ChemicalBook > CAS DataBase List > Acryloyl chloride

Acryloyl chloride

Product Name
Acryloyl chloride
CAS No.
814-68-6
Chemical Name
Acryloyl chloride
Synonyms
prop-2-enoyl chloride;oyL;2-PROPENOYL CHLORIDE;acrylyl chloride;ACRYLIC ACID CHLORIDE;Propenoyl chloride;chloridkyselinyakrylove;Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole;propenoylchloride;ACRYLOYL CHLORIDE
CBNumber
CB4854427
Molecular Formula
C3H3ClO
Formula Weight
90.51
MOL File
814-68-6.mol
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Acryloyl chloride Property

Melting point:
76 °C(Solv: isopropyl ether (108-20-3))
Boiling point:
72-76 °C (lit.)
Density 
1.114 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
1.93 psi ( 20 °C)
refractive index 
n20/D 1.435(lit.)
Flash point:
61 °F
storage temp. 
2-8°C
solubility 
Chloroform (Soluble), Methanol (Slightly)
form 
Oil
color 
Colourless to Pale Yellow
Water Solubility 
Miscible with water.
Sensitive 
Moisture & Light Sensitive
BRN 
635744
Exposure limits
ACGIH: TWA 5 mg/m3 (Skin)
NIOSH: TWA 5 mg/m3
Stability:
Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
InChIKey
HFBMWMNUJJDEQZ-UHFFFAOYSA-N
CAS DataBase Reference
814-68-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoyl chloride(814-68-6)
EPA Substance Registry System
Acrylyl chloride (814-68-6)
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Safety

Hazard Codes 
F,T+
Risk Statements 
11-14-26-34
Safety Statements 
16-26-28-36/37/39-45-7/9
RIDADR 
UN 3383 6.1/PG 1
WGK Germany 
3
RTECS 
AT7350000
8-10
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29161980
Hazardous Substances Data
814-68-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H290May be corrosive to metals

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
549797
Product name
Acryloyl chloride
Purity
97.0%, contains <210ppm MEHQ as stabilizer
Packaging
5g
Price
$76.2
Updated
2024/03/01
Sigma-Aldrich
Product number
549797
Product name
Acryloyl chloride
Purity
97.0%, contains <210ppm MEHQ as stabilizer
Packaging
500g
Price
$646
Updated
2024/03/01
Alfa Aesar
Product number
L10363
Product name
Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
Packaging
10g
Price
$40.5
Updated
2021/12/16
Alfa Aesar
Product number
L10363
Product name
Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
Packaging
50g
Price
$60.6
Updated
2021/12/16
Sigma-Aldrich
Product number
A24109
Product name
Acryloyl chloride
Purity
≥97%, contains ~400ppm phenothiazine as stabilizer
Packaging
5g
Price
$66.7
Updated
2024/03/01
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Acryloyl chloride Chemical Properties,Usage,Production

Chemical Properties

Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator.

Uses

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020

General Description

A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.

Air & Water Reactions

Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.

Reactivity Profile

Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Fire Hazard

When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.

Potential Exposure

May be used as a monomer in preparation of specialty polymers or as a chemical intermediate

Shipping

UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required

Incompatibilities

Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals.

Acryloyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Acryloyl chloride Suppliers

Zibo Ward Chemical Technology Co., Ltd.
Tel
0533-3585309 13287083616
Email
13287083616@163.com
Country
China
ProdList
7
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58
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
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Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52693
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58
Chongqing Yuzhiquan Biological Technology Co., Ltd.
Tel
18306022109
Fax
QQ:2966918840
Email
3236923470@qq.com
Country
China
ProdList
296
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Xi'an Beckman Chemical Technology Co., Ltd.
Tel
029-81136681 15309292692
Email
fangxianwen@xa-bkm.com
Country
China
ProdList
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Pand (Shanghai) international trade Co., LTD
Tel
18662931292 18662931292
Email
3404730042@qq.com
Country
China
ProdList
4760
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58
Shanghai Yanze Chemical Co., Ltd.
Tel
15345144255
Email
260924549@qq.com
Country
China
ProdList
3129
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Lanzhou Yunlianfeng Chemical Co., LTD
Tel
0310-6563881; 13831088306
Fax
0086-310-6563881
Email
dmtf@taifengchem.com
Country
China
ProdList
20
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Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
613
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60
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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View Lastest Price from Acryloyl chloride manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
Acryloyl Chloride 814-68-6
Price
US $10.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10 ton
Release date
2024-08-21
Hebei Kingfiner Technology Development Co.Ltd
Product
Acryloyl chloride 814-68-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
500000kg
Release date
2023-08-03
Hebei Kingfiner Technology Development Co.Ltd
Product
Acryloyl chloride 814-68-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
500000kg
Release date
2023-08-03

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