2-Bromophenethylamine

Product Name: 2-Bromophenethylamine
CAS No.: 65185-58-2
Chemical Name: 2-Bromophenethylamine
Synonyms: RARECHEM AL BW 0201;2-BROMOPHENETHYLAMINE;2-Bromophenethanamine;2-bromophenylethyl amine;2-BroMophenethylaMine 97%;2-BroMo-benzeneethanaMine;2-Bromophenethylamine,99%;2-(2-bromophenyl)ethanamine;BENZENEETHANAMINE, 2-BROMO-;1-Amino-(2-bromophenyl)ethane
CBNumber: CB5716078
Molecular Formula: C8H10BrN
Formula Weight: 200.08
MOL File: 65185-58-2.mol

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2-Bromophenethylamine Property

Boiling point:: 253 °C(lit.)
Density: 1.396 g/mL at 25 °C(lit.)
refractive index: n20/D 1.5770(lit.)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Liquid
pka: 9.52±0.10(Predicted)
color: Clear colorless to slightly yellow
Sensitive: Air Sensitive
CAS DataBase Reference: 65185-58-2(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-27-36/37/39-45
RIDADR: UN 2735 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: Ⅱ
HS Code: 29214990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 534099
Product name: 2-Bromophenethylamine
Purity: 97%
Packaging: 10g
Price: $250
Updated: 2025/07/31

Sigma-Aldrich

Product number: 534099
Product name: 2-Bromophenethylamine
Purity: 97%
Packaging: 5g
Price: $147
Updated: 2023/06/20

TCI Chemical

Product number: B3938
Product name: 2-(2-Bromophenyl)ethylamine
Purity: >98.0%(T)
Packaging: 5g
Price: $119
Updated: 2025/07/31

TCI Chemical

Product number: B3938
Product name: 2-(2-Bromophenyl)ethylamine
Purity: >98.0%(T)
Packaging: 25g
Price: $354
Updated: 2025/07/31

TRC

Product number: B683640
Product name: 2-Bromophenylethylamine
Packaging: 25g
Price: $350
Updated: 2021/12/16

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2-Bromophenethylamine Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to slightly yellow liquid

Uses

2-(2-Bromophenyl)ethylamine is used as a pharmaceutical intermediate.

General Description

May darken in storage

Synthesis

19472-74-3

65185-58-2

The general procedure for the synthesis of o-bromophenethylamine from o-bromobenzyl cyanide was as follows: 1 M borane-tetrahydrofuran complex (BH3-THF, 200 mL, 0.2 mol) was slowly added dropwise to a solution of 2-bromobenzyl cyanide (20.0 g, 0.1 mol) in tetrahydrofuran (THF, 100 mL) at 0 °C for 30 min. Subsequently, the reaction mixture was heated to reflux for 24 hours. Upon completion of the reaction, the reaction was quenched with methanol (MeOH, 50 mL) and 6 M hydrochloric acid (HCl, 50 mL) at 0 °C, and then the mixture was heated and refluxed again for 4 hours. The reaction solution was concentrated under reduced pressure and the residue was diluted with distilled water (H2O, 300 mL) and washed with ethyl acetate (EA, 75 mL × 2). The aqueous layer was neutralized with 15% sodium hydroxide (NaOH) solution and then extracted with ethyl acetate (EA, 75 mL × 2). The organic layers were combined, dried with anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure to afford the target product o-bromophenethylamine (2a) as a yellow oil (17.4 g, 85.2% yield). High-resolution mass spectrometry (HRMS) calculated value C8H11NBr [M + H]+ 200.0069, measured value 200.0068. nuclear magnetic resonance hydrogen spectrum (1H NMR, 500 MHz, CDCl3) δ 7.58 (d, J = 8.0 Hz, 1H), 7.35-7.31 (m, 2H), 7.15 (t, J = 7.0 Hz, 1H). 2.79 (m, 4H), 1.18 (m, 2H). Nuclear magnetic resonance carbon spectrum (13C NMR, 125 MHz, DMSO-d6) δ 139.8,132.9,131.6,128.6,128.2,124.3,42.4,40.3.

References

[1] Journal of Organic Chemistry, 2008, vol. 73, # 24, p. 9627 - 9632
[2] Patent: US2002/198251, 2002, A1
[3] Tetrahedron, 1996, vol. 52, # 21, p. 7525 - 7546
[4] Tetrahedron, 1998, vol. 54, # 25, p. 7121 - 7126
[5] ChemCatChem, 2014, vol. 6, # 2, p. 538 - 546

2-Bromophenethylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromophenethylamine Suppliers

Americas 1 Belgium 1 China 153 Europe 1 Germany 2 India 5 Japan 1 Poland 1 Switzerland 2 Ukraine 1 United Kingdom 6 United States 24 Global 198

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View Lastest Price from 2-Bromophenethylamine manufacturers

LY Global chemicals co.,ltd .

Product: 2-Bromophenethylamine 65185-58-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98.0%
Supply Ability: 10000kg
Release date: 2023-03-30

Career Henan Chemical Co

Product: 2-(2-Bromophenyl)ethanamine 65185-58-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: Min98% HPLC
Supply Ability: g/kg/ton
Release date: 2020-02-03

65185-58-2, 2-BromophenethylamineRelated Search:

DL-ALPHA-METHYLBENZYLAMINE 2-BROMOACETAMIDE L-1-Phenylethylamine Tyramine 2-Phenylethylamine hydrochloride 4-Bromo-alpha-phenethylamine 2-Bromoaniline Methyl 2-bromobenzoate (S)-(-)-4-Bromo-alpha-phenylethylamine (R)-N-BOC-2-Bromophenylalanine 2-PhenylethylaMine 4-Bromo-5-methyl-2,3-indolinedione (S)-N-BOC-2-Bromophenylalanine FMOC-L-2-BROMOPHENYLALANINE D-2-Bromophenylalanine L-2-Bromophenylalanine FMOC-D-2-BROMOPHENYLALANINE DL-6'-BROMOLAUDANOSIN

RARECHEM AL BW 0201

BENZENEETHANAMINE, 2-BROMO-

2-BROMOPHENETHYLAMINE

2-(2-bromophenyl)ethanamine

2-bromophenylethyl amine

2-Bromophenethylamine,99%

2-BroMo-benzeneethanaMine

2-BroMophenethylaMine 97%

2-(2-BroMophenyl)ethanaMine, 98%+

2-(2-bromophenyl)ethylammonium

2-(2-Bromophenyl)ethylamine &gt

1-Amino-(2-bromophenyl)ethane

2-Bromophenethanamine

65185-58-2

Nitrogen Compounds

Organic Building Blocks

C8

Amines

Building Blocks

AMINE

Phenyls & Phenyl-Het

Amines

C8

Nitrogen Compounds

Halides

Phenyls & Phenyl-Het