-(chloromethyl)-1-methyl-;2-(ChloroMethyl)-1-Methyl-1H-iMidazole, >95%
CBNumber: CB5674114
Molecular Formula: C5H7ClN2
Formula Weight: 130.58
MOL File: 19225-92-4.mol

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2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE Property

Melting point:: 182-184°C
Boiling point:: 244℃
Density: 1.20
Flash point:: 101℃
storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: Solid
pka: 6.22±0.25(Predicted)

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 2933299090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC

Product number: C384285
Product name: 2-(Chloromethyl)-1-methyl-1H-imidazole
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 047785
Product name: 2-(Chloromethyl)-1-methyl-1H-imidazole
Purity: >95%
Packaging: 1g
Price: $233
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H32-5-H5
Product name: 2-(Chloromethyl)-1-methyl-1H-imidazole
Packaging: 100mg
Price: $96
Updated: 2021/12/16

Matrix Scientific

Product number: 047785
Product name: 2-(Chloromethyl)-1-methyl-1H-imidazole
Purity: >95%
Packaging: 500mg
Price: $144
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H32-5-H5
Product name: 2-(Chloromethyl)-1-methyl-1H-imidazole
Packaging: 1g
Price: $479
Updated: 2021/12/16

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2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE Chemical Properties,Usage,Production

Synthesis

17334-08-6

19225-92-4

General procedure for the synthesis of 1-methyl-2-chloromethylimidazole from 1-methyl-2-hydroxymethyl-1H-imidazole: 1.8 mL of thionyl chloride was slowly added dropwise to 1.12 g of 1-methyl-2-hydroxymethyl-1H-imidazole at 0 °C. The reaction mixture was stirred at 20 °C for 18 h. Then, the temperature was raised to 70 °C to continue the reaction for 2 h. The reaction was carried out at 20 °C. Upon completion of the reaction, the solvent was removed by concentration under reduced pressure and the target product 1-methyl-2-chloromethylimidazole was quantitatively obtained. 1H NMR data of the product (DMSO-d6, δ/ppm): 3.90 (s, 3H); 5.22 (s, 2H); 5.36 (t, 1H); 7.77 (d, 1H); 7.80 (d, 1H).

References

[1] Patent: US2007/185136, 2007, A1. Location in patent: Page/Page column 67
[2] Patent: WO2007/42545, 2007, A1. Location in patent: Page/Page column 18
[3] Journal of the Chemical Society, 1957, p. 3305
[4] Patent: US4746669, 1988, A
[5] Patent: WO2016/92326, 2016, A1. Location in patent: Paragraph 00802

2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE manufacturers

Career Henan Chemical Co

Product: 2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE 19225-92-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 150KG
Release date: 2019-07-09

19225-92-4, 2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLERelated Search:

1-BENZYL-2-(CHLOROMETHYL)-1H-IMIDAZOLE HCL 2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE 2-CHLOROMETHYL-1-METHYL-1H-IMIDAZOLE HCL,2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE HYDROCHLORIDE 8-CHLORO-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID alpha-(chloromethyl)-2-methyl-5-nitro-imidazole-1-ethan 2-(Chloromethyl)imidazole ETHYL 8-CHLORO-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLATE 1-BENZYL-2-CHLOROMETHYL-1H-BENZOIMIDAZOLE ethyl 6,8-dichloroimidazo[1,2-a]pyridine-2-carboxylate 1-BENZYL-2-CHLOROMETHYL-1H-BENZOIMIDAZOLE HYDROCHLORIDE 5-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE 5-CHLOROMETHYL-1-METHYL-1H-IMIDAZOLE HCL,4-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE 5-(Chloromethyl)-4-methyl-1H-imidazole hydrochloride 5-CHLORO-2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE HYDROCHLORIDE 8-CHLORO-2-(4-FLUOROPHENYL)-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE 8-Chloro-6-(trifluoromethyl)imidazo[1,2-a]pyridine-2-carbohydrazide 8-CHLORO-2-PHENYL-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE 3,8-DICHLORO-2-(4-METHOXYPHENYL)-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE

2-(CHLOROMETHYL)-1-METHYL-1H-IMIDAZOLE

AKOS BBS-00005326

1-Methyl-2-(chloromethyl)imidazole

2-(Chloromethyl)-N-methylimidazole

2-Chloromethyl-1-methylimidazole

2-(ChloroMethyl)-1-Methyl-1H-iMidazole, >95%

1H-Imidazole,2-(chloromethyl)-1-methyl-

19225-92-4

C5H7ClN2