Phenylselenenyl chloride

Product Name: Phenylselenenyl chloride
CAS No.: 5707-04-0
Chemical Name: Phenylselenenyl chloride
Synonyms: enenyL;chloroselenobenzene;Phenylchloroselenium;Phenylseleno chloride;PHENYLSELENYL CHLORIDE;PHENYLSELENIUM CHLORIDE;BENZENESELENYL CHLORIDE;PHENYLSELENENYL CHLORIDE;BENZENESELENENYL CHLORIDE;phenyl selenohypochlorite
CBNumber: CB6128896
Molecular Formula: C6H5ClSe
Formula Weight: 191.52
MOL File: 5707-04-0.mol

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Phenylselenenyl chloride Property

Melting point:: 59-62 °C (lit.)
Boiling point:: 120 °C/20 mmHg (lit.)
Flash point:: 120°C/20mm
storage temp.: Store below +30°C.
solubility: Soluble in methanol.
form: crystal
color: red
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Sensitive: Moisture Sensitive
BRN: 1237091
Exposure limits: ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
Stability:: Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents.
InChI: InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
InChIKey: WJCXADMLESSGRI-UHFFFAOYSA-N
SMILES: C1([Se]Cl)=CC=CC=C1
CAS DataBase Reference: 5707-04-0(CAS DataBase Reference)

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Safety

Hazard Codes: T,N
Risk Statements: 23/25-33-50/53
Safety Statements: 20/21-28-45-60-61
RIDADR: UN 2928 6.1/PG 2
WGK Germany: 3
F: 10-21
TSCA: No
HazardClass: 6.1
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 183342
Product name: Phenylselenyl chloride
Purity: 98%
Packaging: 1g
Price: $53.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 183342
Product name: Phenylselenyl chloride
Purity: 98%
Packaging: 10g
Price: $294
Updated: 2024/03/01

TCI Chemical

Product number: P1091
Product name: Phenylselenenyl Chloride
Purity: >97.0%(T)
Packaging: 5g
Price: $74
Updated: 2024/03/01

TCI Chemical

Product number: P1091
Product name: Phenylselenenyl Chloride
Purity: >97.0%(T)
Packaging: 25g
Price: $253
Updated: 2024/03/01

Alfa Aesar

Product number: A12751
Product name: Phenylselenenyl chloride, 98%
Packaging: 5g
Price: $83.6
Updated: 2024/03/01

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Phenylselenenyl chloride Chemical Properties,Usage,Production

Chemical Properties

crystalline solid

Uses

Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols.

Application

Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins[1].

General Description

Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis.

Purification Methods

Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC.

References

[1] S. Uemura. “Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins.” Tetrahedron Letters 21 1 (1980): 1533–1536.

Phenylselenenyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Phenylselenenyl chloride Suppliers

Americas 1 Belgium 5 CHINA 82 Europe 3 Germany 7 India 7 Japan 3 Singapore 1 Switzerland 2 United Kingdom 7 United States 19 Global 137

Alkemi BVBA

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Acros Organics (Part of Thermo Fisher Scientific )

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Eburon Organics bvba

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Acros Organics

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Country: Belgium
ProdList: 6772
Advantage: 81

Eburon Organics N.V.

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Email: eburon@innet.be
Country: Belgium
ProdList: 490
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View Lastest Price from Phenylselenenyl chloride manufacturers

Career Henan Chemical Co

Product: PHENYLSELENENYL CHLORIDE 5707-04-0
Price: US $2.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100g , 1kg, 5kg , 50kg
Release date: 2020-01-07

5707-04-0, Phenylselenenyl chlorideRelated Search:

Selenium sulfide SELENIUM CHLORIDE PHENYLSELENOL DIETHYLDISELENIDE Selenium Oxychloride Selenium Phenylsilane Diphenyl diselenide Selenium tetrachloride DIPHENYL SELENIDE Selenium dioxide Selenic acid DIMETHYLSELENIDE Phenyltris(trimethylsiloxy)silane Phenyltriethoxysilane Trimethoxyphenylsilane PHENYLTHIOACETONITRILE Phenyltrichlorosilane

PHENYLSELENENYL CHLORIDE

PHENYLSELENIUM CHLORIDE

PHENYLSELENYL CHLORIDE

chloroselenobenzene

Phenylselenenylchloride,98%

Phenylselenyl chloride, 97+%

Benzeneselenenyl chloride, Benzeneselenyl chloride

Phenylselenyl chloride, 98% 10GR

Benzeneselenenic acid chloride

Phenylchloroselenium

Phenylseleno chloride

Phenylselenyl chloride,98%

phenyl hypochloroselenoite

Phenylselenyl chloride 98%

Phenylselenenyl Chloride, 95.0%(T)

P**Phenylselenyl chloride 98%

BENZENESELENENYL CHLORIDE

BENZENESELENYL CHLORIDE

PhenylselenenylChloride&gt

enenyL

phenyl selenohypochlorite

5707-04-0

C6H5ClSe

C6H5SeCl

Classes of Metal Compounds

Semimetal Compounds

Se (Selenium) Compounds

Building Blocks

Selenium Compounds

Organic Building Blocks

Classes of Metal Compounds

Se (Selenium) Compounds

Semimetal Compounds

organoselenides