ChemicalBook > CAS DataBase List > 2-CHLOROPHENETHYLALCOHOL

2-CHLOROPHENETHYLALCOHOL

Product Name
2-CHLOROPHENETHYLALCOHOL
CAS No.
19819-95-5
Chemical Name
2-CHLOROPHENETHYLALCOHOL
Synonyms
2-Chlorophenethanol;2-Chlorobenzeneethanol;2-chlorophenethylalchol;2-CHLOROPHENETHYLALCOHOL;2-(O-CHLOROPHENYL)ETHANOL;Benzeneethanol, 2-chloro-;2-(2-Chlorophenyl)ethanol;2-(2-Chlorophenyl)etnanol;o-chlorophenethylic alcohol;2-Chlorophenethylalcohol,98%
CBNumber
CB5732566
Molecular Formula
C8H9ClO
Formula Weight
156.61
MOL File
19819-95-5.mol
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2-CHLOROPHENETHYLALCOHOL Property

Boiling point:
84-85 °C/3 mmHg (lit.)
Density 
1.19 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.551(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
pka
14.72±0.10(Predicted)
Specific Gravity
1.19
color 
Clear colorless
InChI
InChI=1S/C8H9ClO/c9-8-4-2-1-3-7(8)5-6-10/h1-4,10H,5-6H2
InChIKey
IWNHTCBFRSCBQK-UHFFFAOYSA-N
SMILES
C1(CCO)=CC=CC=C1Cl
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29052900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
193844
Product name
2-Chlorophenethyl alcohol
Purity
98%
Packaging
5g
Price
$99.3
Updated
2023/06/20
TCI Chemical
Product number
C2169
Product name
2-(2-Chlorophenyl)ethanol
Purity
>97.0%(GC)
Packaging
1g
Price
$22
Updated
2025/07/31
TCI Chemical
Product number
C2169
Product name
2-(2-Chlorophenyl)ethanol
Purity
>97.0%(GC)
Packaging
5g
Price
$68
Updated
2025/07/31
TRC
Product number
C424280
Product name
2-(2-Chlorophenyl)ethanol
Packaging
50g
Price
$250
Updated
2021/12/16
AK Scientific
Product number
X8186
Product name
2-(2-Chlorophenyl)ethanol
Packaging
1g
Price
$20
Updated
2021/12/16
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2-CHLOROPHENETHYLALCOHOL Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

2-Chlorophenethyl alcohol may be used in the chemical synthesis of amines.

Definition

ChEBI: 2-Chlorophenethyl alcohol is an organochlorine compound.

Synthesis

2444-36-2

19819-95-5

The general procedure for the synthesis of 2-chlorophenylethanol from o-chlorophenylacetic acid was as follows: first, 20 g of o-chlorophenylacetic acid (o-S1) was dissolved in 200 ml of tetrahydrofuran, stirred and cooled to 0 °C. Subsequently, 8.9 g of lithium aluminum hydride was added in batches and Bi was added as a catalyst. The reaction mixture was warmed up to 25?30°C for the reaction. Upon completion of the reaction, the reaction was terminated by adding 300 ml of water and extracted with 400 ml of dichloromethane. After separation of the organic phase, 20 g of anhydrous sodium sulfate was added for drying. Concentration under reduced pressure at 30-35°C gave 18.3 g of light yellow oil (o-S1-1). Next, phosphorus tribromide was slowly added dropwise to the reaction vial containing o-S1-1 under ice bath conditions, controlling the dropwise temperature at 0-10 °C. After the dropwise addition, stirring was continued for 10 min until white smoke was generated. Subsequently, the reaction mixture was warmed up to 75~80°C and held at this temperature with stirring for 2 hours. Upon completion of the reaction, 30 ml of saturated sodium bicarbonate solution was added to neutralize the reaction and extracted with 200 ml of ethyl acetate. After separation of the organic phase, 20 g of anhydrous sodium sulfate was added for drying. Finally, it was concentrated under reduced pressure at 40?45 °C to give 22.4 g of yellow liquid (neighboring S2) in 87.0% yield.

References

[1] Journal of Medicinal Chemistry, 1981, vol. 24, # 6, p. 678 - 683
[2] Patent: US6342501, 2002, B1. Location in patent: Scheme 2
[3] Angewandte Chemie - International Edition, 2015, vol. 54, # 36, p. 10596 - 10599
[4] Angew. Chem., 2015, vol. 127, p. 10742 - 10745,4
[5] Journal of Organic Chemistry, 1964, vol. 29, p. 3175 - 3179

2-CHLOROPHENETHYLALCOHOL Preparation Products And Raw materials

Raw materials

Preparation Products

2-(2-CHLORO-PHENYL)-ETHANESULFONYL CHLORIDE
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2-CHLOROPHENETHYLALCOHOL Suppliers

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View Lastest Price from 2-CHLOROPHENETHYLALCOHOL manufacturers

Career Henan Chemical Co
Product
2-CHLOROPHENETHYLALCOHOL 19819-95-5
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-09
Career Henan Chemical Co
Product
Pigment Permanent Red F5RK 1211-16-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1kg-1000kg
Release date
2020-01-08

19819-95-5, 2-CHLOROPHENETHYLALCOHOLRelated Search:

2,4-Dichlorophenylacetic acid 2-Chlorophenylacetic acid 2,2'-DICHLOROBENZILIC ACID Methyl 2-chlorophenylacetate 2,6-DICHLOROPHENYLACETIC ACID METHYL ESTER 2,6-DICHLORO-4-(TRIFLUOROMETHYL)PHENYLACETIC ACID 2,4-DICHLOROPHENETHYL ALCOHOL Methyl 2,4-dichlorophenylacetate 2-CHLOROPHENETHYLALCOHOL CHLORFENAC DL-2-(2-Chlorophenyl)glycine 2-Chloromandelic acid 2-Chloro-6-fluorophenylacetic acid 2,3-Difluorophenylacetic acid OCHRATOXIN A 4,4'-DICHLORO-ALPHA-METHYLBENZHYDROL 1-(2,4-Dichlorophenyl)cyclopropane-1-carboxylic acid 2-(2-AMINO-6-CHLOROPHENYL)ETHAN-1-OL

  • 2-(O-CHLOROPHENYL)ETHANOL
  • 2-CHLOROPHENETHYLALCOHOL
  • o-chlorophenethylic alcohol
  • 2-CHLOROPHENETHYLALCOHOL 98%
  • 2-(2-Chlorophenyl)ethanol
  • Benzeneethanol, 2-chloro-
  • o-Chlorophenylmethylcarbinol
  • 2-(2-Chlorophenyl)etnanol
  • 2-Chlorobenzeneethanol
  • 2-Chlorophenethylalcohol,98%
  • 2-Chlorophenethanol
  • 2-Chlorophenethylalcohol, 98% 25GR
  • 2-(2-Chlorophenyl)ethan-1-ol
  • 2-(2-Chlorophenyl)ethanol &gt
  • 2-chlorophenethylalchol
  • 19819-95-5
  • ClC6H4CH2CH2OH
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