Phenylselenenyl chloride
- Product Name
- Phenylselenenyl chloride
- CAS No.
- 5707-04-0
- Chemical Name
- Phenylselenenyl chloride
- Synonyms
- enenyL;chloroselenobenzene;Phenylchloroselenium;Phenylseleno chloride;PHENYLSELENYL CHLORIDE;PHENYLSELENIUM CHLORIDE;BENZENESELENYL CHLORIDE;PHENYLSELENENYL CHLORIDE;BENZENESELENENYL CHLORIDE;phenyl selenohypochlorite
- CBNumber
- CB6128896
- Molecular Formula
- C6H5ClSe
- Formula Weight
- 191.52
- MOL File
- 5707-04-0.mol
Phenylselenenyl chloride Property
- Melting point:
- 59-62 °C (lit.)
- Boiling point:
- 120 °C/20 mmHg (lit.)
- Flash point:
- 120°C/20mm
- storage temp.
- Store below +30°C.
- solubility
- Soluble in methanol.
- form
- crystal
- color
- red
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Sensitive
- Moisture Sensitive
- BRN
- 1237091
- Exposure limits
- ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 - Stability:
- Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents.
- InChI
- InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
- InChIKey
- WJCXADMLESSGRI-UHFFFAOYSA-N
- SMILES
- C1([Se]Cl)=CC=CC=C1
- CAS DataBase Reference
- 5707-04-0(CAS DataBase Reference)
Safety
- Hazard Codes
- T,N
- Risk Statements
- 23/25-33-50/53
- Safety Statements
- 20/21-28-45-60-61
- RIDADR
- UN 2928 6.1/PG 2
- WGK Germany
- 3
- F
- 10-21
- TSCA
- No
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H373May cause damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P234Keep only in original container.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P314Get medical advice/attention if you feel unwell.
N-Bromosuccinimide Price
- Product number
- 183342
- Product name
- Phenylselenyl chloride
- Purity
- 98%
- Packaging
- 1g
- Price
- $53.1
- Updated
- 2024/03/01
- Product number
- 183342
- Product name
- Phenylselenyl chloride
- Purity
- 98%
- Packaging
- 10g
- Price
- $294
- Updated
- 2024/03/01
- Product number
- P1091
- Product name
- Phenylselenenyl Chloride
- Purity
- >97.0%(T)
- Packaging
- 5g
- Price
- $74
- Updated
- 2024/03/01
- Product number
- P1091
- Product name
- Phenylselenenyl Chloride
- Purity
- >97.0%(T)
- Packaging
- 25g
- Price
- $253
- Updated
- 2024/03/01
- Product number
- A12751
- Product name
- Phenylselenenyl chloride, 98%
- Packaging
- 5g
- Price
- $83.6
- Updated
- 2024/03/01
Phenylselenenyl chloride Chemical Properties,Usage,Production
Chemical Properties
crystalline solid
Uses
Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols.
Application
Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins[1].
General Description
Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis.
Purification Methods
Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC.
References
[1] S. Uemura. “Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins.” Tetrahedron Letters 21 1 (1980): 1533–1536.
Phenylselenenyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Phenylselenenyl chloride manufacturers
- Product
- PHENYLSELENENYL CHLORIDE 5707-04-0
- Price
- US $2.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100g , 1kg, 5kg , 50kg
- Release date
- 2020-01-07