ChemicalBook > CAS DataBase List > Acryloyl chloride

Acryloyl chloride

Product Name
Acryloyl chloride
CAS No.
814-68-6
Chemical Name
Acryloyl chloride
Synonyms
oyL;acrylyl chloride;propenoylchloride;ACRYLOYL CHLORIDE;Propenoyl chloride;Acryloylchloride,96%;2-PROPENOYL CHLORIDE;ACRYLIC ACID CHLORIDE;prop-2-enoyl chloride;chloridkyselinyakrylove
CBNumber
CB4854427
Molecular Formula
C3H3ClO
Formula Weight
90.51
MOL File
814-68-6.mol
More
Less

Acryloyl chloride Property

Melting point:
76 °C(Solv: isopropyl ether (108-20-3))
Boiling point:
72-76 °C (lit.)
Density 
1.114 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
1.93 psi ( 20 °C)
refractive index 
n20/D 1.435(lit.)
Flash point:
61 °F
storage temp. 
2-8°C
Water Solubility 
Miscible with water.
Sensitive 
Moisture & Light Sensitive
BRN 
635744
Stability:
Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
InChIKey
HFBMWMNUJJDEQZ-UHFFFAOYSA-N
CAS DataBase Reference
814-68-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoyl chloride(814-68-6)
EPA Substance Registry System
Acrylyl chloride (814-68-6)
More
Less

Safety

Hazard Codes 
F,T+
Risk Statements 
11-14-26-34
Safety Statements 
16-26-28-36/37/39-45-7/9
RIDADR 
UN 3383 6.1/PG 1
WGK Germany 
3
RTECS 
AT7350000
8-10
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29161980
Hazardous Substances Data
814-68-6(Hazardous Substances Data)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H290May be corrosive to metals

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P320Specific treatment is urgent (see … on this label).

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P405Store locked up.

P403+P235Store in a well-ventilated place. Keep cool.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
549797
Product name
Acryloyl chloride
Purity
97.0%, contains <210ppm MEHQ as stabilizer
Packaging
5g
Price
$62
Updated
2021/12/16
Sigma-Aldrich
Product number
8.00826
Product name
Acryloyl chloride
Purity
(stabilised with phenothiazine) for synthesis
Packaging
100 mL
Price
$124
Updated
2021/12/16
Sigma-Aldrich
Product number
8.00826
Product name
Acryloyl chloride
Purity
(stabilised with phenothiazine) for synthesis
Packaging
500 mL
Price
$381.1
Updated
2021/12/16
Sigma-Aldrich
Product number
549797
Product name
Acryloyl chloride
Purity
97.0%, contains <210ppm MEHQ as stabilizer
Packaging
500g
Price
$526
Updated
2021/12/16
Sigma-Aldrich
Product number
A24109
Product name
Acryloyl chloride
Purity
≥97%, contains ~400ppm phenothiazine as stabilizer
Packaging
5g
Price
$57
Updated
2021/03/22
More
Less

Acryloyl chloride Chemical Properties,Usage,Production

Chemical Properties

Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator.

Uses

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020

General Description

A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.

Air & Water Reactions

Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.

Reactivity Profile

Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Fire Hazard

When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.

Potential Exposure

May be used as a monomer in preparation of specialty polymers or as a chemical intermediate

Shipping

UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required

Incompatibilities

Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals.

Acryloyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Acryloyl chloride Suppliers

