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ChemicalBook > CAS DataBase List > DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

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Product Name
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
CAS No.
134524-84-8
Chemical Name
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Synonyms
Dichloro [(S);RuCl2[S-BINAP];(S)-BINAP RUCL2;-binaphthyl]dichlororuthenium;-1,1'-binaphthyl]ruthenium(II);-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichlorobisdiphenylphosphinobinaphthylrutheniu;(S)-(-)2,2'bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);Dichloro[(S)-(-)-,2,2'-bis(diphenylphosphino)-1,1'-binaphthy...;dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium
CBNumber
CB6114507
Molecular Formula
C44H32Cl2P2Ru
Formula Weight
794.65
MOL File
134524-84-8.mol
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Property

Melting point:
>300 ºC
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
form 
Powder
color 
orange
Sensitive 
air sensitive
Stability:
Air Sensitive, Moisture Sensitive
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-36/37
WGK Germany 
3
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3068
Product name
[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
Packaging
250mg
Price
$318
Updated
2024/03/01
Strem Chemicals
Product number
44-0249
Product name
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
100mg
Price
$73
Updated
2024/03/01
Strem Chemicals
Product number
44-0249
Product name
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
500mg
Price
$163
Updated
2024/03/01
Strem Chemicals
Product number
44-0249
Product name
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
2g
Price
$486
Updated
2024/03/01
TRC
Product number
B430400
Product name
[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium
Packaging
250mg
Price
$80
Updated
2021/12/16
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties,Usage,Production

Reaction

  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.

Chemical Properties

Solid

Uses

[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
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62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
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Beijing Ouhe Technology Co., Ltd
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010-82967028 13552068683
Fax
+86-10-82967029
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2355560935@qq.com
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China
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Shanghai Longsheng chemical Co.,Ltd.
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021-58099652-8005 13585536065
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021-58099609
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bin.wu@shlschem.com
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China
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Shijiazhuang Kenuo Da Technology Co., Ltd.
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0311-85461665 13784393231
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0311-85461665
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leichemist@126.com
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China
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Daicel Chiral Technologies (China)CO.,LTD
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021-50460086-9 15921403865
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+86-21-50462321
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han_yajun@dctc.daicel.com
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China
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Maya High Purity Chemicals
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+86 (573) 82222445 (0)18006601000 452520369
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+86 (573) 82222643
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sales@maya-r.com
Country
China
ProdList
11714
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Shanghai Topbiochem Technology Co., Ltd
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021-58170097
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info@topbiochem.com
Country
China
ProdList
9442
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View Lastest Price from DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) manufacturers

Shanghai UCHEM Inc.
Product
(S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 134524-84-8
Price
US $43.00-208.00/g
Min. Order
1g
Purity
0.98
Supply Ability
1kg
Release date
2024-04-12
Hangzhou ICH Biofarm Co., Ltd
Product
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 134524-84-8
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
200kg
Release date
2023-06-28
Hangzhou ICH Biofarm Co., Ltd
Product
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 134524-84-8
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
200kg
Release date
2023-06-28

134524-84-8, DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)Related Search:


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  • RuCl2[S-BINAP]
  • Dichloro[(S)-(-)-,2,2'-bis(diphenylphosphino)-1,1'-binaphthy...
  • DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
  • [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
  • Dichloro [(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • 134524-84-8
  • C44H32Cl2P2Ru
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Ru (Ruthenium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Ru