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6-BROMOBENZOXAZOLE

Product Name
6-BROMOBENZOXAZOLE
CAS No.
52112-66-0
Chemical Name
6-BROMOBENZOXAZOLE
Synonyms
Nsc26185;6-BROMOBENZOXAZOLE;6-BROMOBENZO[D]OXAZOLE;6-Bromo-2-benzoxazolamine;2-amino-6-bromo-benzoxazol;2-Amino-6-bromobenzoxazole;6-Brom-benzoxazol-2-ylamin;2-Benzoxazolamine, 6-bromo-;6-BROMO-2-AMINO BENZOXAZOLE;6-BROMOBENZO[D]OXAZOL-2-AMINE
CBNumber
CB6124368
Molecular Formula
C7H5BrN2O
Formula Weight
213.03
MOL File
52112-66-0.mol
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6-BROMOBENZOXAZOLE Property

Boiling point:
340.4±34.0 °C(Predicted)
Density 
1.6569 (rough estimate)
refractive index 
1.6500 (estimate)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
1.08±0.30(Predicted)
Appearance
White to yellow Solid
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36
Safety Statements 
26
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Matrix Scientific
Product number
119117
Product name
2-Amino-6-bromobenzoxazole
Purity
95+%
Packaging
250mg
Price
$179
Updated
2021/12/16
AK Scientific
Product number
X4770
Product name
2-Amino-6-bromobenzoxazole
Packaging
1g
Price
$212
Updated
2021/12/16
Matrix Scientific
Product number
119117
Product name
2-Amino-6-bromobenzoxazole
Purity
95+%
Packaging
1g
Price
$395
Updated
2021/12/16
Matrix Scientific
Product number
119117
Product name
2-Amino-6-bromobenzoxazole
Purity
95+%
Packaging
5g
Price
$1183
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0037142
Product name
6-BROMOBENZO[D]OXAZOL-2-AMINE
Purity
95.00%
Packaging
5G
Price
$1940.4
Updated
2021/12/16
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6-BROMOBENZOXAZOLE Chemical Properties,Usage,Production

Synthesis

55305-43-6

38191-34-3

52112-66-0

GENERAL METHOD: 2-Amino-5-bromophenol (400 mg, 3.67 mmol) and N-cyano-4-methyl-N-phenylbenzenesulfonamide (998 mg, 3.67 mmol) were dissolved in THF (6 mL), and a hexane solution (3.67 mL, 3.67 mmol) of 1M LiHMDS was slowly added at 0°C. The reaction mixture was stirred at 0°C to room temperature for 1 hour. Subsequently, the reaction mixture was poured into ice water and stirring was continued for 15 min. The reaction mixture was extracted with EtOAc and the organic layer was separated. The organic layer was washed with saturated brine solution and then dried with anhydrous Na2SO4. After filtration, the organic layer was concentrated under reduced pressure. The crude product was purified by silica gel column chromatography to give pure 2-amino-6-bromobenzoxazole in 90% yield (471 mg).

References

[1] Synlett, 2015, vol. 26, # 7, p. 897 - 900

6-BROMOBENZOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMOBENZOXAZOLE Suppliers

China 76 Germany 2 India 3 Switzerland 1 United Kingdom 1 United States 13 Global 96
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Beijing Taiya Jie Technology Development Co., Ltd.
Tel
021-33690831-8001 13552411790
Fax
021-33690831
Email
postmaster@tyjchem.cn
Country
China
ProdList
1542
Advantage
55
NovoChemy Ltd.
Tel
021-31261262/ 49 (0)17662837245
Fax
(0)21-33250524
Email
sales@novochemy.com
Country
Germany
ProdList
6328
Advantage
58
SynAsst Chemical.
Tel
021-60343070
Fax
021-35122006
Country
China
ProdList
12740
Advantage
55
Shanghai ChriChem Co., Ltd.
Tel
021-54880687
Fax
021-54880687
Country
China
ProdList
511
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Shanghai Aspire Biological Technology Co., Ltd.
Tel
021-61317773
Fax
021-61486878
Email
sales@aspirebio.com
Country
China
ProdList
2880
Advantage
58
ShangHai AmK Pharmaceutical Technology Co., Ltd.
Tel
微信 17321281695 18019252918
Fax
17321281695
Email
sale@amkchem.com
Country
China
ProdList
15136
Advantage
55

52112-66-0, 6-BROMOBENZOXAZOLERelated Search:

6-FLUOROQUINOLIN-2-AMINE 2-Amino-6-Iodobenzothiazole ethyl 2-amino-6-chloroisonicotinate 2-amino-6-chloropyridine-4-carboxylic acid 2-Amino-6-chloro-3-pyridinecarboxaldehyde 2-Amino-6-trifluoromethylquinoxaline 2-AMINO-6-BROMOPYRIDO[2,3-D]PYRIMIDIN-4(3H)-ONE 2-Amino-benzothiazole-6-carbonitrile 2-Amino-6-methylpyrazine 2-Amino-5-chloropyridine-3-carboxylic acid ETHYL 2-AMINO-6-CHLOROBENZOATE 2-Amino-6-bromo-pyridine-3-carbaldehyde 6-bromo-3-methoxypyridin-2-amine 2-AMINO-6-BROMO-1,8-NAPHTHYRIDINE 5-BROMOBENZOXAZOLE BENZOOXAZOL-2-YLAMINE 6-BROMOBENZOXAZOLE 6-BROMOBENZOXAZOLE

  • 6-BROMOBENZO[D]OXAZOLE
  • 2-Benzoxazolamine, 6-bromo-
  • Nsc26185
  • Benzoxazole,2-amino-6-bromo- (7CI)
  • 6-Brom-benzoxazol-2-ylamin
  • 6-Bromo-2-benzoxazolamine
  • 2-Amino-6-bromobenzoxazole
  • 6-BROMOBENZOXAZOLE
  • 6-BROMOBENZO[D]OXAZOL-2-AMINE
  • 6-bromo-1,3-benzoxazol-2-amine
  • 2-amino-6-bromo-benzoxazol
  • 6-BROMO-2-AMINO BENZOXAZOLE
  • 52112-66-0
  • Miscellaneous