Phenylsilane
- Product Name
- Phenylsilane
- CAS No.
- 694-53-1
- Chemical Name
- Phenylsilane
- Synonyms
- Silylbenzene;Phenylsilane, 98% 25ML;Fenylsilan;PHENYLSILANE;phenyl-silan;CHLORODIMETHYL;Benzene, silyl-;Silane, phenyl-;Phenylsilane>Phenylsilane,98%
- CBNumber
- CB1677768
- Molecular Formula
- C6H8Si
- Formula Weight
- 108.21
- MOL File
- 694-53-1.mol
Phenylsilane Property
- Melting point:
- -64 to -68°C
- Boiling point:
- 120 °C (lit.)
- Density
- 0.877 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.510(lit.)
- Flash point:
- 45 °F
- storage temp.
- Flammables area
- form
- clear liquid
- color
- Colorless to Almost colorless
- Specific Gravity
- 0.868
- Water Solubility
- Contact with water releases a flammable alcohol. Soluble in water (Contact with water releases flammable gases), and most common organic solvents.
- Sensitive
- Air & Moisture Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 2935169
- InChIKey
- PARWUHTVGZSQPD-UHFFFAOYSA-N
- CAS DataBase Reference
- 694-53-1(CAS DataBase Reference)
- EPA Substance Registry System
- Silane, phenyl- (694-53-1)
Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 11-14/15-20/22-36/37/38
- Safety Statements
- 16-43
- RIDADR
- UN 3399 4.3/PG 2
- WGK Germany
- 1
- RTECS
- VV4825000
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 4.3
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 335150
- Product name
- Phenylsilane
- Purity
- 97%
- Packaging
- 1g
- Price
- $35.6
- Updated
- 2024/03/01
- Product number
- 335150
- Product name
- Phenylsilane
- Purity
- 97%
- Packaging
- 5g
- Price
- $102
- Updated
- 2024/03/01
- Product number
- P1291
- Product name
- Phenylsilane
- Purity
- >97.0%(GC)
- Packaging
- 5mL
- Price
- $161
- Updated
- 2024/03/01
- Product number
- P1291
- Product name
- Phenylsilane
- Purity
- >97.0%(GC)
- Packaging
- 25mL
- Price
- $440
- Updated
- 2024/03/01
- Product number
- A17901
- Product name
- Phenylsilane, 97%
- Packaging
- 5g
- Price
- $88.8
- Updated
- 2024/03/01
Phenylsilane Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Uses
Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.
Uses
phenylsilane is used as a pharmaceutical intermediate.
Application
Employed in the reduction of esters to ethers. Reduces α,β-unsaturated ketones to saturated ketones in the presence of tri-n-butyltin hydride. Reduces tin amides to tin hydrides. Used in the tin-catalyzed reduction of nitroalkanes to alkanes. Reduces α-halo ketones in presence of Mo(0).
Definition
ChEBI: Phenylsilane is an organosilicon compound that is benzene in which a hydrogen is replaced by a silyl group. It has a role as a reducing agent. It is an organosilicon compound and a member of benzenes.
Synthesis
The method for preparing phenyl silane comprises the following steps: adding trichlorophenylsilane in a tetrahydrofuran solution dissolved with a catalyst, carrying out a reaction at the temperature of -10-0 ℃, after the completion of the reaction is monitored by a TLC method, adding the product into an inorganic acid dilute solution under an ice bath condition, and extracting an organic layer, to obtain phenyl silane.
Phenylsilane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Phenylsilane manufacturers
- Product
- Phenylsilane 694-53-1
- Price
- US $2000.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1 tons
- Release date
- 2024-06-04
- Product
- Trifluoromethanesulfonic anhydride 358-23-6
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-29
- Product
- phenylsilicon 694-53-1
- Price
- US $1.00/g
- Min. Order
- 300g
- Purity
- 99.8%
- Supply Ability
- 20 TONS
- Release date
- 2021-07-27