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ChemicalBook > CAS DataBase List > 6-BROMOBENZOXAZOLE

6-BROMOBENZOXAZOLE

Uses
Product Name
6-BROMOBENZOXAZOLE
CAS No.
375369-14-5
Chemical Name
6-BROMOBENZOXAZOLE
Synonyms
6-BROMOBENZO[D]OXAZOLE;6-BROMOBENZOXAZOLE;6-Chlorbenzoxazole;Benzoxazole, 6-bromo-;6-broMo-1,3-benzoxazole;6-BROMOBENZOXAZOLE ISO 9001:2015 REACH
CBNumber
CB6354082
Molecular Formula
C7H4BrNO
Formula Weight
198.02
MOL File
375369-14-5.mol
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6-BROMOBENZOXAZOLE Property

Boiling point:
251.2±13.0 °C(Predicted)
Density 
1.710±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
-0.49±0.30(Predicted)
form 
granular crystalline powder
color 
Reddish salmon (hint of tan)
InChI
InChI=1S/C7H4BrNO/c8-5-1-2-6-7(3-5)10-4-9-6/h1-4H
InChIKey
YXVFVHLEIBLKCA-UHFFFAOYSA-N
SMILES
O1C2=CC(Br)=CC=C2N=C1
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
B680673
Product name
6-Bromobenzoxazole
Packaging
25mg
Price
$45
Updated
2021/12/16
TRC
Product number
B680673
Product name
6-Bromobenzoxazole
Packaging
250mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB140209
Product name
6-Bromobenzoxazole
Packaging
500mg
Price
$80
Updated
2021/12/16
Apolloscientific
Product number
OR43655
Product name
6-Bromo-1,3-benzoxazole
Purity
98%
Packaging
250mg
Price
$58
Updated
2021/12/16
SynQuest Laboratories
Product number
4H44-9-22
Product name
6-Bromo-1,3-benzoxazole
Purity
98%
Packaging
250mg
Price
$64
Updated
2021/12/16
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6-BROMOBENZOXAZOLE Chemical Properties,Usage,Production

Uses

6-Bromobenzo[D]oxazole is a heterocyclic organic compound that can be used as a pharmaceutical intermediate.

Synthesis

38191-34-3

149-73-5

375369-14-5

General procedure for the synthesis of 6-bromobenzo[d]oxazole from 2-amino-5-bromophenol and trimethyl orthoformate: A mixture of 2-amino-5-bromophenol (1.0 g, 5.34 mmol), p-toluenesulfonic acid (100 mg, 0.581 mmol), and trimethyl orthoformate (6 mL) was stirred and reacted for 1 hr at 80 °C and under nitrogen protection. After completion of the reaction, the mixture was concentrated under vacuum. The residue was purified by silica gel column chromatography (petroleum ether/ethyl acetate = 9:1) to afford 6-bromobenzo[d]oxazole (980 mg, 93% yield) as a brown solid.LC-MS analysis showed no specific mass peaks and retention time tR = 1.73 min.

References

[1] Patent: WO2017/176961, 2017, A1. Location in patent: Paragraph 00510

6-BROMOBENZOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMOBENZOXAZOLE Suppliers

Awesome (Beijing)TechnologyCo.,Ltd.
Tel
18201687790 18201687790
Fax
QQ:1103319299
Email
yunbo12291229@163.com
Country
China
ProdList
175
Advantage
58
Shanghai Na Qian Chemical Technology Co. Ltd.
Tel
13598610367
Fax
QQ:2468833170
Email
2841375912@qq.com
Country
China
ProdList
2786
Advantage
52
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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61
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Beijing Taiya Jie Technology Development Co., Ltd.
Tel
021-33690831-8001 13552411790
Fax
021-33690831
Email
postmaster@tyjchem.cn
Country
China
ProdList
1542
Advantage
55
Wuhan ariel chemical Co., LTD.
Tel
18986259541
Fax
027-87840182
Email
sales@3stc.com
Country
China
ProdList
3763
Advantage
58
Wuhan Fortuna Chemical Co., Ltd
Tel
027-59207852 13308628970
Fax
QQ3130921841
Email
buy@fortunachem.com
Country
China
ProdList
2744
Advantage
58
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View Lastest Price from 6-BROMOBENZOXAZOLE manufacturers

Honest Joy Holdings Limited
Product
6-Bromobenzo[d]oxazole 375369-14-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98.6%
Supply Ability
100 tons
Release date
2022-01-14
Career Henan Chemical Co
Product
6-BROMOBENZOXAZOLE 375369-14-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KG
Release date
2019-12-18