ChemicalBook > CAS DataBase List > 3-Ethoxyacryloyl chloride

3-Ethoxyacryloyl chloride

Product Name
3-Ethoxyacryloyl chloride
CAS No.
6191-99-7
Chemical Name
3-Ethoxyacryloyl chloride
Synonyms
88.0%;3-EthoxyacryL;Ethoxyacryloylchloride;3-Oxopropenoylchloride;b-Ethoxyacrylic chloride;3-ETHOXYACRYLOYL CHLORIDE;3-Ethoxyacryloyl Chloride >3-Ethoxyacrylic acid chloride;3-ethoxyprop-2-enoyl chloride;(2E)-3-Ethoxyacryloyl chloride
CBNumber
CB5850789
Molecular Formula
C5H7ClO2
Formula Weight
134.56
MOL File
6191-99-7.mol
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3-Ethoxyacryloyl chloride Property

Boiling point:
75°C/10mmHg(lit.)
Density 
1.125±0.06 g/cm3(Predicted)
refractive index 
1.4860 to 1.4910
Flash point:
25 °C
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
InChI
InChI=1S/C5H7ClO2/c1-2-8-4-3-5(6)7/h3-4H,2H2,1H3
InChIKey
SFMFACMIOWQIPR-UHFFFAOYSA-N
SMILES
C(Cl)(=O)C=COCC
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Safety

Hazard Codes 
C
Risk Statements 
10-22-34-42/43
Safety Statements 
23-24-26-36/37/39-45
RIDADR 
UN2920 8/PG 2
WGK Germany 
3
HazardClass 
8/3
PackingGroup 
II
HS Code 
2909500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
691119
Product name
3-Ethoxy-acryloyl chloride
Purity
≥85% (H-NMR)
Packaging
250mg
Price
$349
Updated
2023/06/20
TCI Chemical
Product number
E1066
Product name
3-Ethoxyacryloyl Chloride
Purity
>88.0%(GC)
Packaging
5g
Price
$181
Updated
2025/07/31
TRC
Product number
E890908
Product name
3-Ethoxy-acryloyl chloride
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
E890908
Product name
3-Ethoxy-acryloyl chloride
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
E890908
Product name
3-Ethoxy-acryloyl chloride
Packaging
500mg
Price
$90
Updated
2021/12/16
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3-Ethoxyacryloyl chloride Chemical Properties,Usage,Production

Chemical Properties

light yellow liquid

Uses

Used as an intermediate in organic synthesis.

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 13, p. 1015, 1976 DOI: 10.1002/jhet.5570130515
Synthesis, p. 1079, 1993

Synthesis

To a solution of ethyl 3,3-diethoxypropionate (20 g) in water (50 mL) was added sodium hydroxide (5 g) at room temperature and the reaction was heated to 110°C and stirred at this temperature for 1 hour. Then the reaction system was naturally cooled to room temperature, diluted with water (2L), extracted with ethyl acetate (1L), the extract was washed with saturated brine (1L), dried over anhydrous sodium sulfate and filtered; the filtrate was directly concentrated to obtain To the crude was added thionyl chloride (30 mL) and the reaction was heated to 70°C and stirring was continued at this temperature for one hour. After the reaction, the reaction solution was directly concentrated under reduced pressure to obtain a brown solid 3-Ethoxyacryloyl chloride (14 g, yield 90%).

References

[1] Patent: WO2009/140342, 2009, A1. Location in patent: Page/Page column 118-119
[2] Patent: US2014/142114, 2014, A1. Location in patent: Paragraph 0464; 0465

3-Ethoxyacryloyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-Ethoxyacryloyl chloride manufacturers

Henan Fengda Chemical Co., Ltd
Product
(2E)-3-Ethoxyacryloyl chloride 6191-99-7
Price
US $5.00-0.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-13
Career Henan Chemical Co
Product
3-Ethoxyacryloyl chloride 6191-99-7
Price
US $150.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
20KG
Release date
2018-07-27

6191-99-7, 3-Ethoxyacryloyl chlorideRelated Search:

Methacryloyl chloride Sodium chloride 2-Ethoxyphenol Acryloyl chloride Ethoxyquin Ferric chloride Calcium chloride Potassium chloride DIETHOXYMETHANE 3-Ethoxyacrylonitrile Polyvinyl chloride Choline chloride Ammonium chloride Sulfuryl chloride Phenetidine Methylene Chloride 2-OXO-2H-PYRAN-5-CARBONYL CHLORIDE 3-Ethoxyacryloyl chloride

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