ChemicalBook > CAS DataBase List > 3-Chloro-4-methylaniline

3-Chloro-4-methylaniline

Product Name
3-Chloro-4-methylaniline
CAS No.
95-74-9
Chemical Name
3-Chloro-4-methylaniline
Synonyms
CPT;2-CHLORO-4-TOLUIDINE;3-CHLORO-4-METHYL-PHENYLAMINE;OCPT;3-cpt;cpt[qr];drc1347;2B oil;DKC 1347;DRC 1339
CBNumber
CB5854707
Molecular Formula
C7H8ClN
Formula Weight
141.6
MOL File
95-74-9.mol
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3-Chloro-4-methylaniline Property

Melting point:
25 °C
Boiling point:
237-238 °C(lit.)
Density 
1.17
vapor pressure 
4.973-8.666Pa at 25℃
refractive index 
n20/D 1.584(lit.)
Flash point:
212 °F
storage temp. 
2-8°C
solubility 
Chloroform, Methanol (Slightly)
form 
powder to lump to clear liquid
pka
pK1: 4.05(+1) (25°C)
color 
White or Colorless to Light orange to Yellow
Specific Gravity
1.167
Water Solubility 
1 g/L (20 ºC)
BRN 
636511
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, acid chlorides, acids, acid anhydrides, chloroformates, reducing agents.
LogP
2.27
CAS DataBase Reference
95-74-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 3-chloro-4-methyl-(95-74-9)
EPA Substance Registry System
3-Chloro-4-methylaniline (95-74-9)
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Safety

Hazard Codes 
T,N,Xn
Risk Statements 
24/25-36/38-43-50/53-36/37/38-22
Safety Statements 
36/37/39-45-61-60-36/37-26
RIDADR 
UN 2239 6.1/PG 3
WGK Germany 
2
RTECS 
XU5111000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29214300
Hazardous Substances Data
95-74-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
236322
Product name
2-Chloro-4-aminotoluene
Purity
98%
Packaging
50g
Price
$18.4
Updated
2024/03/01
TCI Chemical
Product number
C0538
Product name
3-Chloro-4-methylaniline
Purity
>97.0%(GC)
Packaging
25g
Price
$68
Updated
2024/03/01
TCI Chemical
Product number
C0538
Product name
3-Chloro-4-methylaniline
Purity
>97.0%(GC)
Packaging
500g
Price
$411
Updated
2024/03/01
Alfa Aesar
Product number
A15439
Product name
3-Chloro-4-methylaniline, 98%
Packaging
250g
Price
$48.65
Updated
2024/03/01
Alfa Aesar
Product number
A15439
Product name
3-Chloro-4-methylaniline, 98%
Packaging
1000g
Price
$115.65
Updated
2024/03/01
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3-Chloro-4-methylaniline Chemical Properties,Usage,Production

Chemical Properties

brown solid

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Uses

2-Chloro-4-aminotoluene has been used in the preparation of 2-chloro-4-cyanotoluene by Sandmeyer reaction with cuprous cyanide.

Definition

ChEBI: A monochloroaniline that is p-toluidine in which one of the hydrogens that is meta to the amino group is replaced by a chlorine.

General Description

Brown solid with a mild odor.

Air & Water Reactions

May be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

3-Chloro-4-methylaniline may be sensitive to prolonged exposure to air and light. 3-Chloro-4-methylaniline may react with oxidizing agents. 3-Chloro-4-methylaniline is incompatible with acids, acid chlorides, acid anhydrides and chloroformates. 3-Chloro-4-methylaniline is also incompatible with reducing agents.

Fire Hazard

3-Chloro-4-methylaniline is combustible.

Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl and NOx. See also other chloro toluidme entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

3-Chloro-4-methylaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Chloro-4-methylaniline Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from 3-Chloro-4-methylaniline manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
3-Chloro-4-methylaniline 95-74-9
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2024-08-20
Career Henan Chemical Co
Product
3-Chloro-4-methylaniline 95-74-9
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kg
Release date
2019-08-30

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