Diclofop-methyl
- Product Name
- Diclofop-methyl
- CAS No.
- 51338-27-3
- Chemical Name
- Diclofop-methyl
- Synonyms
- HOELON;Hoelan;Iloxan;NOGRASS;ILLOXAN;HOEGRASS;HOXAN(R);DICLOSAN;ELOGRASS;HOELON(R)
- CBNumber
- CB6118732
- Molecular Formula
- C16H14Cl2O4
- Formula Weight
- 341.19
- MOL File
- 51338-27-3.mol
Diclofop-methyl Property
- Melting point:
- 39-41°C
- Boiling point:
- 173-175°C (0.1 mbar)
- Density
- 1.3
- refractive index
- 1.5300 (estimate)
- storage temp.
- 0-6°C
- Water Solubility
- 0.005 g/100 mL
- Merck
- 13,3109
- BRN
- 2224754
- LogP
- 4.620
- CAS DataBase Reference
- 51338-27-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Propanoic acid, 2-[4-(2,4-dichlorophenoxy)phenoxy]-, methyl ester(51338-27-3)
- EPA Substance Registry System
- Diclofop methyl (51338-27-3)
Safety
- Hazard Codes
- Xn;N,N,Xn
- Risk Statements
- 22-43-50/53
- Safety Statements
- 24-37-60-61
- RIDADR
- UN 3077
- WGK Germany
- 2
- RTECS
- UF1180000
- HS Code
- 29189900
- Hazardous Substances Data
- 51338-27-3(Hazardous Substances Data)
- Toxicity
- dog,LD50,oral,1600mg/kg (1600mg/kg),"Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A138, Pg. 1983,
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H317May cause an allergic skin reaction
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 45442
- Product name
- Diclofop-methyl
- Purity
- PESTANAL
- Packaging
- 250mg
- Price
- $51.8
- Updated
- 2022/05/15
- Product number
- D431555
- Product name
- Diclofop-methyl
- Packaging
- 250mg
- Price
- $150
- Updated
- 2021/12/16
- Product number
- D431555
- Product name
- Diclofop-methyl
- Packaging
- 2.5g
- Price
- $920
- Updated
- 2021/12/16
- Product number
- CHM0165600
- Product name
- 2-[4-(2',4'-DICHLORO-PHENOXY)PHENOXY]-METHYL-PROPANOATE
- Purity
- 98.00%
- Packaging
- 50ML
- Price
- $2728
- Updated
- 2021/12/16
- Product number
- CDX-D0867-M500
- Product name
- Diclofop-methyl
- Purity
- ≥98%(HPLC)
- Packaging
- 500mg
- Price
- $47
- Updated
- 2021/12/16
Diclofop-methyl Chemical Properties,Usage,Production
Chemical Properties
A white crystalline solid. Odorless. Can also be commercially available as a clear to dark brown liquid with a typical solvent odor
Uses
Herbicide.
Definition
ChEBI: Methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate is a methyl ester resulting from the formal condensation of the carboxylic acid group of 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoic acid with methanol. It is an aromatic ether, a dichlorobenzene, a diether and a methyl ester.
General Description
Colorless crystals. Decomposed by either strong acid or base. Used as a selective herbicide.
Air & Water Reactions
Slightly soluble in water (3 mg/l).
Reactivity Profile
A bridged diphenyl.
Hazard
Moderately toxic by ingestion and skin contact. Low toxicity by inhalation.
Agricultural Uses
Herbicide: Some uses are classified as U.S. Restricted Use Pesticide (RUP). Diclofop-methyl is a selective post-emergence herbicide used to control wild oats and annual grassy weeds in grain and vegetable crops: alfalfa, carrots, celery, box, field and french beans, barley, wheat, brassicas, parsnips, peas, potatoes, rapeseed (canola), soy beans, oilseed rape, onions, sugar beets and lettuce.
Trade name
DICHLORDIPHENPROP®; HOELON®; HOELON® 3EC; HOE-GRASS®; HOEGRASS®; HOE® 23408; ILOXAN®; ILLOXAN®; ONE SHOT®[C]
Potential Exposure
Diclofop-methyl is a chlorophenoxy; aryloxyphenoxypropionate acid selective postemergenceherbicide used to control wild oats and annual grassy weeds in grain and vegetable crops: alfalfa, carrots, celery, box, field and French beans, barley, wheat, brassicas, parsnips, peas, potatoes, rapeseed (canola), soy beans, oilseed rape, onions, sugar beets and lettuce. Some uses are classified RUP
Environmental Fate
Biological. From the first-order biotic and abiotic rate constants of diclofop-methyl in estuarine water and sediment/water systems, the estimated biodegradation half-lives were 0.24–12.4 and 0.11–2.2 days, respectively (Walker et al., 1988).
Metabolic pathway
Two resistant biotypes of black-grass (Peldon A1 and Lincs. E1 of Alopecurus myosuroides) exhibit moderately enhanced metabolism of 14C-diclofop methyl. Diclofop methyl is hydrolyzed to the corresponding propionic acid which undergoes further degradation to give polar metabolites. The amounts of the metabolites depend on the metabolism activity of the individual biotypes. In wheat, three isomeric hydroxylated metabolites are identified in a major metabolic pathway after acid hydrolysis of the glucoside conjugates.
Shipping
UN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3348 Phenoxyacetic acid derivative pesticide, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. Note: Commercial product may also be a liquid in a flammable carrier.
Incompatibilities
Incompatible with oxidizers, chlorates nitrates, peroxides, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, and epichlorohydrin.
Waste Disposal
In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office
Diclofop-methyl Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Diclofop-methyl manufacturers
- Product
- Diclofop-methyl 51338-27-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 10 tons
- Release date
- 2020-01-10