PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE
- Product Name
- PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE
- CAS No.
- 26822-37-7
- Chemical Name
- PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE
- Synonyms
- Nsc149999;N-Methyl-4-piperidone methodide;1,1-DIMETHYL-4-OXO-PIPERIDINIUM IODIDE;1,1-Dimethylpiperidin-1-ium-4-one iodide;1,1-DiMethyl-4-oxopiperidin-1-iuM iodide;1,1-Dimethyl-4-oxo-1-piperidinium iodide;PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE;N,N'-Dimethyl-4-oxopiperidine iodium salt, 97%
- CBNumber
- CB5839261
- Molecular Formula
- C7H14INO
- Formula Weight
- 255.09663
- MOL File
- 26822-37-7.mol
PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE Property
- Melting point:
- 174-179 °C (decomp)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Appearance
- White to off-white Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- CHM1007572
- Product name
- 1,1-DIMETHYL-4-OXO-PIPERIDINIUM IODIDE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $496.97
- Updated
- 2021/12/16
- Product number
- CM179451
- Product name
- 1,1-Dimethyl-4-oxopiperidin-1-iumiodide
- Purity
- 95%
- Packaging
- 25g
- Price
- $569
- Updated
- 2021/12/16
- Product number
- CD11155958
- Product name
- 1,1-Dimethyl-4-oxopiperidin-1-iumiodide
- Purity
- 95+%
- Packaging
- 25g
- Price
- $608
- Updated
- 2021/12/16
- Product number
- 26822377
- Product name
- 1,1-Dimethyl-4-oxopiperidin-1-iumiodide
- Packaging
- 25g
- Price
- $620.16
- Updated
- 2021/12/16
- Product number
- CD11155958
- Product name
- 1,1-Dimethyl-4-oxopiperidin-1-iumiodide
- Purity
- 95+%
- Packaging
- 1g
- Price
- $57
- Updated
- 2021/12/16
PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE Chemical Properties,Usage,Production
Synthesis
1445-73-4
74-88-4
26822-37-7
Step 1: Preparation of 1,1-dimethyl-4-oxopiperidinium iodide Iodomethane (1.6 mL, 26.5 mmol) was slowly added dropwise to an acetone solution (10 mL) of N-methyl-4-piperidone (2.0 g, 17.6 mmol) at 0 °C. The reaction mixture was stirred at room temperature for 1 hour. The resulting precipitate was collected by filtration and washed with cold acetone to afford 1,1-dimethyl-4-oxopiperidinium iodide as an off-white solid (4.0 g, 88% yield). Product characterization data: 1H NMR (D2O, 400 MHz): δ 3.38 (t, J = 5.8 Hz, 4H), 3.06 (s, 6H), 1.95-2.05 (m, 4H). LCMS (Method D): measured mass (M+ 128.2), retention time (Rt): 1.19 min, % peak area: 95.3% (maximum purity).
References
[1] Journal of Organic Chemistry, 2006, vol. 71, # 22, p. 8602 - 8609
[2] Journal of Organic Chemistry, 2014, vol. 79, # 8, p. 3358 - 3373
[3] Organic Process Research and Development, 2004, vol. 8, # 6, p. 939 - 941
[4] Angewandte Chemie - International Edition, 2008, vol. 47, # 32, p. 5968 - 5972
[5] Journal of the American Chemical Society, 2009, vol. 131, # 1, p. 357 - 367