Zibo Ward Chemical Technology Co., Ltd.
Tel
0533-3585309
Email
13287083616@163.com
Country
CHINA
ProdList
5
Advantage
58
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
021-20337333-801
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
24980
Advantage
65
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
400-900-4166
Email
3007522970@qq.com
Country
China
ProdList
52515
Advantage
58
Chongqing Yuzhiquan Biological Technology Co., Ltd.
Tel
023-18306022-109;023-13098782-745
Fax
QQ:2966918840
Email
2966918840@qq.com;2910278169@qq.com;2974174958@qq.com;
Country
China
ProdList
310
Advantage
58
Shanghai QianYan Bio-technology Co., Ltd
Tel
02781293128
Email
orders@biochemsafebuy.com
Country
China
ProdList
9965
Advantage
55
Shanghai Billion Chemical Chemical Co. Ltd.
Tel
021-58771921-
Fax
QQ: 3440059551
Email
info@chemofchina.com;
Country
China
ProdList
2999
Advantage
58
Shanghai Xuanlin Pharmaceutical Technology Co., Ltd
Tel
;
Fax
QQ3450014153 ;
Email
3295742260@qq.com;3450014153@qq.com
Country
China
ProdList
976
Advantage
58
Xi'an Synthetize Industrial Co., Ltd.
Tel
Fax
15934815775
Email
lintengfei@xa-sks.com
Country
China
ProdList
9
Advantage
58
Neostar United (Changzhou) Industrial Co., Ltd.
Tel
0519-85551759-
Fax
0519-85557389
Email
markting@neostarunited.com
Country
China
ProdList
500
Advantage
58
Xi'an Beckman Chemical Technology Co., Ltd.
Tel
029-85722158-
Email
fangxianwen@xa-bkm.com
Country
China
ProdList
13
Advantage
58
More
Less

View Lastest Price from Acryloyl chloride manufacturers

Hebei Crovell Biotech Co Ltd
Product
Acryloyl Chloride 814-68-6
Price
US $10.00/Kg/Drum
Min. Order
1KG
Purity
98%
Supply Ability
10 ton
Release date
2021-07-08
Shijiazhuang tongyang Import and Export Co., LTD
Product
Acryloyl chloride 814-68-6
Price
US $10.00/KG
Min. Order
10KG
Purity
99
Supply Ability
100 mt
Release date
2021-08-13
Zhuozhou Wenxi import and Export Co., Ltd
Product
Acryloyl chloride 814-68-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

814-68-6, Acryloyl chlorideRelated Search:


  • chloridkyselinyakrylove
  • Propenoyl chloride
  • propenoylchloride
  • Acryloyl chloride, stabilized with 400 ppM phenothiazine
  • Acryloyl chloride, 97%, stabilized with p-Hydroxyanisole
  • Acryloyl chloride, 97%, stabilized with 400 ppm phenothiazine
  • Acryloyl chloride, 97%, stabilized with 400 ppm p-Hydroxyanisole
  • Acrylyl chloride manufacturer kf-wang(at)kf-chem.com
  • oyL
  • ACRYLOYL CHLORIDE, 96%, STABILIZED
  • ACRYLOYL CHLORIDE STAB. WITH 2 6-DI-TER
  • ACRYLOYL CHLORIDE, STAB.
  • Acryloylchloride,96%
  • Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
  • Acryloyl Chloride (stabilized with MEHQ)
  • Acryloyl Chloride (stabilized with Phenothiazine)
  • Acryloyl Chloride, Stab. With 400Ppm Phenothiazine
  • ACRYLOYL CHLORIDE, 97.0%
  • Acryloyl chloride,2-Propenoyl chloride
  • acrylyl chloride
  • ACRYLOYL CHLORIDE
  • ACRYLIC ACID CHLORIDE
  • ACRYLOYL CHLORIDE (STABILISED WITH PHENO
  • 2-PROPENOYL CHLORIDE
  • Chlorid kyseliny akrylove
  • Acryloyl Chloride (stabilized with Phenothiazine)&gt
  • Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole
  • Ibandronate Sodium Impurity J
  • prop-2-enoyl chloride
  • Ibandronate Impurity 17
  • Acryloyl chloride ISO 9001:2015 REACH
  • 814-68-6
  • CH2CHCOCl
  • C3H3OCl
  • Building Blocks
  • Carbonyl Compounds
  • Acid Halides
  • Organic Building Blocks
  • ACID CHLORIDES
  • Industrial/Fine Chemicals
  • Halogen compounds