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Phenylselenenyl chloride

Product Name
Phenylselenenyl chloride
CAS No.
5707-04-0
Chemical Name
Phenylselenenyl chloride
Synonyms
enenyL;chloroselenobenzene;Phenylchloroselenium;Phenylseleno chloride;PHENYLSELENYL CHLORIDE;PHENYLSELENIUM CHLORIDE;BENZENESELENYL CHLORIDE;PHENYLSELENENYL CHLORIDE;BENZENESELENENYL CHLORIDE;phenyl selenohypochlorite
CBNumber
CB6128896
Molecular Formula
C6H5ClSe
Formula Weight
191.52
MOL File
5707-04-0.mol
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Phenylselenenyl chloride Property

Melting point:
59-62 °C (lit.)
Boiling point:
120 °C/20 mmHg (lit.)
Flash point:
120°C/20mm
storage temp. 
Store below +30°C.
solubility 
Soluble in methanol.
form 
crystal
color 
red
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
BRN 
1237091
Exposure limits
ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
Stability:
Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents.
InChI
InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
InChIKey
WJCXADMLESSGRI-UHFFFAOYSA-N
SMILES
C1([Se]Cl)=CC=CC=C1
CAS DataBase Reference
5707-04-0(CAS DataBase Reference)
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Safety

Hazard Codes 
T,N
Risk Statements 
23/25-33-50/53
Safety Statements 
20/21-28-45-60-61
RIDADR 
UN 2928 6.1/PG 2
WGK Germany 
3
10-21
TSCA 
No
HazardClass 
6.1
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
183342
Product name
Phenylselenyl chloride
Purity
98%
Packaging
1g
Price
$53.1
Updated
2024/03/01
Sigma-Aldrich
Product number
183342
Product name
Phenylselenyl chloride
Purity
98%
Packaging
10g
Price
$294
Updated
2024/03/01
TCI Chemical
Product number
P1091
Product name
Phenylselenenyl Chloride
Purity
>97.0%(T)
Packaging
5g
Price
$74
Updated
2024/03/01
TCI Chemical
Product number
P1091
Product name
Phenylselenenyl Chloride
Purity
>97.0%(T)
Packaging
25g
Price
$253
Updated
2024/03/01
Alfa Aesar
Product number
A12751
Product name
Phenylselenenyl chloride, 98%
Packaging
5g
Price
$83.6
Updated
2024/03/01
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Phenylselenenyl chloride Chemical Properties,Usage,Production

Chemical Properties

crystalline solid

Uses

Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols.

Application

Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins[1].

General Description

Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis.

Purification Methods

Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC.

References

[1] S. Uemura. “Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins.” Tetrahedron Letters 21 1 (1980): 1533–1536.

Phenylselenenyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Phenylselenenyl chloride Suppliers

Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1686
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94658
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40240
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44700
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12439
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42959
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
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View Lastest Price from Phenylselenenyl chloride manufacturers

Career Henan Chemical Co
Product
PHENYLSELENENYL CHLORIDE 5707-04-0
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100g , 1kg, 5kg , 50kg
Release date
2020-01-07

5707-04-0, Phenylselenenyl chlorideRelated Search:


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