POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

Synthesis

Product Name: POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
CAS No.: 166328-09-2
Chemical Name: POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
Synonyms: Potassium (3,5-bis(trifluoromethyl);POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&;[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE;Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate;potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui;Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%;Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%;potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001：2015 REACH
CBNumber: CB5731640
Molecular Formula: C8H3BF9K
Formula Weight: 320
MOL File: 166328-09-2.mol

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POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Property

Melting point:: >300℃
storage temp.: Inert atmosphere,Room Temperature

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
Hazard Note: Irritant
HS Code: 2931900090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 571563
Product name: Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
Packaging: 1g
Price: $59.8
Updated: 2023/06/20

Alfa Aesar

Product number: H53113
Product name: Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
Packaging: 1g
Price: $49.9
Updated: 2023/06/20

Alfa Aesar

Product number: H53113
Product name: Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
Packaging: 5g
Price: $205
Updated: 2023/06/20

TRC

Product number: P699195
Product name: Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
Packaging: 500mg
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: AMTB724
Product name: Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
Packaging: 1g
Price: $20
Updated: 2021/12/16

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POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Chemical Properties,Usage,Production

Synthesis

A solution of 3,5-bis(triflfluoromethyl)phenylboronic acid (10 g, 38.8 mmol) in methanol (15 mL) was added to an aqueous solution of KHF2 (4.5 M, 26 mL, 117 mmol) at room temperature. A heavy precipitate was deposited. The resulting suspension was stirred 148 MODERN ORGANIC SYNTHESIS IN THE LABORATORYfor 1 h at room temperature, and the precipitated product was collected and washed with methanol. Recrystallization from a minimum amount of acetone produced 11 g (89%) of potassium 3,5-bis(triflfluoromethyl)phenyltriflfluoroborate. Reference: Molander, G. A.; Biolatto, B. J. Org. Chem. 2003, 68, 4302−4314.

Uses

Thos chemical has been used for inserting a 3,5-bis(trifluoromethyl)phenyl group into the position of a halogen or triflate group of various arenes and various heterocycles in Pd-catalyzed Suzuli-Miyaura cross-coupling reactions.

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Suppliers

China 42 France 1 Germany 1 India 2 Switzerland 1 United Kingdom 1 United States 7 Global 55

J & K SCIENTIFIC LTD.

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166328-09-2, POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATERelated Search:

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potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%

Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%

Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&

Potassium (3,5-bis(trifluoromethyl)

Borate(1-), [3,5-bis(trifluoromethyl)phenyl]trifluoro-, potassium (1:1), (T-4)-

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001：2015 REACH

[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide

potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui

166328-09-2

C8H3BF9K

CF32C6H3BF3K

Organometallic Reagents

Trifluoroborate Salts

Boronic Acids and Derivatives

Aryl

Boronic Acids and Derivatives

Trifluoroborate Salts

blocks

Trifluoroborates

Molander Ates

Organoborons

Aryl Trifluoroborate Salts

Boronic Acids and Derivatives

Chemical Synthesis

Organometallic Reagents

Trifluoroborate Salts